Acids, Bases, and Salts Quiz
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Questions and Answers

What taste is associated with acids?

Sour

What color does blue litmus paper turn when dipped in an acid?

Red

What color does red litmus paper turn when dipped in a base?

Blue

Name a natural indicator other than litmus.

<p>Turmeric</p> Signup and view all the answers

What is the original color of litmus solution when it is neither acidic nor basic?

<p>Purple</p> Signup and view all the answers

What type of plant does litmus come from?

<p>Lichen</p> Signup and view all the answers

What are substances called that indicate the presence of acid or base?

<p>Indicators</p> Signup and view all the answers

Give an example of a synthetic indicator.

<p>Methyl orange or phenolphthalein</p> Signup and view all the answers

What happens to a curry stain on white cloth when soap is applied?

<p>It turns reddish-brown</p> Signup and view all the answers

Explain why distilled water does not conduct electricity, whereas rain water does.

<p>Distilled water is devoid of any ionic compounds, while rain water dissolves atmospheric gases, such as carbon dioxide, which form ions allowing it to conduct electricity.</p> Signup and view all the answers

A metal compound A reacts with dilute hydrochloric acid to produce effervescence. The gas evolved extinguishes a burning candle. Write a chemical equation for the reaction if one of the compounds formed is calcium chloride.

<p>CaCO3(s) + 2HCl(aq) -&gt; CaCl2(aq) + H2O(l) + CO2(g)</p> Signup and view all the answers

What is the effect of concentration of $H^{+}$(aq) ions on the nature of the solution?

<p>An increase in the concentration of $H^{+}$(aq) ions makes the solution more acidic, while a decrease in the concentration of $H^{+}$(aq) ions makes the solution more basic.</p> Signup and view all the answers

You have two solutions, A and B. The pH of solution A is 6 and pH of solution B is 8. Which solution has more hydrogen ion concentration? Which of these is acidic and which one is basic?

<p>Solution A has more hydrogen ion concentration and it is acidic. Solution B is basic.</p> Signup and view all the answers

Under what soil conditions do you think a farmer would treat the soil with quick lime (calcium oxide) or slaked lime (calcium hydroxide) or chalk (calcium carbonate)?

<p>If the soil is too acidic, a farmer would treat it with quick lime, slaked lime, or chalk to neutralize the excess acidity.</p> Signup and view all the answers

What happens when an acid or base is mixed with water?

<p>When an acid is mixed with water, it releases $H_3O^+$ ions. When a base is mixed with water, it increases the concentration of $OH^⁻$ ions.</p> Signup and view all the answers

How would you distinguish between baking powder and washing soda by heating?

<p>Baking powder, when heated, produces carbon dioxide gas, which can turn limewater milky. Washing soda does not produce carbon dioxide upon heating.</p> Signup and view all the answers

What is a neutralization reaction? Give an example.

<p>A neutralization reaction is when an acid and a base react to form salt and water. For example, $HCl(aq) + NaOH(aq) \rightarrow NaCl(aq) + H_2O(l)$.</p> Signup and view all the answers

If a family member is suffering from acidity after overeating, why is baking soda recommended as a remedy?

<p>Baking soda is a mild base that neutralizes the excess hydrochloric acid produced in the stomach, providing relief from acidity.</p> Signup and view all the answers

A white cloth has a curry stain. When soap is applied, it turns reddish-brown. Why does this happen, and what causes the stain to revert to yellow after rinsing with water?

<p>Turmeric in the curry acts as a natural indicator. Soap, being basic, changes the turmeric's color to reddish-brown. Rinsing with water removes the alkaline soap, and the turmeric reverts to its original yellow color.</p> Signup and view all the answers

Explain why diluting a strong acid is always done by slowly adding acid to water, rather than the reverse. What are the potential consequences of adding water to a concentrated acid?

<p>Adding water to a concentrated acid can cause the water to boil rapidly, splashing concentrated acid out of the container and potentially causing burns. This is due to the highly exothermic nature of the reaction, where heat is released very quickly. Adding acid to water allows the heat to be dissipated more safely.</p> Signup and view all the answers

Many metal oxides react with acids to form salt and water. Explain the chemical principle behind this reaction, and classify the nature of metal oxides based on their reactivity with acids.

