Atomic Structure and Periodic Table

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Questions and Answers

How many sublevels are present in the principal quantum number n=3?

  • 4
  • 2
  • 5
  • 3 (correct)

What is the total number of orbitals associated with the principal quantum number n=4?

  • 9
  • 16 (correct)
  • 14
  • 7

According to the Aufbau Principle, which orbital will be filled last?

  • 3d
  • 4d (correct)
  • 5s
  • 4p

How many electrons can occupy a single orbital according to the Pauli Exclusion Principle?

<p>2 (A)</p> Signup and view all the answers

What does Hund's Rule state about electron distribution in orbitals?

<p>Electrons fill each orbital before pairing occurs. (A)</p> Signup and view all the answers

What characteristic defines an element?

<p>The number of protons in the nucleus (B)</p> Signup and view all the answers

Which group in the periodic table contains metals that are good conductors of heat and electricity?

<p>Transition Metals (C)</p> Signup and view all the answers

How many vertical groups are there in the periodic table?

<p>18 (D)</p> Signup and view all the answers

Elements in which group are typically highly reactive and exist as compounds with other elements?

<p>Alkali Metals (C)</p> Signup and view all the answers

What do the horizontal rows in the periodic table represent?

<p>Number of electron shells (B)</p> Signup and view all the answers

Which group contains elements with four valence electrons?

<p>Carbon Group (A)</p> Signup and view all the answers

What is a key property of elements in the Boron Group?

<p>Three valence electrons (A)</p> Signup and view all the answers

Which characteristic describes alkaline earth metals?

<p>They are solid and harder than alkali metals. (A)</p> Signup and view all the answers

What type of reaction occurs when two or more substances combine to form a more complex substance?

<p>Combination (C)</p> Signup and view all the answers

In the equation 2Al(s) + 3Cl2(g) → 2AlCl3(s), how many chlorine atoms are present on the reactant side?

<p>6 (D)</p> Signup and view all the answers

Which reaction classification involves a compound breaking down into simpler compounds or elements?

<p>Decomposition (D)</p> Signup and view all the answers

In combustion reactions, which product is produced when there is insufficient oxygen?

<p>Carbon Monoxide (CO) (A)</p> Signup and view all the answers

What is defined as the minimum amount of energy needed to initiate a chemical reaction?

<p>Activation Energy (A)</p> Signup and view all the answers

How does increasing the surface area of reactants affect the rate of a chemical reaction?

<p>Makes it faster (B)</p> Signup and view all the answers

Which statement about complete combustion is true?

<p>It produces carbon dioxide and water (B)</p> Signup and view all the answers

Which factor directly relates to how fast or slow reactants are converted into products in a chemical reaction?

<p>Activation Energy (A)</p> Signup and view all the answers

What is the primary characteristic of the elements in the Nitrogen Group?

<p>They commonly form nitrogen-based compounds. (B)</p> Signup and view all the answers

What happens to electronegativity as you move across a period from left to right?

<p>It increases as atoms attract electrons more strongly. (C)</p> Signup and view all the answers

How does the atomic radius change across a period in the periodic table?

<p>It decreases from left to right. (D)</p> Signup and view all the answers

What is the primary conclusion from Rutherford’s Gold Foil Experiment?

<p>The positive charge is concentrated in the nucleus. (A)</p> Signup and view all the answers

Which group of elements is characterized by having eight valence electrons and being stable?

<p>Noble Gases (D)</p> Signup and view all the answers

Which atomic model proposed that electrons occupy stable orbitals around the nucleus?

<p>Bohr’s Orbit Model (D)</p> Signup and view all the answers

What happens to an atom when it loses electrons and forms a cation?

<p>It becomes smaller. (D)</p> Signup and view all the answers

What best describes the Heisenberg's Uncertainty Principle?

<p>It's impossible to know exactly where an electron is at any moment. (C)</p> Signup and view all the answers

Which of the following describes the ionization energy trend as you move down a group in the periodic table?

<p>It decreases down a group. (A)</p> Signup and view all the answers

What defines the shape and type of orbitals in an atom?

<p>Sublevel (Subshell) (B)</p> Signup and view all the answers

What is a significant property of Halogens?

<p>They are highly reactive and form compounds with metals. (D)</p> Signup and view all the answers

Which of the following correctly describes valence electrons?

