Aldehydes Preparation and Properties

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Questions and Answers

What is the product formed when an aldehyde or ketone is reduced to a primary alcohol?

  • Alcohol (correct)
  • Hydrazone
  • Oxime
  • Imine

Which reagent is used in the Gatterman-Koch reaction for the preparation of aldehydes and ketones?

  • Zincamalgam
  • Sodium borohydride
  • Chromic oxide (correct)
  • Hydroxylamine

What is the product obtained from the reduction of a ketone to a secondary alcohol?

  • Hydrazone
  • Imine
  • Oxime
  • Alcohol (correct)

In the Wolff-Kishner reduction, what is the high boiling solvent used for the reduction of a carbonyl group to a CH2 group?

<p>Ethylene glycol (A)</p> Signup and view all the answers

Which method involves the preparation of aldehydes and ketones from acyl chlorides?

<p>Gatterman-Koch reaction (D)</p> Signup and view all the answers

What is the product formed when an aldehyde reacts with ammonia?

<p>Imine (A)</p> Signup and view all the answers

How are aromatic aldehydes prepared using chromyl chloride or CrO3?

<p>Oxidation of methylbenzene (A)</p> Signup and view all the answers

Which method is used for the preparation of aromatic ketones?

<p>Friedel-Crafts acylation of aromatic hydrocarbons with acyl chlorides (D)</p> Signup and view all the answers

How are ketones prepared from nitriles?

<p>Reaction with acyl chlorides (C)</p> Signup and view all the answers

What is the method for preparing aldehydes from acyl halides?

<p>Selective reduction (C)</p> Signup and view all the answers

Which reaction is involved in the Gatterman-Koch reaction?

<p>Chlorination followed by hydrolysis (B)</p> Signup and view all the answers

How are ketones prepared from acyl chlorides and anhydrides?

<p>Friedel-Crafts acylation of aromatic hydrocarbons (A)</p> Signup and view all the answers

Which method is suitable for preparing aldehydes and ketones from volatile alcohols?

<p>Dehydrogenation of alcohols (B)</p> Signup and view all the answers

Which method involves passing alcohol vapors over heavy metal catalysts to produce aldehydes and ketones?

<p>Dehydrogenation of alcohols (B)</p> Signup and view all the answers

In the Gatterman-Koch reaction, what is the role of CO and HCl?

<p>CO acts as an oxidizing agent and HCl as a reducing agent (C)</p> Signup and view all the answers

Which method involves the use of acyl chlorides to prepare ketones?

<p>Gatterman-Koch reaction (A)</p> Signup and view all the answers

How are ketones prepared from nitriles?

<p>By Gatterman-Koch reaction (D)</p> Signup and view all the answers

Which method involves the oxidation of primary and secondary alcohols to prepare aldehydes and ketones, respectively?

<p>Dehydrogenation of alcohols (D)</p> Signup and view all the answers

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