<p>Metal oxides react with acids because they act as bases, neutralizing the acid to form a salt and water. This is a neutralization reaction. Metal oxides are classified as basic oxides because of their ability to neutralize acids.</p> Signup and view all the answers

Given two solutions, one with a pH of 3 and another with a pH of 6, determine how many times more acidic is the first solution compared to the second. Explain your reasoning based on the logarithmic nature of the pH scale.

<p>The solution with a pH of 3 is 1000 times more acidic than the solution with a pH of 6. This is because each unit change in pH represents a tenfold change in acidity, so a difference of 3 pH units (6-3) corresponds to $10^3$ or 1000 times more acidic.</p> Signup and view all the answers

Explain the difference between a strong acid and a weak acid in terms of their ionization in an aqueous solution. Give an example of each.

<p>A strong acid completely ionizes in an aqueous solution, meaning it dissociates fully into its ions. An example is hydrochloric acid (HCl). A weak acid only partially ionizes, meaning only some of its molecules dissociate into ions. An example is acetic acid ($CH_3COOH$).</p> Signup and view all the answers

Describe how an indicator works to signal the endpoint of a titration between a strong acid and a strong base. What properties must an indicator possess to be effective?

<p>An indicator signals the endpoint of a titration by changing color at or near the equivalence point, where the acid and base have completely neutralized each other. To be effective, an indicator must have a distinct color change within a narrow pH range that includes the equivalence point of the titration.</p> Signup and view all the answers

Explain the term 'buffer solution' and describe its importance in biological systems. Provide a specific example of a buffer system found in blood and explain how it functions.

<p>A buffer solution resists changes in pH when small amounts of acid or base are added. Buffers are crucial in biological systems to maintain a stable pH for proper functioning of enzymes and other biochemical processes. An example is the carbonic acid-bicarbonate buffer system in blood, which maintains a stable pH by neutralizing excess acids or bases: $H_2CO_3(aq) \rightleftharpoons H^+(aq) + HCO_3^-(aq)$</p> Signup and view all the answers

Explain the difference between neutralization and titration. How is titration used to determine the concentration of an unknown acid or base?

<p>Neutralization is the reaction between an acid and a base, resulting in the formation of salt and water. Titration is a laboratory technique used to determine the concentration of an unknown acid or base by gradually adding a known concentration of a base or acid until neutralization occurs, which can be identified by an indicator or pH meter.</p> Signup and view all the answers

Considering the Bronsted-Lowry definition of acids and bases, identify the conjugate acid-base pairs in the following reaction: $NH_3(aq) + H_2O(l) \rightleftharpoons NH_4^+(aq) + OH^-(aq)$.

<p>In the given reaction, the conjugate acid-base pairs are: $NH_3$ (base) and $NH_4^+$ (conjugate acid), and $H_2O$ (acid) and $OH^-$ (conjugate base). Ammonia ($NH_3$) accepts a proton to form the ammonium ion ($NH_4^+$), while water ($H_2O$) donates a proton to form the hydroxide ion ($OH^-$).</p> Signup and view all the answers

Explain why pure water is considered neutral, even though it contains both $H^+$ and $OH^-$ ions. What is the relationship between the concentrations of these ions in neutral, acidic, and basic solutions?

<p>Pure water is neutral because the concentrations of $H^+$ and $OH^-$ ions are equal ($[H^+] = [OH^-]$). In acidic solutions, $[H^+] &gt; [OH^-]$, while in basic solutions, $[OH^-] &gt; [H^+]$.</p> Signup and view all the answers

Describe the process of acid rain formation. What are the primary pollutants involved, and what are some of the environmental consequences of acid rain?

<p>Acid rain forms when pollutants like sulfur dioxide ($SO_2$) and nitrogen oxides ($NO_x$) react with water, oxygen, and other chemicals in the atmosphere to form sulfuric and nitric acids. These acids fall to the earth as acid rain, which can acidify lakes and streams, damage forests, and corrode buildings and monuments.</p> Signup and view all the answers

A chemist discovers a novel organic compound extracted from a rare deep-sea organism. Initial tests indicate the compound can act as both a Bronsted-Lowry acid and a Lewis base. Elucidate the structural features that would enable this dual functionality, and the conditions under which each activity would be favored.

