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Questions and Answers
A weak acid is one for which the equilibrium lies far to the right.
A weak acid is one for which the equilibrium lies far to the right.
False
Phosphoric acid (H3PO4) is an example of a strong acid.
Phosphoric acid (H3PO4) is an example of a strong acid.
False
A strong conjugate base is formed from a weak acid.
A strong conjugate base is formed from a weak acid.
True
PH = -log [OH-] for a strong acid.
PH = -log [OH-] for a strong acid.
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The pH of a 0.10M solution of HCl is 2.
The pH of a 0.10M solution of HCl is 2.
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The pH of a 0.10M solution of H2SO4 is -log[0.2].
The pH of a 0.10M solution of H2SO4 is -log[0.2].
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The concentration of H+ in an aqueous solution with an OH- concentration of 1.2 x 10-6 M is 8.3 x 10-7.
The concentration of H+ in an aqueous solution with an OH- concentration of 1.2 x 10-6 M is 8.3 x 10-7.
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The pH of an aqueous solution with an OH- concentration of 1.2 x 10-6 M is 7.1.
The pH of an aqueous solution with an OH- concentration of 1.2 x 10-6 M is 7.1.
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A weak acid dissociates completely into ions.
A weak acid dissociates completely into ions.
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The conjugate base of a weak acid is always weak.
The conjugate base of a weak acid is always weak.
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Study Notes
Volumetric Analysis
- Volumetric analysis is a type of analytical chemistry that deals with the measurement of the volume of a solution required to react completely with a known volume of another solution.
- Problems in volumetric analysis include calculating the mole fraction of a substance in a solution, determining the normality of a solution, and expressing the concentration of a solution in different units.
Mole Fraction and Molarity
- The mole fraction of a substance in a solution is the ratio of the number of moles of the substance to the total number of moles of all substances in the solution.
- The molarity of a solution is the number of moles of solute per liter of solution.
Normality and Molarity
- The normality of a solution is the number of equivalents of solute per liter of solution.
- Normality is related to molarity by the formula: Normality = Molarity x Number of equivalents per mole.
Concentration Units
- Concentration units include g/L, ppm, and ppb.
- ppm (parts per million) is a unit of concentration that represents the number of parts of a substance per million parts of a solution.
- ppb (parts per billion) is a unit of concentration that represents the number of parts of a substance per billion parts of a solution.
Acids and Bases
- Acids are substances that donate a proton (H+), while bases are substances that accept a proton.
- The Arrhenius theory of acids and bases defines acids as substances that increase the concentration of H+ in a solution, and bases as substances that increase the concentration of OH- in a solution.
Bronsted-Lowry Theory
- The Bronsted-Lowry theory of acids and bases defines an acid as a substance that donates a proton, and a base as a substance that accepts a proton.
- This theory is an improvement over the Arrhenius theory because it can explain the behavior of acids and bases in non-aqueous solutions.
Lewis Theory
- The Lewis theory of acids and bases defines an acid as a substance that accepts an electron pair, and a base as a substance that donates an electron pair.
- This theory is more general than the Bronsted-Lowry theory because it can explain the behavior of acids and bases in a wide range of solutions.
Leveling Effect
- The leveling effect is the phenomenon where the strength of an acid is determined by the solvent in which it is dissolved.
- In a solvent such as water, the leveling effect causes strong acids to be completely dissociated, while weak acids are only partially dissociated.
Acid Strength
- The strength of an acid is defined by the equilibrium position of its dissociation reaction.
- A strong acid is one that is completely dissociated in a solvent, while a weak acid is one that is only partially dissociated.
pH Calculation
- The pH of a solution is calculated using the formula: pH = -log[H+].
- The pH of a strong acid solution can be calculated using the formula: pH = -log[Concentration of acid].
- The pH of a weak acid solution can be calculated using the formula: pH = -log[Concentration of acid] + pKa.
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Description
This quiz covers volumetric analysis in analytical chemistry, with questions on weak acids and mole fractions. Prepared by Dr. Ahmed Bahgat.