Alfred Werner's Coordination Compounds

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Questions and Answers

Who was the first chemist to formulate ideas about the structures of coordination compounds?

  • Dmitri Mendeleev
  • Louis Pasteur
  • Alfred Werner (correct)
  • Marie Curie

What did Alfred Werner propose in relation to metal ions in coordination compounds?

  • Secondary valence only
  • Both primary and secondary valence (correct)
  • Primary valence only
  • Tertiary valence

How many primary valences do CoCl2 and PdCl2 have according to Alfred Werner?

  • CoCl2 - 4, PdCl2 - 4
  • CoCl2 - 1, PdCl2 - 1
  • CoCl2 - 3, PdCl2 - 2 (correct)
  • CoCl2 - 2, PdCl2 - 3

In Werner's experiments with cobalt(III) chloride and ammonia, what was observed when excess silver nitrate was added?

<p>Some chloride ions precipitated as AgCl while some remained in solution (B)</p> Signup and view all the answers

How many moles of silver chloride (AgCl) are formed when reacting 1 mol of CoCl3.6NH3 (Yellow) according to the observations by Alfred Werner?

<p>3 mol AgCl (A)</p> Signup and view all the answers

Based on Werner's theory, how many groups remain bonded to the cobalt ion during the reaction in coordination compounds?

<p>Six groups (C)</p> Signup and view all the answers

According to Werner's theory of coordination compounds, what is the primary valence satisfied by?

<p>Negative ions (C)</p> Signup and view all the answers

What term is used for compounds like [CoCl3.4NH3] which have the same empirical formula but different properties?

<p>Isomers (A)</p> Signup and view all the answers

What is the secondary valence in coordination compounds according to Werner's theory?

<p>Non-ionisable (B)</p> Signup and view all the answers

In the context of coordination compounds, what are coordination polyhedra?

<p>Spatial arrangements around the metal ion (B)</p> Signup and view all the answers

Which geometrical shapes did Werner postulate as more common in coordination compounds of transition metals?

<p>Octahedral, tetrahedral, square planar (D)</p> Signup and view all the answers

How do double salts differ from complex ions in terms of dissociation in water?

<p>Double salts dissociate into simple ions, but complex ions do not dissociate (C)</p> Signup and view all the answers

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