Atomic Structure and Models Quiz

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Questions and Answers

What is the small positively charged center of the atom called?

  • Proton bundle
  • Atom core
  • Nucleus (correct)
  • Electron cloud

According to Rutherford's model, how do electrons move around the nucleus?

  • In fixed orbits (correct)
  • In circular waves
  • In elliptical paths
  • In random directions

What effect do the forces exerted by the nucleus and the centrifugal force have on electrons?

  • They cause electrons to orbit the nucleus (correct)
  • They cause electrons to gain energy
  • They pull the electrons into the nucleus
  • They cancel each other out

What did the atomic spectra reveal about elements?

<p>They have unique spectral lines (D)</p> Signup and view all the answers

What happens to an electron moving in an orbit according to Maxwell's theory?

<p>It loses energy and spirals into the nucleus (D)</p> Signup and view all the answers

How was the line spectrum of an element obtained?

<p>By heating the element or using electric discharge (C)</p> Signup and view all the answers

What does the term 'negligible mass' refer to in the context of electrons?

<p>Electrons have mass that can generally be ignored compared to that of the nucleus (A)</p> Signup and view all the answers

What primarily constitutes the mass of an atom?

<p>Protons and neutrons in the nucleus (B)</p> Signup and view all the answers

What is the visible part of the light analyzed using an optical analyzer called?

<p>Visible spectrum (B)</p> Signup and view all the answers

What is the primary limitation of the Bohr model regarding electron movement?

<p>It allows for precise measurement of electron speed and location. (D)</p> Signup and view all the answers

Which type of atomic spectrum appears as black lines in a continuous spectrum?

<p>Absorption spectrum (C)</p> Signup and view all the answers

What does Bohr's model suggest about the energy levels of electrons in an atom?

<p>Energy levels are fixed and quantized. (D)</p> Signup and view all the answers

What concept did Bohr introduce to explain the energy levels of electrons?

<p>Quantum numbers (B)</p> Signup and view all the answers

Which statement describes a key feature of Sommerfeld's atomic model compared to Bohr's?

<p>It introduces sub-levels for energy levels. (A)</p> Signup and view all the answers

How many maximum energy levels are there in an atom in its ground state according to Bohr's model?

<p>Seven (D)</p> Signup and view all the answers

What happens to an excited electron after it gains energy?

<p>It returns to its original level, emitting energy as radiation. (B)</p> Signup and view all the answers

What happens to the energy difference between levels as an electron moves away from the nucleus?

<p>It decreases. (B)</p> Signup and view all the answers

How did Sommerfeld modify Bohr’s theory regarding electron orbits?

<p>Orbits were allowed to be oval in shape. (D)</p> Signup and view all the answers

What observation led Bohr to develop his atomic model?

<p>The spectrum produced by heating hydrogen. (C)</p> Signup and view all the answers

According to Bohr's model, what role do centrifugal and attraction forces play in an atom?

<p>They help electrons revolve around the nucleus. (B)</p> Signup and view all the answers

What is a consequence of the Bohr model for electron energy transitions?

<p>Radiation occurs only in the form of individual spectral lines. (A)</p> Signup and view all the answers

What phenomenon did Bohr's model successfully explain?

<p>The hydrogen atom spectrum (D)</p> Signup and view all the answers

What is a quantum in the context of Bohr's atomic model?

<p>The amount of energy gained or lost during an electron's transition. (B)</p> Signup and view all the answers

What is the significance of the new quantum number introduced by Sommerfeld?

<p>It denotes the energy of sub-level orbits. (B)</p> Signup and view all the answers

What equation did Summerfield use to determine the value of the orbital axis length?

<p>K = n - 1 (D)</p> Signup and view all the answers

What describes the wave nature of an electron according to de Broglie?

<p>Every moving body is associated with wave motion. (C)</p> Signup and view all the answers

According to Heisenberg’s uncertainty principle, what is true about an electron's position and velocity?

<p>Both cannot be known at the same time. (A)</p> Signup and view all the answers

What concept was introduced to represent the region where an electron is likely to be found?

