Aldehydes, Ketones, and Carboxylic Acids Chemistry Quiz
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Questions and Answers

What is the general term for compounds with a carbonyl group bonded to at least one hydrogen atom and one alkyl or aryl group?

  • Aldehydes (correct)
  • Ketones
  • Carboxylic acids
  • Esters

Which reaction involves the self-condensation of an aldehyde or a ketone followed by dehydration to give α,β-unsaturated carbonyl compound?

  • Friedel-Crafts acylation
  • Aldol condensation (correct)
  • Cannizzaro reaction
  • Esterification

Which of the following is formed when an aldehyde undergoes self-oxidation and reduction processes simultaneously in the presence of concentrated alkali?

  • Carboxylic acid
  • Alcohol
  • Ester (correct)
  • Acid chloride

Which functional group is present in acid chlorides, but absent in esters and amides?

<p>Carbonyl group (C)</p> Signup and view all the answers

Flashcards

Aldehyde

A compound with a carbonyl group (C=O) bonded to at least one hydrogen atom and one alkyl or aryl group.

Aldol Condensation

A reaction where two aldehydes or ketones react to form a larger molecule with a double bond. It involves self-condensation followed by dehydration.

Cannizzaro Reaction

A reaction where an aldehyde molecule reacts with itself, forming an ester and an alcohol. This happens in the presence of a strong base.

Acyl Chloride

A functional group containing a carbonyl group (C=O) bonded to a chlorine atom. This group is found in acid chlorides and contributes to their reactivity.

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Study Notes

Carbonyl Compounds

  • General term for compounds with a carbonyl group (C=O) bonded to at least one hydrogen atom and one alkyl or aryl group is aldehydes.
  • If the carbonyl group is bonded to two alkyl or aryl groups with no hydrogen, it is referred to as a ketone.

Reaction of Aldehydes and Ketones

  • The reaction involving the self-condensation of an aldehyde or ketone, followed by dehydration, produces α,β-unsaturated carbonyl compounds.
  • This reaction is commonly known as aldol condensation.

Special Reactions of Aldehydes

  • When an aldehyde undergoes simultaneous self-oxidation and reduction in the presence of concentrated alkali, it leads to the formation of a geminal diol or hydrate.

Functional Groups in Organic Compounds

  • Acid chlorides are characterized by the presence of a carbonyl group (C=O) combined with a chlorine atom (Cl).
  • This functional group is absent in esters and amides, which contain carbonyl groups bonded to other groups (like alkoxides in esters or amine groups in amides) instead of a chlorine atom.

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Description

Test your knowledge of IUPAC nomenclature, general chemical reactions of aldehydes and ketones including Aldol condensation and Cannizzaro reaction, and carboxylic acids and their derivatives such as esters, acid chlorides, and amides. Explore the acidity, electrophilic substitution reactions, and other chemical properties of carboxylic acids in this quiz.

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