<p>The compound must possess both a labile proton for Bronsted-Lowry acidity and a lone pair of electrons or pi system for Lewis basicity. Acidic activity is favored in high pH environments, basicity in low pH.</p> Signup and view all the answers

Consider a buffer solution prepared from a weak acid, $HA$, and its conjugate base, $A^-$. Derive an expression, using only fundamental constants and measurable solution parameters, to quantitatively predict the buffer capacity as a function of pH, given that buffer capacity is defined as the amount of strong acid or base (in moles) required to change the pH of the buffer by one unit.

<p>Buffer capacity $\beta = 2.303 ([H_3O^+] + [OH^-] + \frac{K_a[HA]}{([H_3O^+] + K_a)})$. It describes the effectiveness of a buffer solution in resisting changes in pH upon addition of acid or base.</p> Signup and view all the answers

A scientist synthesizes a series of novel indicators with varying degrees of electron-donating and electron-withdrawing substituents on a common chromophore. Describe how Hammett parameters could be used to quantitatively predict the shift in $pK_a$ for these indicators, and discuss the limitations of this approach in highly non-ideal solutions.

<p>Hammett parameters correlate substituent electronic effects with reaction rates/equilibria. $\Delta pK_a = \rho \sigma$, where $\rho$ is the reaction constant and $\sigma$ is the substituent constant. Limitations arise from steric hindrance and solvation effects.</p> Signup and view all the answers

You are tasked with designing a chemical sensor that utilizes a pH-responsive fluorescent dye to detect minute changes in acidity within a microfluidic device. The dye's fluorescence quantum yield is highly sensitive to protonation state. Outline a detailed experimental protocol, including specific spectroscopic techniques and calibration methods, to ensure quantitative accuracy and minimize systematic errors in the pH measurements.

<p>Use fluorescence spectrophotometry with a series of buffers covering the expected pH range for calibration. Plot fluorescence intensity vs. pH to obtain a calibration curve, correcting for inner-filter effects and photobleaching. Use the Stern-Volmer equation to account for quenching effects.</p> Signup and view all the answers

Consider an equilibrium reaction involving a weak acid, $HA$, in a non-aqueous solvent. Given that the autoprotolysis constant of the solvent is significantly different from that of water, explain how the strength of $HA$ as an acid would be affected, and predict the impact on the shape of the titration curve when titrating $HA$ with a strong base in this solvent.

<p>The strength of $HA$ depends on the solvent's ability to stabilize ions. A less polar solvent reduces ionization, weakening $HA$. The titration curve will show a less pronounced endpoint and a smaller pH change near the equivalence point.</p> Signup and view all the answers

A solution contains a mixture of three acids: a strong acid (HCl), a weak acid (acetic acid), and an extremely weak acid (phenol). Develop a detailed experimental procedure, utilizing a combination of titrimetric and spectroscopic methods, to determine the individual concentrations of each acid in the mixture with a high degree of accuracy and precision.

<p>First, titrate with a strong base to determine total acid concentration. Use a pH meter to determine the equivalence points for HCl and acetic acid. Use UV-Vis spectroscopy to quantify phenol concentration, using its molar absorptivity at a specific wavelength.</p> Signup and view all the answers

In the context of superacids (acidity exceeding that of 100% sulfuric acid), discuss the theoretical and practical limitations of using the Hammett acidity function, $H_0$, to quantify their acidity. Propose an alternative method for quantifying the acidity of superacids, particularly in non-aqueous media, and justify your choice.

<p>Hammett acidity function ($H_0$) relies on indicator protonation, which is limited by indicator basicity and solvent effects. An alternative is computational methods using density functional theory (DFT) to calculate proton affinities, providing a more direct measure of acidity.</p> Signup and view all the answers

Design a novel electrochemical cell that utilizes a redox-active indicator molecule immobilized on an electrode surface to quantitatively measure pH changes in real-time within a highly corrosive environment (e.g., concentrated hydrofluoric acid). Describe the chemical and physical properties of the indicator and electrode materials that would be essential for the sensor's long-term stability and accuracy.

<p>Use a robust electrode material (e.g., glassy carbon) coated with a chemically inert polymer containing a redox-active quinone derivative. The quinone's redox potential is pH-dependent, measured by cyclic voltammetry. Stability requires chemical inertness and strong adhesion.</p> Signup and view all the answers

A researcher is investigating the catalytic activity of a series of metal-oxide nanoparticles in promoting a specific organic reaction. It is hypothesized that the surface acidity of the nanoparticles is a critical factor influencing their catalytic performance. Describe a battery of experimental techniques that could be employed to characterize the surface acidity of these nanoparticles, distinguishing between Bronsted and Lewis acid sites and quantifying their respective concentrations.

