Aldehydes, Ketones, and Carboxylic Acids Chemistry Quiz

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Questions and Answers

What is the general term for compounds with a carbonyl group bonded to at least one hydrogen atom and one alkyl or aryl group?

  • Aldehydes (correct)
  • Ketones
  • Carboxylic acids
  • Esters

Which reaction involves the self-condensation of an aldehyde or a ketone followed by dehydration to give α,β-unsaturated carbonyl compound?

  • Friedel-Crafts acylation
  • Aldol condensation (correct)
  • Cannizzaro reaction
  • Esterification

Which of the following is formed when an aldehyde undergoes self-oxidation and reduction processes simultaneously in the presence of concentrated alkali?

  • Carboxylic acid
  • Alcohol
  • Ester (correct)
  • Acid chloride

Which functional group is present in acid chlorides, but absent in esters and amides?

<p>Carbonyl group (C)</p> Signup and view all the answers

Flashcards

Aldehyde

A compound with a carbonyl group (C=O) bonded to at least one hydrogen atom and one alkyl or aryl group.

Aldol Condensation

A reaction where two aldehydes or ketones react to form a larger molecule with a double bond. It involves self-condensation followed by dehydration.

Cannizzaro Reaction

A reaction where an aldehyde molecule reacts with itself, forming an ester and an alcohol. This happens in the presence of a strong base.

Acyl Chloride

A functional group containing a carbonyl group (C=O) bonded to a chlorine atom. This group is found in acid chlorides and contributes to their reactivity.

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Study Notes

Carbonyl Compounds

  • General term for compounds with a carbonyl group (C=O) bonded to at least one hydrogen atom and one alkyl or aryl group is aldehydes.
  • If the carbonyl group is bonded to two alkyl or aryl groups with no hydrogen, it is referred to as a ketone.

Reaction of Aldehydes and Ketones

  • The reaction involving the self-condensation of an aldehyde or ketone, followed by dehydration, produces α,β-unsaturated carbonyl compounds.
  • This reaction is commonly known as aldol condensation.

Special Reactions of Aldehydes

  • When an aldehyde undergoes simultaneous self-oxidation and reduction in the presence of concentrated alkali, it leads to the formation of a geminal diol or hydrate.

Functional Groups in Organic Compounds

  • Acid chlorides are characterized by the presence of a carbonyl group (C=O) combined with a chlorine atom (Cl).
  • This functional group is absent in esters and amides, which contain carbonyl groups bonded to other groups (like alkoxides in esters or amine groups in amides) instead of a chlorine atom.

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