Air Pollution Introduction

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Questions and Answers

What constitutes an air pollutant?

  • Any matter in the atmosphere other than oxygen, nitrogen, and inert gases (correct)
  • Only naturally occurring materials in their normal concentrations
  • Only solid particles from industrial sources
  • Only gases like carbon dioxide and nitrogen

What is ambient air quality primarily concerned with?

  • The levels of pollutants found only near pollutant sources
  • The immediate emissions from industrial sources
  • The purity of air in confined spaces
  • The average purity of air in a broad area (correct)

Which of the following is NOT classified as a primary pollutant?

  • Ozone (correct)
  • Sulfur dioxide
  • Carbon monoxide
  • Lead

What are fugitive emissions?

<p>Emissions that escape during industrial processes (C)</p> Signup and view all the answers

Which pollutant is NOT among the six conventional or criteria pollutants?

<p>Volatile organic compounds (A)</p> Signup and view all the answers

What is a major natural source of sulfur dioxide in the atmosphere?

<p>Evaporation of sea spray (C)</p> Signup and view all the answers

What percentage of emissions from oil refineries and chemical plants comes from fugitive industrial emissions?

<p>90% (A)</p> Signup and view all the answers

What is the primary concern of criteria pollutants?

<p>They pose serious threats to human health and welfare. (B)</p> Signup and view all the answers

What is the primary cause of carbon monoxide (CO) production?

<p>Incomplete combustion of fuel (C)</p> Signup and view all the answers

What percentage of carbon monoxide in the atmosphere is converted to carbon dioxide (CO2)?

<p>90% (C)</p> Signup and view all the answers

How does carbon monoxide affect hemoglobin in the blood?

<p>It irreversibly binds to hemoglobin (C)</p> Signup and view all the answers

Which compounds are primarily involved in producing ground-level ozone (O3)?

<p>Nitrogen oxides and volatile organic compounds (D)</p> Signup and view all the answers

What is the primary definition of air pollution?

<p>Discharges of substances that can harm public health or the environment. (D)</p> Signup and view all the answers

What is the largest source of volatile organic compounds (VOCs)?

<p>Plants (D)</p> Signup and view all the answers

Which of the following is NOT considered a common pollutant of the air?

<p>Pesticides (D)</p> Signup and view all the answers

What is a major consequence of air pollution mentioned in the discussion?

<p>Over 3 million deaths annually (B)</p> Signup and view all the answers

Which gas is not a primary contributor to photochemical reactions producing ozone?

<p>Carbon monoxide (B)</p> Signup and view all the answers

What happens to nitrogen dioxide (NO2) during the reaction to form ozone?

<p>It is converted to nitrous oxide (NO) and Oxygen (O) (D)</p> Signup and view all the answers

Which statement best reflects the challenges involved in addressing air pollution?

<p>Widespread deaths from pollution often complicate policy initiatives. (B)</p> Signup and view all the answers

Which gas is produced by natural wetlands and is a significant contributor to greenhouse gases?

<p>Methane (CH4) (D)</p> Signup and view all the answers

Which of the following pollutants can contribute to the phenomenon referred to as 'haze'?

<p>Smoke and dust (C)</p> Signup and view all the answers

What does the term 'air resources' refer to in the context of air pollution?

<p>The overall quality and purity of the atmosphere. (A)</p> Signup and view all the answers

Which approach is NOT effective in controlling air pollution?

<p>Limiting public transportation options. (A)</p> Signup and view all the answers

What is the significance of the phrase 'Tapat ko linis ko' in the context of air pollution?

<p>It highlights the futility in addressing air pollution challenges. (B)</p> Signup and view all the answers

Which of the following sources contributes the most to airborne mercury emissions?

<p>Coal-burning power plants (B)</p> Signup and view all the answers

What is the primary form of mercury that accumulates in living animal tissues?

<p>Methyl mercury (C)</p> Signup and view all the answers

What percentage of human exposure to mercury is attributed to dietary fish consumption?

<p>75% (B)</p> Signup and view all the answers

Which metal is mentioned as being toxic in minute doses, specifically affecting young children and developing fetuses?

<p>Lead (B)</p> Signup and view all the answers

What significant event in the 1950s highlighted the dangers of mercury poisoning?

<p>Minamata disease (C)</p> Signup and view all the answers

Which seafood is NOT mentioned as a significant source of mercury in our diet?

<p>Salmon (C)</p> Signup and view all the answers

What was established as the primary cause of growing mercury emissions in the Pacific?

<p>Coal burning in China (D)</p> Signup and view all the answers

How long after the connection was established did waste dumping in Minamata Bay continue?

