AP Chemistry Units 1-4 and Unit 6 Quizzes
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Questions and Answers

Which of the following lists the samples in order of increasing number of moles in the sample?

  • NaCl < KBr < KCl
  • KCl < NaCl < KBr
  • NaCl < KCl < KBr
  • KBr < KCl < NaCl (correct)
  • In addition to Avogadro's number, which of the following must the student know to determine the number of molecules in a pure solid sample?

  • Molar mass of the compound (correct)
  • Density of the compound
  • Temperature of the sample
  • Volume of the sample
  • Which numerical expression gives the number of particles in 2.0g of Ne?

    (2.0g/20.18 g/mole)(6.0x10^23 particles/mol)

    The mass spectrum of the element Sb is most likely represented by which of the following?

    <p>Graph with amu lines at 121 and 123</p> Signup and view all the answers

    Which element has the mass spectrum represented above?

    <p>Mo</p> Signup and view all the answers

    The peak at 26 amu in the mass spectrum represents an isotope of which element?

    <p>Mg with 14 neutrons</p> Signup and view all the answers

    What is the formula unit of each compound with different ionic compounds containing copper and chlorine?

    <p>What is the formula unit of each compound?</p> Signup and view all the answers

    Which sample has the higher purity based on percent by mass of chlorine?

    <p>Which sample has the higher purity?</p> Signup and view all the answers

    Which has the greater molar mass, X or Z?

    <p>Which has the greater molar mass?</p> Signup and view all the answers

    What information could be used to determine which mixture has the higher proportion of KCl?

    <p>The mass of Cl in each mixture</p> Signup and view all the answers

    Which columns provide all the information necessary to determine the mole ratio of Ca to Mg in the rock?

    <p>3, 4, 6, 7</p> Signup and view all the answers

    What quantities are needed to determine if the sample is pure MgCl2?

    <p>The mass of Mg and the mass of Cl in the sample</p> Signup and view all the answers

    Which ground-state electron configuration represents the atom with the lowest first-ionization energy?

    <p>1s2-2s2-2p6-3s1</p> Signup and view all the answers

    What is the ground-state electron configuration of the F− ion?

    <p>1s2-2s2-2p6</p> Signup and view all the answers

    What represents the ground-state electron configuration for an atom of selenium?

    <p>1s2-2s2-2p6-3s2-3p6-4s2-3d10-4p4</p> Signup and view all the answers

    Which electron configuration is consistent with the complete photoelectron spectrum?

    <p>1s2-2s2-2p6-3s2-3p3</p> Signup and view all the answers

    What observation would provide evidence that the spectrum is consistent with the atomic model?

    <p>In its compounds, the element tends to form ions with a charge of +1.</p> Signup and view all the answers

    How is the photoelectron spectrum consistent with the electron shell model of the atom?

    <p>The electrons in the 2p sublevel have the smallest binding energy.</p> Signup and view all the answers

    Study Notes

    Moles and Sample Masses

    • In comparing 1g samples of NaCl, KBr, and KCl, the order of increasing number of moles is KBr < KCl < NaCl.
    • To determine the number of molecules in a pure solid compound, knowledge of molar mass and mass of the sample is essential.
    • The calculation for the number of particles in 2.0g of Ne involves using the formula: (2.0g/20.18 g/mole) × (6.0 × 10^23 particles/mol).

    Mass Spectrum Analysis

    • The mass spectrum of antimony (Sb) shows peaks at atomic mass units (amu) 121 and 123.
    • Molybdenum (Mo) is identified as having a mass spectrum aligning with these amu values.
    • The presence of a peak at 26 amu in a mass spectrum indicates an isotope of magnesium (Mg) with 14 neutrons.

    Ionic Compound Analysis

    • An elemental analysis of two copper-chlorine ionic compounds can help determine their formula units based on differences observed.
    • Measuring the percent by mass of chlorine in two NaCl samples helps identify which has higher purity if KCl is the only contaminant.
    • Comparing the mass of residues after heating two unknown alkali metal chlorates allows determination of which compound has a greater molar mass between X and Z.

    Mixtures and Composition

    • Analysis of two 10g mixtures of NaCl and KCl can determine which has a higher proportion of KCl by assessing the mass of Cl in each.
    • The mole ratio of calcium to magnesium in a mixed carbonate rock is derived from specific columns in a lab analysis table (3, 4, 6, 7).
    • For assessing purity in a 5.0g sample of MgCl2, knowledge of both the mass of Mg and the mass of Cl is crucial.

    Electron Configurations

    • The lowest first-ionization energy corresponds to the ground-state electron configuration of 1s²-2s²-2p⁶-3s¹.
    • The electron configuration of the F⁻ ion is represented as 1s²-2s²-2p⁶.
    • Selenium's ground-state electron configuration is illustrated as 1s²-2s²-2p⁶-3s²-3p⁶-4s²-3d¹⁰-4p⁴.

    Photoelectron Spectroscopy

    • An element's complete photoelectron spectrum can be consistent with the electron configuration of 1s²-2s²-2p⁶-3s²-3p³.
    • If an element tends to form ions with a +1 charge, this provides evidence that its spectrum aligns with known atomic models.
    • In the case of nitrogen, its photoelectron spectrum demonstrates that electrons in the 2p sublevel have the lowest binding energy.

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    Test your knowledge of key concepts in AP Chemistry with these quizzes covering Units 1-4 and Unit 6. Each question dives into core ideas, such as molar relationships and the properties of compounds. Perfect for reinforcing your understanding and exam preparation.

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