<p>They are electrons in the outermost energy level of an atom. (B)</p> Signup and view all the answers

Which statement most accurately describes the elements in the Oxygen Group?

<p>They have six valence electrons and form essential compounds for life. (D)</p> Signup and view all the answers

According to the quantum mechanical model, what does the orbital represent?

<p>A possible location of an electron. (A)</p> Signup and view all the answers

What effect does increasing the number of protons in the nucleus have on atomic attraction?

<p>It increases nuclear attraction, causing the atom to shrink. (A)</p> Signup and view all the answers

Which statement best reflects Dalton's Atomic Theory regarding atoms?

<p>All atoms of a particular element are identical. (D)</p> Signup and view all the answers

What is the correct way to name the ionic compound formed from magnesium and chlorine?

<p>Magnesium chloride (C), Magnesium(II) chloride (D)</p> Signup and view all the answers

Which of the following correctly describes the properties of ionic compounds?

<p>Ionic compounds generally have high melting and boiling points. (B)</p> Signup and view all the answers

What prefix is used when naming the covalent compound with one atom of the first element?

<p>mono- (B)</p> Signup and view all the answers

In a chemical equation, what does a skeleton equation represent?

<p>The chemical reaction using symbols without coefficients (B)</p> Signup and view all the answers

Which of the following compounds is correctly named and represents a covalent compound?

<p>N₂O₄ = Dinitrogen tetroxide (A), CO = Carbon monoxide (B), PCl₂ = Phosphorus dichloride (C)</p> Signup and view all the answers

What happens to mass during a chemical reaction according to the law of conservation of mass?

<p>Total mass remains constant. (B)</p> Signup and view all the answers

What describes why ionic compounds often conduct electricity in water?

<p>Ionic compounds dissociate into ions in water. (B)</p> Signup and view all the answers

Which of these statements is NOT true regarding the naming of ionic compounds?

<p>Prefixes are used for naming ionic compounds. (C)</p> Signup and view all the answers

Flashcards

Element

A pure substance made up of only one type of atom, defined by the number of protons in its nucleus.

Periods

Horizontal rows in the Periodic Table, indicating the number of electron shells an atom has.

Groups or Families

Vertical columns in the Periodic Table containing elements with similar properties and the same number of valence electrons.

Alkali Metals

Highly reactive metals that naturally exist as compounds with other elements. They are soft, shiny, and have low densities and melting points.

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Alkaline Earth Metals

Also highly reactive, these metals are harder than alkali metals and are good conductors of heat and electricity.

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Transition Metals

Hard, shiny solids with high thermal and electrical conductivity. They are often found in alloys and are good conductors of heat and electricity.

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Boron Group

Elements with three valence electrons, including metals and metalloids, some of which are semiconductors.

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Carbon Group

Elements with four valence electrons, including nonmetals, metalloids, and metals. They are essential for organic compounds.

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Atomic Radius

The distance between the nucleus of an atom and its outermost electron shell.

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Nuclear Attraction

The force of attraction between the nucleus and electrons in an atom. It increases as the number of protons increases, making the atom smaller.

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Ionic Radius

The size of an ion, which is an atom that has gained or lost electrons.

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Ionization Energy

The energy required to remove an electron from a gaseous atom, creating a positive ion.

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Nitrogen Group (Pnictogens)

Elements with five valence electrons. They include nonmetals and metalloids and commonly form nitrogen-based compounds.

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Oxygen Group (Chalcogens)

Elements with six valence electrons. They include oxygen and sulfur and are essential for life, forming a variety of compounds.

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Halogens

Highly reactive nonmetals that react violently, especially with metals. They are poor conductors of heat and electricity, and have low melting and boiling points.

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Noble Gases

Colorless, odorless, and nonflammable gases under standard conditions. They are the most stable elements, with eight valence electrons, making them inert and unreactive.

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Aufbau Principle

A principle that states electrons fill the lowest energy orbitals first before moving to higher energy ones. Orbitals are filled in a specific order, starting with 1s.

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Pauli Exclusion Principle

The principle that dictates only two electrons can occupy an orbital, and they must have opposite spins. This accounts for the different energy states of electrons.

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Hund's Rule

A rule that states each orbital must receive one electron before any orbital can receive a second electron. It helps explain the filling of orbitals with multiple electrons.

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Principal Quantum Number (n)

The number that indicates the energy level of an electron in an atom. It's a positive integer starting with 1 for the lowest energy level.