<p>10 years (A)</p> Signup and view all the answers

What is the approximate annual emission of CO2 from respiration?

<p>370 billion tons (C)</p> Signup and view all the answers

How much is the atmospheric level of CO2 increasing each year?

<p>0.5 percent (B)</p> Signup and view all the answers

Why are halogens commonly used in various applications?

<p>They are lightweight and highly reactive. (C)</p> Signup and view all the answers

Which greenhouse gas is noted for having a global warming potential thousands of times greater than CO2?

<p>CFCs (C)</p> Signup and view all the answers

What is a consequence of increasing atmospheric CO2 levels?

<p>Global climate change (A)</p> Signup and view all the answers

What are the six greenhouse gases that the EPA regulates?

<p>Carbon dioxide, methane, nitrous oxide, hydrofluorocarbons, perfluorocarbons, sulfur hexafluoride (B)</p> Signup and view all the answers

How long do perfluorocarbons persist in the atmosphere?

<p>Thousands of years (B)</p> Signup and view all the answers

Which of the following statements about CO2 at normal concentrations is true?

<p>It is non-toxic and innocuous. (D)</p> Signup and view all the answers

What are chlorofluorocarbons (CFCs) primarily responsible for in the atmosphere?

<p>Destroying ozone molecules (D)</p> Signup and view all the answers

Which characteristic best defines hazardous air pollutants (HAPs)?

<p>They are monitored due to their dangerous nature. (C)</p> Signup and view all the answers

Why are some hazardous air pollutants particularly dangerous?

<p>They bioaccumulate in animal and human tissues. (B)</p> Signup and view all the answers

What is a common source of aesthetic degradation in urban areas?

<p>Light pollution (B)</p> Signup and view all the answers

What has the EPA found regarding indoor air quality compared to outdoor air quality?

<p>Indoor air often has higher concentrations of pollutants. (D)</p> Signup and view all the answers

What purpose do factories spray 'odor maskants' or perfumes in smokestacks serve?

<p>To conceal objectionable odors (A)</p> Signup and view all the answers

Which type of pollutants does the category of hazardous air pollutants primarily include?

<p>Metal compounds, chlorinated hydrocarbons, or volatile organic compounds (A)</p> Signup and view all the answers

What is the primary concern associated with aesthetic degradation?

<p>It influences quality of life and may increase stress. (D)</p> Signup and view all the answers

Flashcards

Air Pollution

Any change in air's physical, chemical, or biological properties, or the release of liquids, gases, or solids that harms public health, safety, and welfare, or interferes with air resource use.

Harmful Air Substances

Examples include smoke, haze, dust, odors, corrosive gases, noise, and toxic compounds.

Global Air Pollution Deaths

Estimated at over 3 million deaths per year globally.

Air Pollution Regulation

Difficult to implement effective policies in developing countries, often due to weaker government oversight.

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Atmospheric Air

The air in the atmosphere, a thin layer around the earth.

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Public Health

The well-being of people in society, a key concern in air pollution.

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Air Resource Use

Activities like domestic, commercial, industrial, agricultural, recreational, and other legitimate purposes that can be negatively affected by pollution.

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Atmospheric Pollutant Trapping

Pollutants released enter the atmosphere and often return to the same area resulting in poor air.

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Ambient Air

The air that surrounds us, representing the general quality of the atmosphere in a broad area.

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Primary Pollutants

Pollutants released directly from a source in a harmful form.

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Secondary Pollutants

Pollutants transformed into a harmful form after entering the air or through chemical reactions.

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Fugitive Emissions

Pollutants that escape from a source without going through a smokestack, like dust from construction sites or leaks from refineries.

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Six Conventional Pollutants

These are the six major air pollutants that were addressed first due to their high volume and health risks: sulfur dioxide, nitrogen oxides, carbon monoxide, ozone, lead, and particulate matter.

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What are some natural sources of sulfur in the atmosphere?

Natural sources of sulfur in the atmosphere include evaporation of sea spray, erosion of sulfate-containing dust from arid soils, fumes from volcanoes and hot springs, and biogenic emissions of hydrogen sulfide (H2S) and organic sulfur-containing compounds.

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Sulfur Dioxide

A gas released from burning fossil fuels, volcanoes, and industrial processes, contributing to acid rain and respiratory problems.

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Ambient Air Quality

The overall level of pollution in a broad area, reflecting the average purity of the atmosphere.

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CO's effect on blood

Carbon monoxide (CO) binds to hemoglobin, preventing oxygen from attaching and being carried throughout the body.

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CO's source

Most CO comes from incomplete burning of fuels like coal, oil, and wood.