<p>Orbital (B)</p> Signup and view all the answers

What is the primary difference between electromagnetic waves and matter waves?

<p>Separation from the moving body (C)</p> Signup and view all the answers

What did Schrödinger's wave equation help to determine?

<p>The allowed energy levels of the electron (A)</p> Signup and view all the answers

What is described as 'electron clouds'?

<p>Areas where the electron has a high probability of being found (A)</p> Signup and view all the answers

How does the speed of matter waves compare to electromagnetic waves?

<p>They travel slower than electromagnetic waves. (D)</p> Signup and view all the answers

What does the principal quantum number (n) indicate?

<p>The distance of the electron from the nucleus (B)</p> Signup and view all the answers

How many electrons can the 3rd energy level hold?

<p>18 (D)</p> Signup and view all the answers

What is the maximum number of sublevels in the 4th energy level?

<p>4 (B)</p> Signup and view all the answers

Which quantum number represents the number of orbitals in an energy sublevel?

<p>Magnetic quantum number (m) (D)</p> Signup and view all the answers

What symbol is assigned to the first sublevel of the first energy level?

<p>1s (C)</p> Signup and view all the answers

What is the value of the subsidiary quantum number (L) for the 4th energy level?

<p>3 (C)</p> Signup and view all the answers

How many directions does the s sublevel have?

<p>1 (D)</p> Signup and view all the answers

What does the formula m = 2l + 1 calculate?

<p>The number of orbitals in a sublevel (A)</p> Signup and view all the answers

How many orbitals are present in the d sublevel?

<p>5 (C)</p> Signup and view all the answers

What is the correct order of energy levels for electronic configuration?

<p>1s &lt; 2s &lt; 2p &lt; 3s &lt; 3p &lt; 4s &lt; 3d &lt; 4p &lt; 5s (D)</p> Signup and view all the answers

Which of the following statements reflects Hund's Rule?

<p>No electron pairing occurs until each orbital has one electron. (A)</p> Signup and view all the answers

What are the possible values of the spin quantum number?

<p>+1/2 and -1/2 (D)</p> Signup and view all the answers

What geometric shape do the p orbitals represent?

<p>Dumbbell-shaped (C)</p> Signup and view all the answers

What principle dictates that lower energy sub-levels must be filled first?

<p>Building-up Principle (D)</p> Signup and view all the answers

Which orbitals come after the 3d orbitals in the sequence of electron filling?

<p>5s (B)</p> Signup and view all the answers

How many orbitals does the f sublevel have?

<p>7 (B)</p> Signup and view all the answers

Flashcards

What is the nucleus of an atom?

The positively charged central core of an atom, containing protons and neutrons. Most of the atom's mass is concentrated in the nucleus.

What are electrons?

The negatively charged particles that orbit the atom's nucleus. They have negligible mass compared to the nucleus.

What is the attraction force between the nucleus and electrons?

The force that pulls electrons towards the nucleus due to their opposite charges.

What is the centrifugal force acting on electrons?

The force that pushes electrons away from the nucleus due to their circular motion.

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What is Rutherford's nuclear model of the atom?

A model of the atom proposed by Rutherford, suggesting that the atom has a small, dense, positively charged nucleus at the center, with negatively charged electrons orbiting around it.

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What is an atomic spectrum?

A unique set of colored lines observed when an element's atoms are heated or energized, representing the specific wavelengths of light emitted by them. Each element has its own distinct line spectrum.

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What is Bohr's theory of atomic spectra?

It stated that electrons could only occupy specific orbits around the nucleus, each with a fixed energy level. Transitions between these orbits resulted in the emission or absorption of specific wavelengths of light, explaining atomic spectra.

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Why is the study of atomic spectra important?

The study of the properties of light emitted or absorbed by atoms, providing crucial insights into the structure and behavior of atoms.

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Linear Emission Spectrum

The specific colors (or wavelengths) of light emitted by an excited element, appearing as distinct lines against a dark background.

