Aryl Halides Definition and Preparation Quiz
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Questions and Answers

Why are aryl halides less reactive under SN2 reactions compared to alkyl halides?

  • Aryl halides form strong hydrogen bonds with the nucleophile.
  • Aryl halides do not form stable carbocations as intermediates.
  • Aryl halides have bulky groups attached to the benzene ring. (correct)
  • Aryl halides have lone pairs on the halogen atom.

Which metal is usually preferred for the preparation of bromobenzene?

  • Zinc
  • Copper
  • Iron (correct)
  • Aluminum

What is formed first when using iron in the preparation of aryl halides?

  • Iron(III) chloride
  • Iron(II) chloride
  • Iron(III) bromide (correct)
  • Iron(II) bromide

Why is 1-ethyl-2-iodobenzene classified as an aryl iodide and not an aryl halide?

<p>The iodine atom is directly attached to the benzene ring. (C)</p> Signup and view all the answers

What differentiates the reactivity of aryl halides from ordinary alkyl halides?

<p>Aryl halides undergo different mechanisms of nucleophilic substitution. (B)</p> Signup and view all the answers

Why do aryl halides not undergo SN1 reactions?

<p>Because they involve backside attack on the carbon-halogen bond. (A)</p> Signup and view all the answers

Why are aryl halides inert under SN2 conditions?

<p>The reaction goes through the plane of the benzene ring. (D)</p> Signup and view all the answers

Which type of aryl halides can undergo nucleophilic substitution reactions?

<p>Aryl halides with ortho or para nitro groups. (D)</p> Signup and view all the answers

In nucleophilic aromatic substitution reactions, which aryl halide is the most reactive?

<p>Aryl fluoride (C)</p> Signup and view all the answers

What is the order of reactivity for aryl halides in SN1 or SN2 reactions?

<p>Ar-F &gt;&gt; Ar-Cl ≈ Ar-Br ≈ Ar-I (C)</p> Signup and view all the answers

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