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How is CO removed?

Catalytic converters in vehicles help oxidize CO into CO2, which is less harmful.

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Ozone formation

Ground-level ozone forms when sunlight reacts with pollutants like NO2 and VOCs.

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What are VOCs?

Volatile Organic Compounds (VOCs) are organic chemicals that easily evaporate into the air.

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Largest VOC source

Plants release large amounts of VOCs, mainly isoprene and terpenes.

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Methane source

Natural wetlands, rice paddies, and animals like termites produce significant methane.

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Photochemical Oxidants

A general term for substances produced from photochemical reactions, ozone being a prime example.

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Carbon Dioxide Emission

The release of carbon dioxide gas into the atmosphere, primarily from respiration and human activities.

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CO2 and Photosynthesis

Green plants absorb carbon dioxide during photosynthesis, a process that converts light energy into chemical energy.

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CO2 Levels and Climate Change

Increasing atmospheric carbon dioxide levels contribute to global warming, with serious consequences for humans and ecosystems.

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Halogens

A group of highly reactive elements, including chlorine, fluorine, bromine, and iodine, often used in industrial and consumer products.

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Halogen Compounds and Greenhouse Effect

Halogen compounds are powerful greenhouse gases, trapping heat in the atmosphere and contributing to global warming.

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Perfluorocarbons (PFCs)

A type of halogen compound with a very long atmospheric lifetime, persisting for thousands of years.

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Global Warming Potential

A measure of a greenhouse gas's ability to trap heat in the atmosphere compared to carbon dioxide.

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CFCs and Global Warming

Chlorofluorocarbons (CFCs) have a global warming potential thousands of times greater than carbon dioxide.

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Mercury Source

Coal-burning power plants are the largest source of airborne mercury, contributing to about 70% of emissions.

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Methylmercury Formation

Aquatic bacteria convert airborne mercury into methylmercury, a highly toxic form that accumulates in fish.

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Mercury Exposure Source

Eating fish is the primary source of mercury exposure for humans, particularly seafood like swordfish and shrimp.

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Global Mercury Circulation

Air currents deposit airborne mercury worldwide, even from distant sources like Asian coal plants.

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Minamata Disease

A devastating case of mercury poisoning in Japan, causing severe neurological damage in babies and adults.

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Mercury Poisoning Symptoms

Mercury poisoning can cause neurological impairments like deafness, blindness, mental retardation, and cerebral palsy.

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Toxic Metal Release Sources

Fuel combustion, ore smelting, and waste disposal release toxic metals like lead and mercury.

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Mercury Regulation

Mercury has been recently regulated, with policies like DAO 1997-38 in the Philippines, to prevent further contamination.

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CFCs and Ozone

Chlorofluorocarbons (CFCs) release chlorine and fluorine atoms in the stratosphere, which destroy ozone molecules, reducing Earth's protection from harmful ultraviolet radiation.

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Hazardous Air Pollutants (HAPs)

These are particularly dangerous toxins monitored by the EPA. They include carcinogens, neurotoxins, mutagens, teratogens, endocrine disruptors, and other highly toxic compounds.

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Bioaccumulation of HAPs

Many HAPs persist in ecosystems, accumulate in animal and human tissues, making them especially dangerous.

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Common HAPs

Most HAPs are metal compounds, chlorinated hydrocarbons, or volatile organic compounds. Examples include gasoline vapors, solvents, and plastics.

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Aesthetic Degradation

This refers to any undesirable change in the environment's physical characteristics or chemistry, such as noise, odors, and light pollution.

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Impact of Aesthetic Degradation

While not directly threatening life or health, aesthetic degradation affects our quality of life. It can increase stress and negatively impact well-being.

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Indoor vs. Outdoor Air Quality

The EPA found that toxic air pollutants are often more concentrated indoors than outdoors, posing a greater risk to people who spend significant time inside.

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Indoor Air Pollution Sources

Indoor air often contains high concentrations of chemicals that would be illegal outdoors or in workplaces. Sources include building materials, furniture, cleaning products, and personal care products.

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Study Notes

Air Pollution Introduction

  • Air pollution is the alteration of atmospheric properties, chemically, physically, or biologically.
  • It involves discharge of substances into the air, harming public health, safety, or welfare.
  • Air pollution includes smoke, haze, dust, odors, corrosive gases, noise, and toxic compounds.

Learning Outcomes

  • Identify the various effects of air pollution.
  • Describe the role of engineers in the handling of resources/materials.
  • Identify the sources of air pollution.
  • Discuss how to control air pollution.

