Approximation Methods for Stationary States
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Approximation Methods for Stationary States

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Questions and Answers

What does the condition of boundary matching ensure in the context of quantum mechanics?

  • It simplifies the wave function to a single solution.
  • It guarantees a complete wave function which is acceptable. (correct)
  • It ensures that the potential energy is constant throughout.
  • It allows for the estimation of classical turning points only.
  • When $k²(x)$ is approximated as $ ho x^n(1 + ext{terms})$, what is the significance of the term $n$?

  • It indicates the quadratic nature of the potential.
  • It specifies the required energy level for stability.
  • It is a positive integer indicating the type of turning point. (correct)
  • It determines the rate of decay of the wave function.
  • What happens to $E - V$ at the classical turning point when the origin of the x coordinate is placed there?

  • $E - V$ increases without bound as x approaches zero.
  • $E - V$ remains constant as x changes.
  • $E - V$ equals zero at that specific point. (correct)
  • $E - V$ is negative for all values of x.
  • What kind of solutions does the wave equation yield when $k²$ is approximated to its leading term?

    <p>It provides solutions that are exactly soluble.</p> Signup and view all the answers

    What potential behavior is observed when moving across a linear turning point?

    <p>The value of $k$ transitions from positive to negative.</p> Signup and view all the answers

    What is the approximation of k for small x?

    <p><em>k</em> ≈ <em>p</em>1/2 <em>x</em>1/2</p> Signup and view all the answers

    Which expression approximates u+ near x = 0?

    <p><em>u</em>+ ≈ ξ+1/2 * (ξ+1/2 * p1/2)1/3 / Γ(1/3) * x</p> Signup and view all the answers

    What condition must be met for u+ and u- to smoothly join together?

    <p><strong>C</strong>+ = <strong>C</strong>- + <strong>C</strong>+</p> Signup and view all the answers

    How are suitable linear combinations of u+ and u- utilized?

    <p>To create particular solutions with specified asymptotic properties.</p> Signup and view all the answers

    What does the combination (u+ + u-) exhibit as x goes into the interior of the class?

    <p>It decreases exponentially.</p> Signup and view all the answers

    Study Notes

    Approximation Methods for Stationary States

    • Asymptotic solutions valid far from classical turning points, demanding slow variations of potential.
    • Complete wave functions require matching solutions across turning point boundaries.
    • Near a turning point at energy E, the coordinates can be set so that (E - V) = 0, with a Taylor expansion approximating k²(x).
    • The equation d²u/dx² + pxⁿu = 0 has exact solutions expressed in terms of Bessel functions.
    • Modified equations arise if k²(x) does not fit the exact polynomial form.
    • Small x approximations allow effective use of solutions around turning points.

    Linear Turning Points

    • Linear turning points characterize energy-derived variations of (E - V) or k² with linear dependencies.
    • Solutions transition from positive to negative regions with changing k and ξ values.
    • For x > 0 (E > V), k is approximated, allowing smooth joins of positive and negative solutions at x = 0.
    • Conditions for smooth joining involve specified linear combinations ensuring continuity in values and derivatives.

    WKB Approximation

    • Semi-classical approximation useful for solving differential equations of the form du/dx² + Q(x)u = 0.
    • Its efficacy increases as ℏ approaches zero, connecting to Bohr-Sommerfeld quantum rules.
    • The WKB solution performs in three key stages: generates series approximations, derives near turning point solutions, and applies boundary conditions.
    • d²u/dx² + (2m(E - V)/ℏ²)u = 0 results in solutions forming oscillatory behaviors linked to energy levels.

    Wave Function Behavior

    • u(x) can be expressed in terms of amplitude A(x) and phase S(x), yielding conditions on potential energy variations.
    • The approach leads to results that align with classical mechanics, including de Broglie wavelength associations with momentum.
    • Consistency across turning points necessitates comparing integral expressions, establishing integer relationships for quantization.

    Boundary Conditions and Potential

    • Wave function expressions relate to classical turning points; conditions include the integral formulation over positive and negative regions.
    • Integration must yield consistent results linking wave functions across defined boundaries, reinforcing quantum states and energy levels.
    • The Bohr-Sommerfeld condition links the momentum integral to quantized energy states.

    Radial Wave Equation

    • The radial wave function derived from spherical symmetry maintains similarity to one-dimensional potential solutions.
    • Appropriate transformations prepare boundary conditions for treatment, aligning the wave functions with those from previous approximations.
    • Specifically defined limits (s₁, s₂) allow approximation of potential wells analogous to one-dimensional cases.

    Problems for Practice

    • A series of complex problems focuses on potential energy differences in finite nuclei, relativistic particle scenarios, and harmonic oscillators.
    • Encourages application of methods like perturbation theory and variation methods in estimating ground state energies for different systems.
    • Examines the effects of external magnetic fields and deviations in potential shapes on overall energy distributions and wave functions.

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    Description

    This quiz explores approximation methods for stationary states in quantum mechanics. It covers asymptotic solutions, wave function matching across turning points, and the role of linear turning points in energy variations. Dive deep into the mathematical descriptions and techniques applicable to wave functions near turning points.

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