Alkynes: Addition Reactions and Bond Energies

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Why do alkynes readily undergo addition reactions?

Because the pi bonds of alkynes are electron-rich, like alkenes

Why are the reactions of alkynes usually exothermic?

Sigma bonds are generally stronger than pi bonds

How many pi bonds do alkynes have?

Two

Why should we consider the possibility of double addition when a reagent adds across the triple bond of an alkyne?

Because alkynes have two pi bonds

Under what conditions might a reaction across the triple bond of an alkyne stop after a single addition?

Specific reaction conditions

Alkynes have a higher bond energy than alkenes.

True

Pi bonds in alkynes are electron-poor.

False

Alkynes can only have one molecule add across the triple bond.

False

Reactions across the triple bond of an alkyne never result in double addition.

False

Sigma bonds are generally weaker than pi bonds in alkynes.

False

Learn about the similarities between the reactions of alkynes and alkenes, focusing on addition reactions and bond energies. Understand the exothermic nature of these reactions and the potential for up to two molecules to add across the triple bond in alkynes.

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