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Linear Absorption Spectrum

Dark lines appearing at specific wavelengths within a continuous spectrum, indicating wavelengths that have been absorbed by an element.

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Bohr's Atomic Model

Bohr's model described the atom as having a positively charged nucleus surrounded by electrons orbiting in specific energy levels.

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Bohr's Postulates (Energy Levels)

Electrons can only exist in specific energy levels around the nucleus, and can jump between these levels by absorbing or releasing energy.

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Bohr's Postulates (Orbital Stability)

Electrons orbiting the nucleus don't lose energy continuously, but only when transitioning between energy levels.

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Quantum

The amount of energy absorbed or released when an electron jumps between energy levels.

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Excitation

The process where an electron absorbs energy and jumps to a higher energy level.

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De-excitation

The process where an excited electron releases energy and returns to a lower energy level, emitting light of a specific wavelength.

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Principal Quantum Number (n)

Describes the distance of an electron from the nucleus.

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Energy Levels or Electron Shells

Represents the different energy levels within an atom.

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Subsidiary or Azimuthal Quantum Number (l)

Indicates the shape of an electron's orbital.

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Energy Difference in Electron Shells

The difference in energy between electron shells is not equal. This energy difference decreases as you move further from the nucleus.

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Magnetic Quantum Number (ml)

Determines the number of orbitals within a sublevel and their orientation in space.

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Electron Cloud

The region of space surrounding the nucleus where there's a high probability of finding an electron.

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Quantum Jumps

An electron can only move between energy levels by absorbing or emitting a specific amount of energy equal to the difference between the two levels.

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Orbital

A specific region within the electron cloud where there's a high probability of finding a single electron.

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Successes of the Bohr Model

The Bohr model successfully explained the spectrum of the hydrogen atom. It introduced quantum numbers to describe electron energy levels and explained why electrons don't radiate energy in the ground state.

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Bohr's Postulate: Energy Levels

States that electrons can only exist in specific energy levels around the nucleus.

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Limitations of the Bohr Model

The Bohr model failed to explain the spectra of other elements beyond hydrogen. It treated electrons as particles without wave properties and assumed that both position and velocity could be measured simultaneously.

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Sommerfeld Atomic Model

Sommerfeld improved the Bohr model by introducing elliptical orbits for electrons. Each energy level has multiple sub-levels, with one circular orbit and the rest elliptical.

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Azimuthal Quantum Number

To describe the energy of an electron in an elliptical orbit, Sommerfeld introduced a new quantum number called the azimuthal, or orbital, quantum number (K). It quantifies the energy of electrons in sub-levels.

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Elliptical Orbit Speed

Electrons in elliptical orbits move at different speeds, travelling faster when closer to the nucleus.

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Fine Structure of Spectral Lines

Each spectral line in a hydrogen atom spectrum actually consists of multiple closely spaced spectral lines, indicating that energy levels have sub-levels.

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Oval Orbit Equation

Describes the relationship between the major and minor axes of an oval orbit, using the values 'n' and 'K'.

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Heisenberg's Uncertainty Principle

A principle in quantum mechanics stating that it's impossible to know both the exact position and momentum (velocity) of an electron at the same time.

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Electron Clouds & Orbitals

Regions around the nucleus where there is a high probability of finding an electron. They are described by specific energy levels and shapes, represented by quantum numbers.

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Quantum Numbers

A set of four numbers that describe the state of an electron in an atom: principal quantum number (n), azimuthal quantum number (l), magnetic quantum number (ml), and spin quantum number (ms).

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Wave-particle Duality of Electrons

The idea that electrons exhibit wave-like behavior, implying they can be both particles and waves.

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Schrödinger's Equation

Schrödinger's equation describes the wave-like behavior of electrons in atoms, allowing us to determine their energy levels and orbitals.

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Quantized Energy Levels

The idea that electrons can only occupy certain energy levels, like steps on a staircase, not continuously varying.

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Quantum Mechanical Model of the Atom

A theoretical model where electrons are constantly moving around the nucleus in specific orbitals, based on their energy levels and shapes.