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Sublevel (l)

Indicates the shape of an electron orbital. It can be s, p, d, or f, representing different shapes and energy levels.

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Electronegativity

The ability of an atom to attract electrons towards itself when forming a chemical bond.

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Atomic Theory (Democritus)

All matter is composed of tiny indivisible particles called 'atomos'.

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Dalton’s Atomic Theory (John Dalton)

All elements are made up of tiny particles called 'atoms'. All atoms of a particular element are identical. The atoms of one element are different from another element. Atoms of an element can combine with atoms of another element to form compounds. Atoms are indivisible, they can’t be created nor destroyed in chemical reactions.

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Thomson’s Plum Pudding Model (JJ Thomson)

Discovered electrons, negative particles within atoms. Proposed the atom is a 'plum pudding' with electrons embedded in a positively charged 'pudding'.

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Rutherford’s Gold Foil Experiment (Ernest Rutherford)

Positive charge is not like a pudding but it's concentrated in the nucleus. Concluded that atoms have a dense, positively charged nucleus with electrons surrounding it.

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Bohr’s Orbit Model (Niels Bohr)

Electrons in an atom occupy certain orbits with quantized energies. Atoms have allowable energy states. Electrons revolve in stable orbitals around a nucleus. Atoms have certain allowable energy states

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Heisenberg’s Uncertainty Principle (Werner Heisenberg)

It's impossible to know exactly where an electron is at any moment. There is uncertainty in the position and motion of the electron.

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Quantum Mechanical Model of An Atom

It is a map of the probably location of the electrons. It helps us predict the orbitals' possible location, shape, and energy of the location

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Law of Conservation of Mass

In a chemical reaction, mass is neither created nor destroyed. The total mass of reactants equals the total mass of products. Atoms are rearranged but not lost or gained.

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Chemical Equation

A statement using symbols to represent a chemical reaction. It shows reactants, products, and the direction of the reaction.

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Word Equation

A chemical equation that uses words to describe a reaction. Example: Aluminum and Chlorine react to form Aluminum Chloride.

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Skeleton Equation

A chemical equation that uses symbols to represent the reaction but doesn't balance the number of atoms on each side.

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Writing Covalent Compounds

Using prefixes like mono-, di-, tri-, etc., to indicate the number of atoms in a covalent compound. Example: CO₂ = Carbon dioxide.

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Naming Covalent Compounds

Naming covalent compounds by naming the first element with a prefix (if more than one atom) and the second element with the prefix and '-ide' ending. Example: CO₂ = Carbon dioxide.

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Crisscrossing Charges

A method of balancing ionic charges in a compound by crisscrossing the numerical values of the charges and using those as subscripts. Example: Na⁺ + Cl⁻ → NaCl.

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Naming Ionic Compounds

Naming ionic compounds by naming the cation first (no prefix), then the anion with '-ide' ending. For transition metals, use Roman numerals for the charge. Example: NaCl = Sodium chloride, FeCl₂ = Iron (II) chloride.

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Combination or Synthesis Reaction

A chemical reaction where two or more simple substances combine to form a more complex substance. Example: A + B → AB

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Decomposition Reaction

A chemical reaction where a compound breaks down into two or more simpler compounds or elements. Example: AB → A + B

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Single Replacement Reaction

A chemical reaction where an element replaces another element in a compound. Example: A + BC → AC + B

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Double Displacement Reaction

A chemical reaction where two compounds exchange cations to produce two different compounds. Example: AB + CD → AD + BC

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Combustion Reaction

A chemical reaction that happens when a hydrocarbon reacts with oxygen, producing energy in the form of heat and light. Example: CxHy + O2 → CO2 + H2O (Complete Combustion) CxHy + O2 → C + CO + H2O (Incomplete Combustion)

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Activation Energy

The minimum amount of energy needed to start a chemical reaction. Higher activation energy means a slower reaction, and lower activation energy means a faster reaction.

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Rate of Chemical Reaction

The speed at which reactants are converted into products. A faster rate means the reaction happens quickly, while a slower rate means it takes longer.

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Surface Area and Reaction Rate

Increasing the surface area of reactants will make the reaction happen faster because more particles are exposed and can interact.