<p>Use temperature-programmed desorption of ammonia (TPD-NH3) to quantify total acidity. Use pyridine adsorption followed by infrared spectroscopy to distinguish between Bronsted and Lewis acid sites. XPS can provide information of the oxidation states to correlate with acidity.</p> Signup and view all the answers

In the context of acid-base catalysis, explain how the concept of 'concerted proton transfer' can influence the rate-determining step of an enzymatic reaction involving multiple protonatable residues within the enzyme's active site. Provide a detailed mechanistic explanation, accompanied by a potential energy diagram, illustrating the energetic consequences of a concerted versus stepwise proton transfer mechanism.

<p>Concerted proton transfer involves simultaneous proton donation and acceptance, lowering the activation energy compared to stepwise transfer due to stabilization of the transition state. The potential energy diagram will show a single transition state for the concerted mechanism, as opposed to two for the stepwise mechanism. Tunneling may also be a factor.</p> Signup and view all the answers

What is the natural color of litmus solution when it is neither acidic nor basic?

<p>Purple</p> Signup and view all the answers

Name two natural substances, other than litmus, that can be used as acid-base indicators.

<p>Turmeric, red cabbage leaves, coloured petals of some flowers such as Hydrangea, Petunia and Geranium.</p> Signup and view all the answers

Explain why applying soap to a curry stain on white cloth causes it to turn reddish-brown.

<p>Soap is basic in nature.</p> Signup and view all the answers

What is the effect of acids on blue litmus paper?

<p>Acids turn blue litmus paper red.</p> Signup and view all the answers

If a substance is bitter in taste and turns red litmus blue, is it an acid or a base?

<p>Base</p> Signup and view all the answers

Considering the chemical properties of acids and bases, explain why baking soda solution is suggested as a remedy for acidity.

<p>Baking soda is a base and neutralizes excess acid in the stomach.</p> Signup and view all the answers

You have two solutions, A and B. Solution A has a pH of 3 and Solution B has a pH of 8. Which solution will liberate hydrogen gas on reacting with active metals like magnesium?

<p>Solution A</p> Signup and view all the answers

Describe one advantage and one disadvantage of using natural indicators like red cabbage juice, compared to synthetic indicators like methyl orange.

<p>Advantage: Natural indicators are readily available and environmentally friendly. Disadvantage: Natural indicators may not provide as sharp or distinct a color change as synthetic indicators, and might degrade more quickly.</p> Signup and view all the answers

A solution turns phenolphthalein pink. What does this indicate about the solution's pH, and why would this make it unsuitable for a titration involving a strong acid?

<p>The solution is basic. Phenolphthalein is unsuitable because it changes color in the basic range (pH 8.3-10), making it difficult to accurately determine the equivalence point with a strong acid.</p> Signup and view all the answers

A chemist mistakenly mixes a strong acid and a strong base, but forgets which is which. They perform a titration using a known concentration of sodium hydroxide ( exttt{NaOH}) and phenolphthalein as an indicator, observing a color change at a low volume of exttt{NaOH} added. However, upon repeating the experiment with methyl orange, the color change occurs immediately upon adding the first drop of exttt{NaOH}. Explain this discrepancy, and hypothesize the identity of the unknown solutions.

<p>The initial solution was likely a strong acid, contaminated with a trace amount of a volatile weak base like ammonia ($ ext{NH}_3$). The initial phenolphthalein test only detects the neutralization of the weak base due to it's high pH range, not the acidic solution. Methyl orange, with a much lower pH range, detects the strong base being added to the strong acid almost immediately.</p> Signup and view all the answers

Flashcards

Acids

Substances with a sour taste that turn blue litmus red.

Bases

Substances with a bitter taste that turn red litmus blue.

Litmus Test

A method using litmus paper to identify acids and bases.

Natural Indicators

Substances like turmeric and red cabbage used to test pH.

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Synthetic Indicators

Man-made substances like methyl orange used to identify acids/bases.

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Neutralization

The reaction between an acid and a base to cancel each other's effects.

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Turmeric as Indicator

Turmeric turns yellow in acids and reddish-brown in bases.

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Methyl Orange

A synthetic indicator that changes color at pH levels.

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Phenolphthalein

A synthetic indicator turning pink in basic solutions.