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What is a P sublevel?

A sublevel with 3 orbitals, each having a specific shape and orientation in space. They are labeled as Px, Py, and Pz and resemble dumbbells.

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What is a D sublevel?

A sublevel with 5 orbitals, each having a unique shape and orientation. These orbitals are more complex than 'p' orbitals and have various shapes.

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What is an F sublevel?

A sublevel with 7 orbitals, each with a distinct shape and spatial orientation. These orbitals are even more complex than 'd' orbitals.

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What is the Aufbau principle?

Electrons can only occupy specific energy levels around the nucleus, and they fill up orbitals with lower energy levels first. This rule helps determine the electron configuration of an atom.

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What is Hund's rule?

This rule states that electrons will individually occupy each orbital within a sublevel before pairing up in any one orbital. This minimizes electron-electron repulsion.

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What is the spin quantum number (ms)?

This is the quantum number that describes the direction of an electron's spin as it orbits the nucleus. It can be either +1/2 or -1/2, representing clockwise or counterclockwise spin.

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What is electron spin?

This refers to the number of ways an electron can spin around its axis. This spin creates a magnetic field, and electrons in the same orbital spin in opposite directions to minimize repulsion.

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What is an orbital diagram?

A diagram showing the filling of orbitals in an element's electronic configuration. It helps visualize the distribution of electrons among various atomic orbitals.

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Study Notes

Atomic History

  • Democritus (400 BC): First to use the term "atom" (indivisible). He theorized that matter could be divided into fundamental units.
  • Aristotle (350 BC): Proposed that matter was composed of four elements: earth, fire, water, and air.
  • John Dalton (1800s): Adapted Democritus' theory to create the first modern atomic model.

Dalton's Atomic Model

  • Atoms are solid spheres.
  • All atoms of an element have the same properties (size, mass, shape).
  • Atoms of different elements have different properties.
  • Atoms combine to form compounds.

J.J. Thomson's Model

  • Discovered the electron using cathode ray tube experiments.
  • Proposed an atomic model where negative electrons are embedded in a positively charged sphere (plum pudding model).

Rutherford's Model

  • Performed gold foil experiments using alpha particles to test Thomson's model.
  • Results showed most of the atom is empty space, with a dense, positively charged nucleus at the center.
  • Alpha particles were deflected by the positive nucleus.

Bohr's Model

  • Based on the observation of hydrogen's spectrum (light emitted when heated).
  • Proposed that electrons orbit the nucleus in specific energy levels.
  • Electrons do not radiate energy while in stable orbits.
  • Electrons can only gain or lose energy by jumping between energy levels.

Sommerfeld's Model

  • Improved Bohr's model by proposing that electron orbits can be elliptical, not just circular.
  • Introduced subsidiary quantum numbers to explain the split spectral lines.
  • Explained that electrons in an orbital can have different energies (sublevels).

Wave Nature of Electron

  • De Broglie proposed that electrons exhibit wave properties as well as particle properties.
  • Electrons are considered to exist within orbitals.

Heisenberg's Uncertainty Principle

  • It's impossible to know both the position and momentum of an electron precisely.

Schrodinger's Model

  • Developed a wave equation to describe the electron's wave-like behavior in an atom.
  • Replaced the concept of fixed electron orbits with electron clouds (probability of finding an electron).

Quantum Numbers

  • Describe the properties of atomic orbitals (e.g., energy level, shape, orientation in space).
    • Four types of quantum numbers:
      • Principle Quantum Number (n): Describes the energy level and distance from the nucleus.
      • Subsidiary Quantum Number (l): Defines the shape of the orbital.
      • Magnetic Quantum Number (ml) : Defines the orientation of the orbital in space.
      • Electron Spin Quantum Number (ms): Describes the electron spin direction.

Hund's Rule

  • No electron pairing occurs in a sublevel until each orbital contains one electron (with the same spin direction).

Building-up Principle

  • Electrons first fill the lower energy levels and orbitals before filling higher ones.

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