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Study Notes

Atomic Structure

  • Atoms are the smallest units of matter retaining element characteristics.
  • Composed of protons (positive charge), neutrons (neutral charge), and electrons (negative charge).
  • Protons are positively charged particles found in the nucleus and define element identity.
  • Electrons are negatively charged particles orbiting the nucleus, responsible for chemical bonding.
  • Neutrons have no charge and stabilize the nucleus.
  • Atomic number is the number of protons in the nucleus.
  • Mass number is the total number of protons and neutrons.
  • To find the number of protons, use the atomic number.
  • To find the number of electrons, it's the same as the number of protons.
  • To find the number of neutrons, subtract the atomic number from the mass number.

The Periodic Table

  • Elements are pure substances of one type of atom.
  • Elements on the periodic table are classified into metals, nonmetals, and metalloids.
  • Periods are horizontal rows indicating the number of electron shells.
  • Groups (or families) are vertical columns with similar properties and valence electrons.
  • The periodic table is organized in 7 rows (periods) and 18 columns (groups).
  • Group 1 (Alkali Metals): Highly reactive, low density and low melting points.
  • Group 2 (Alkaline Earth Metals): Highly reactive, denser and harder than alkali metals with higher boiling and melting points compared to alkali metals.
  • Atomic radius: Decreases across a period, increases down a group.
  • Nuclear attraction: Increases across a period, due to more protons pulling electrons closer.
  • Ionic radius: Atoms that lose electrons become smaller cations, while gaining electrons create larger anions.
  • Ionization energy: Increases across a period, decreases down a group.
  • Electronegativity: Increases across a period, decreases down a group, describing the tendency for an atom to attract electrons.

Atomic Theory

  • Democritus: Proposed that all matter is composed of tiny indivisible particles called atomos.
  • Dalton: Proposed the atomic theory, including that atoms of the same element are identical and atoms combine to form compounds.
  • Thomson: Discovered electrons, with a plum pudding-type model.
  • Rutherford: Discovered the nucleus through the Gold Foil experiment, stating that atoms are mostly empty space with a dense, positively charged nucleus.
  • Bohr: Electrons orbit the nucleus in specific energy levels.
  • Heisenberg: Uncertainty principle states it's impossible to know an electron's exact position and momentum simultaneously.

Quantum Mechanical Model

  • Explains the location, shape, and energy of electrons.
  • Energy levels (or shells): Discrete energy values for electrons around the nucleus.
  • Sublevels (subshells): Different shapes in which orbitals exist.
  • Orbitals: Regions where electrons are likely to be found.
  • Valence electrons: The electrons in the outermost energy level, involved in chemical reactions.

Electronic Configuration

  • Aufbau Principle: Electrons fill the lowest energy orbitals first.
  • Pauli Exclusion Principle: Only two electrons can occupy an orbital, with opposite spins.
  • Hund's Rule: Each orbital receives one electron before a second electron enters.
  • Determining electron configuration requires the atomic number and knowledge of orbital filling order.

Chemical Bonding

  • Electrostatic Forces cause attraction or repulsion based on charges between atoms to form compounds.
  • lonic Bonding: Transfer of electrons between a metal and nonmetal, forming oppositely charged ions.
  • Covalent Bonding: Sharing of electrons between two nonmetals.
  • Metallic Bonding: Electrons are delocalized and shared among metal atoms.

Types of Chemical Bonding

  • Ionic bonds occur when electrons are transferred between atoms, forming positively and negatively charged ions that attract each other. These bonds usually occur between metals and nonmetals.
  • Covalent bonds occur when electrons are shared between atoms, typically occurring between nonmetals.
  • Metallic bonds occur among metals, characterized by delocalized electrons shared among multiple atoms leading to high electrical & thermal conductivity, malleability and ductility.

Naming Ionic and Covalent Compounds

  • Ionic compounds are named with the positive ion (cation) first and negative ion (anion) second.
  • Covalent compounds use prefixes to indicate the number of each atom.

Chemical Reactions and Equations

  • A chemical reaction is a process where substances are transformed into new substances.
  • The Law of Conservation of Mass dictates that mass is neither gained nor lost during a chemical reaction.
  • A chemical equation shows the reactants (initial substances) and products (substances produced).
  • Types of chemical reactions include combination, decomposition, single replacement, double replacement, and combustion.
  • Steps involved in balancing and writing a chemical equation involves writing the skeleton equation, counting atoms of reactants and products for each element, ensuring balancing the count by adding coefficients when necessary. Always verify that the count of atoms per type of element on both sides of the equation equal each other, ensuring no touching of the subscripts.

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