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Litmus Solution

A purple dye from lichen used to test pH.

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Acidity Problem Remedy

Baking soda neutralizes excess acidity to relieve heartburn.

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Acid Taste

Acids are known for their sour flavor.

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Base Taste

Bases are recognized for their bitter taste.

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Litmus Color Change

Blue litmus turns red in acidic solutions.

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Turmeric Indicator

Turmeric turns yellow in acidic solutions and reddish-brown in basic solutions.

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Natural Acid-Base Indicators

Substances like red cabbage and flowers that show pH levels.

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Synthetic Acid-Base Indicators

Man-made dyes like methyl orange and phenolphthalein that signal pH changes.

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Neutralization Reaction

The process where an acid and a base interact and cancel each other's properties.

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Litmus Composition

Litmus solution is made from a purple dye extracted from lichens.

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Indicators

Substances that signal whether a solution is acidic or basic.

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Litmus Color in Neutral

Litmus solution is purple when neither acidic nor basic.

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Acid-Base Reaction in Cooking

Acids and bases can neutralize flavors in cooking remedies.

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Curry Stain Change

Curry stains turn reddish-brown with soap, a base.

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Indicators from Flowers

Some colored petals act as natural indicators for pH.

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Purple Dye Resource

Litmus dye is extracted from lichens, a plant type.

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Red Cabbage Indicator

Red cabbage leaves change color, indicating pH levels.

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Baking Soda Solution

A common remedy for acidity that neutralizes stomach acid.

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Turmeric Color Change

Turmeric shows yellow in acids and reddish-brown in bases.

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Indicator Sources

Natural materials like turmeric and red cabbage indicate pH.

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Acids in Food

Substances that give food a sour taste.

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Bases in Food

Substances that impart a bitter taste.

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Natural pH Indicators

Substances from nature that indicate acidity or basicity.

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Synthetic pH Indicators

Man-made substances used to test for acids and bases.

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Litmus Solution in Neutral

Litmus solution is purple when neither acidic nor basic.

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Curry Stain Reaction

Curry stains turn reddish-brown with soap, which is basic.

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Acid-Base Neutralization

The reaction where an acid cancels the effects of a base and vice versa.

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Sour Taste of Acids

Acids are known for their characteristic sour flavor in foods.

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Bitter Taste of Bases

Bases have a characteristic bitter taste.

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Blue Litmus Test

Blue litmus paper turns red in the presence of acids.

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Red Litmus Test

Red litmus paper turns blue in the presence of bases.

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Natural Indicators Examples

Natural indicators include turmeric and red cabbage.

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Synthetic Indicators Example

Methyl orange is a synthetic indicator for pH.

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Reaction of Acids and Bases

Acids and bases neutralize each other's properties.

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Turmeric Color Reaction

Turmeric turns yellow in acidic solutions and reddish-brown in basic ones.

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Litmus Solution Color Change

Litmus solution appears purple when neutral.

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Study Notes

Acids, Bases, and Salts

  • Acids have a sour taste and turn blue litmus red.
  • Bases have a bitter taste and turn red litmus blue.
  • Litmus is a natural indicator (purple dye from lichen).
  • Turmeric is another natural indicator.
  • Synthetic indicators like methyl orange and phenolphthalein can also be used.
  • Acids and bases can neutralize each other.
  • Red cabbage leaves, petals of flowers (Hydrangea, Petunia, Geranium), and turmeric can also be used to identify acids and bases.
  • These natural indicators are called acid-base indicators or simply indicators.
  • A stain of curry on a white cloth will become reddish-brown when soap (a base) is scrubbed on it.
  • The stained cloth will turn yellow again when washed with water.
  • Lemon juice, vinegar, or baking soda solution are examples of remedies used to neutralize acidity.
  • Acids are sour in taste and change the color of blue litmus to red.
  • Bases are bitter and change the color of red litmus to blue.
  • Litmus solution, when neutral, is purple. Other natural materials like red cabbage leaves, turmeric, and colored flower petals (e.g., Hydrangea, Petunia, Geranium) can also indicate the presence of acids or bases.
  • Litmus solution is a purple dye extracted from lichen.

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Acids, Bases and Salts PDF

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Test your knowledge on acids, bases, and their properties with this engaging quiz. Learn about natural and synthetic indicators, neutralization reactions, and how to identify these chemical substances. Perfect for students studying chemistry.

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