After-treatments of direct dyes
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Questions and Answers

What is the main purpose of after-treatments of direct dyes?

  • To decrease the molecular weight of the dye
  • To increase the solubility of the dye
  • To render the dye less soluble in water (correct)
  • To enhance the light fastness of the dye
  • Why is it important for the preliminary deposition to be achieved with a soluble and comparatively small molecule?

  • To facilitate the in situ reaction (correct)
  • To improve the color intensity of the dye
  • To prevent the dye from entering the fiber
  • To ensure easy removal of the dye
  • What group in the dye molecule allows it to be diazotized during the in situ reaction?

  • Carboxylic group
  • Primary amino group (correct)
  • Sulfonyl group
  • Phenolic group
  • In what year was the oldest method of improving fastness by an in situ reaction discovered?

    <p>1887</p> Signup and view all the answers

    Direct dyes exhibit good wet-fastness properties without any additional treatments.

    <p>False</p> Signup and view all the answers

    The oldest method of improving fastness involved diazotizing the primary amino group attached to the aromatic nucleus.

    <p>True</p> Signup and view all the answers

    What causes a complete alteration in shade when added to a dye molecule?

    <p>Chromophore</p> Signup and view all the answers

    After diazotization, the dye molecule is coupled with phenols or aromatic amines to form new azo dyes in situ on the fiber.

    <p>True</p> Signup and view all the answers

    The addition of another chromophore to the dye molecule during the in situ reaction does not affect the shade of the dye.

    <p>False</p> Signup and view all the answers

    If the dye molecule is too large, it will not enter the fiber, resulting in uneven dyeing.

    <p>True</p> Signup and view all the answers

    The preliminary deposition of the dye should be achieved with a soluble and comparatively large molecule.

    <p>False</p> Signup and view all the answers

    The diazotization reaction is carried out in a hot solution containing sodium nitrite and excess hydrochloric acid.

    <p>False</p> Signup and view all the answers

    The dye molecule Primuline, discovered by A.G. Green, exhibited good fastness to both light and washing before any after-treatments.

    <p>False</p> Signup and view all the answers

    The in situ reaction increases the molecular weight of the dye, rendering it less soluble in water and more fast to wet treatments.

    <p>True</p> Signup and view all the answers

    $\text{The primary amino group in the Primuline dye molecule is represented by the structure } -NH_2$.

    <p>True</p> Signup and view all the answers

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