Air Pollutants

  • Any material in the atmosphere other than oxygen, nitrogen, water vapor, carbon dioxide, and inert gases is an air pollutant.
  • Pollutants can be detrimental to health or the environment, including smoke, dust, soot, cinders, fly ash, solid particles, gases, fumes, chemical mists, steam, and radioactive substances.

Ambient Air Quality

  • The general amount of pollution present in a broad surrounding area, and refers to the average purity of the atmosphere.

Primary Pollutants

  • These are hazardous pollutants released directly into the atmosphere from sources.

Secondary Pollutants

  • Hazardous pollutants formed from chemical reactions occurring in the air after they enter the atmosphere.

Fugitive Emissions

  • Emissions not passing through a smoke stack, but are from several sources.
  • These come from sources such as soil erosion, strip mining, rock crushing, building construction, or leaks and evaporation from oil processing facilities.

Six Conventional/Criteria Pollutants

  • Sulfur dioxide
  • Nitrogen oxides
  • Carbon monoxide
  • Ozone
  • Lead
  • Particulate matter

Sulfur Dioxide (SO2)

  • Natural sources include sea spray, erosion of soil, and volcanoes.
  • Yearly emissions are around 114 million tons, with anthropogenic sources making up 2/3 of global emissions.
  • The major source is the combustion of fossil fuels containing sulfur.
  • SO2 is a colorless corrosive gas, causing damage to plants and animals.
  • SO3 and H2SO4 form causing acid rain.

Nitrogen Oxides (NOx)

  • NOx are toxic gases produced when fuel or air is heated above 650 degrees Celsius in the presence of oxygen.
  • Bacteria oxidize nitrogen-containing compounds in soil and water to form NO.
  • NO oxidizes further in the atmosphere to form NO2 which contributes to smog.
  • Nitrous oxide (N2O) is an intermediate form.
  • NOx are important components of acid rain, contributing to global emissions close to 230 million metric tons each year.

Carbon Monoxide (CO)

  • Colorless, odorless toxic gas resulting from incomplete combustion.
  • Formed from fuel (coal, oil, charcoal, gas) and decomposition of organic materials.
  • CO binds irreversibly with hemoglobin.
  • Human activities account for about half of the CO released each year (1 billion metric tons).

Ozone (O3) and Photochemical Oxidants

  • Formed from reactions between other pollutants, primarily nitrogen oxides and volatile organic compounds (VOCs) in the presence of sunlight.
  • VOCs are organic chemicals found in plants (trees) that evaporate or turn into gases easily or naturally.
  • Sources of ozone include plants (ex. isoprene, terpenes).
  • Global emissions are estimated at 400 million tons for methane.

Lead

  • Most commonly produced metal air pollutant.
  • Lead is released from smelting of metals, mining activities, fuel combustion, or industrial processes.
  • Significantly toxic to humans and animals.

Particulate Matter

  • Solid particles and liquid droplets suspended in a gas.
  • Includes dust, ash, soot, smoke, and pollen.
  • Fine particles smaller than 2.5 micrometers (PM2.5) are harmful to lungs.
  • Concerns over the effects of these include their effect on allergies.

Other Pollutants

  • Mercury* - Toxic metal produced by burning coal, oil, mining, and manufacturing.
  • Carbon Dioxide (CO2)* - Major greenhouse gas, released through human activities.
  • Halogens* - Reactive elements contributing to greenhouse effect.
  • Hazardous Air Pollutants (HAPs)* - Dangerous toxins often monitored by the EPA.

Stratospheric Ozone

  • Ozone levels are dropping over the south pole in September/October which has been occurring since about 1960s.
  • This depletion is most greatly affected by chlorine-based aerosols. This is especially true of CFCs and other halon gases.

Acid Precipitation

  • The deposition of acidic solutions (rain, snow, or dry acidic particles) from the air.
  • Created from transportation-related pollutants (automobile exhaust) and industrial emissions.

Air Pollution Control Facilities (APCF)

  • General term for structure or installation controlling emissions from air pollution.
  • Examples include filters, scrubbers, and dust collectors.
  • Processes like particulate removal, sulfur removal, and nitrogen oxide removal, and hydrocarbon removal.

Temperature Inversions

  • Atmospheric layer of warmer air located above a layer of cooler air.
  • These prevent the dispersal of pollutants.

Indoor Air Pollution

  • Indoor air pollutant concentrations can be much higher than outdoor concentrations.
  • People spend more time indoors than outdoors.

Air Pollution- The Silent Killer

  • Air pollution is a substantial environmental risk to human health.
  • Millions die due to exposure every year.
  • Air quality reduction can be a major contributing factor to heart disease, stroke, and lung cancer, along with many other respiratory problems.

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