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Questions and Answers
What happens to atomic radius across a period and down a group?
Atomic radius decreases across a period from left to right and increases down a group from top to bottom.
How does ionization energy change across periods and down groups?
Ionization energy increases across a period from left to right and decreases down a group from top to bottom.
Define electronegativity and its trend in the periodic table.
Electronegativity is the ability of an atom to attract electrons. It increases across a period from left to right and decreases down a group.
What is electron affinity and how does it change across terms in the periodic table?
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Explain the relationship between cations and ionic radius.
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Describe the trend in melting and boiling points from group I to IV.
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What is electropositivity and how does it vary in the periodic table?
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What is the valence electron configuration for alkali metals?
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How does the ionic radius of non-metals change across periods?
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Explain the trend in ease of formation of ions for non-metals across periods.
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What similarities exist between lithium and magnesium regarding their chemical properties?
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How does the metallic character change down the groups of the periodic table?
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What is the electron gain trend for halogens as you move down the group?
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Describe the trend in chemical reactivity for alkaline earth metals down the group.
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What characteristic do Beryllium and Aluminium share that illustrates diagonal relationships?
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How does the ionization energy trend across periods affect non-metals?
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What is the trend of ionic radius across the periodic table?
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How does the melting point change from Group I to Group III?
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Describe the trend in chemical reactivity for non-metals across periods.
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What happens to electron affinity across the periodic table?
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How does atomic size change as you go down a group in the periodic table?
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Explain the trend of ionization energy across the periodic table.
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What is the relationship between electronegativity and reactivity of non-metals?
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Describe the changes in thermal stability of compounds from Groups I to VII.
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Study Notes
Atomic Properties
- Electronegativity is an atom's ability to attract electrons and become negatively charged.
- Electropositivity is an atom's ability to lose electrons and become positively charged.
- Electron Affinity is the energy change when one mole of electrons is added to one mole of gaseous atoms to form negative ions.
- Atomic Radius decreases across periods from left to right, but increases down groups from top to bottom.
- Ionization Energy increases across periods from left to right, but decreases down groups from top to bottom.
- Electronegativity increases across periods from left to right, but decreases down groups from top to bottom.
- Electropositivity decreases across periods from left to right, but increases down groups from top to bottom.
- Electron Affinity decreases across periods and generally increases down groups.
- Ionic radius decreases for metals across periods and increases for non-metals. Ionic radius generally increases down groups and decreases across periods.
- Cations are smaller than the neutral atom they are formed from, while anions are larger than the neutral atom.
- The larger the charge on a cation, the smaller the ionic radius. The larger the charge on an anion, the larger the ionic radius.
Trends in Atomic Properties
- Ionization Energy increases across periods and decreases down groups.
- Atomic Radius decreases across periods and increases down groups.
Variation in Physical Properties
- Melting Point and Boiling Point increase across periods for Group I-III elements, with Group IV elements having the highest values. The trend then decreases for Group V-VII elements. Melting and boiling points decrease down groups for Group I-IV elements, but increase down groups for Group V-VII elements.
- Ease of Ion Formation decreases across the periods from Group I-III for metals, and increases for non-metals from Group IV-VII. Ease of ion formation increases down the groups for metals and decreases for non-metals.
Diagonal Relationship in Properties
- Diagonal relationships exist between pairs of diagonally adjacent elements in the second and third periods (e.g., Li and Mg, Be and Al, B and Si).
- The chemistry of a second-period element often has similarities to the chemistry of the third-period element one column to the right.
- Charge density is a factor in the diagonal relationship.
Examples of Li-Mg Diagonal Relationship
- Lithium and Magnesium form normal oxides, while Sodium forms peroxide and superoxides.
- Lithium is the only Group I element to form a stable nitride (Li3N). Magnesium and other Group II elements also form nitrides.
- Lithium trioxocarbonate (IV) and Lithium fluoride are sparingly soluble, while corresponding Group II salts are insoluble.
- Chlorides of Li and Mg are deliquescent and soluble in ethanol. Lithium chloride and magnesium chloride crystallize as hydrated salts.
Variation in Other Physical Properties
- Melting and Boiling Point trends are influenced by the strength of metallic and covalent bonding, as well as intermolecular forces of attraction.
- Electrical and Thermal Conductivity decrease across periods but increase down groups. Metals are good conductors, while non-metals are poor conductors.
Variation in Chemical Properties
- Chemical Properties of elements show periodic variation due to the number of valence electrons.
- Groups of elements within the same column have similar chemical properties due to similar valence electron configurations.
- Periods of elements within the same row have different chemical properties.
Chemical Properties Across the Periodic Table
- Chemical Reactivity: Decreases across periods for metals from Group I-III and increases for non-metals from Group IV-VII. Reactivity increases down groups for metals and decreases down groups for non-metals.
- Thermal Stability of Compounds: Decreases across periods for metals from Group I-III and increases for non-metals from Group IV-VII. Thermal stability increases down groups for metals and decreases for non-metals.
- Ease of Ion Formation: Decreases across periods for metals from Group I-III and increases for non-metals from Group IV-VII. Ease of ion formation increases down groups for metals and decreases for non-metals.
- Metallic Properties: Decrease across periods and increase down groups.
- Non-Metallic Properties: Increase across periods and decrease down groups.
Groups of Elements with Similar Properties
- Alkali Metals (Group 1)
- Alkaline Earth Metals (Group 2)
- Halogens ( Group 7)
- Noble Gases (Group 0)
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Description
Test your knowledge of atomic properties such as electronegativity, electropositivity, electron affinity, atomic radius, and ionization energy. This quiz covers key concepts and trends within the periodic table. Perfect for students studying chemistry!