Acids, Bases and pH

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Questions and Answers

What role do properly balanced acid and base concentrations NOT play in biological systems?

  • Facilitating enzyme activity
  • Supporting the synthesis of biopharmaceutical medicines
  • Altering the rate of nuclear decay (correct)
  • Ensuring optimal protein function

Which of the following chemical equations represents the behavior of an acid in water?

  • $NaCl \rightarrow Na^+ + Cl^-$
  • $NaOH \rightarrow Na^+ + OH^-$
  • $HCl + H_2O \rightarrow H_3O^+ + Cl^-$ (correct)
  • $H_2O \rightarrow H^+ + OH^-$

Which statement accurately describes the behavior of a base in an aqueous solution?

  • It accepts electrons, increasing the concentration of hydronium ions.
  • It accepts protons, increasing the concentration of hydroxide ions. (correct)
  • It donates protons, increasing the concentration of hydronium ions.
  • It donates electrons, decreasing the concentration of hydroxide ions.

Why is it important to remember that hydrogen ions (H+) do not exist independently in water?

<p>Because they combine with water molecules to form hydronium ions (H3O+). (A)</p> Signup and view all the answers

What happens to the concentration of hydroxide ions (OH-) in water when the concentration of hydronium ions (H3O+) increases?

<p>Decreases. (C)</p> Signup and view all the answers

What is the significance of the water dissociation constant ($K_w$) in the context of acid-base chemistry?

<p>It remains constant and indicates the degree to which water dissociates into ions. (A)</p> Signup and view all the answers

Which of the following is a property that is generally associated with acids?

<p>Corrosiveness (C)</p> Signup and view all the answers

If a solution has a higher concentration of hydroxide ions (OH-) than hydronium ions (H3O+), how is the solution classified?

<p>Basic (B)</p> Signup and view all the answers

What occurs when an acid reacts with a base?

<p>Formation of water and a salt (C)</p> Signup and view all the answers

What characterizes pure water in terms of its ion composition and pH?

<p>Equal, small amounts of hydronium and hydroxide ions, resulting in a neutral pH (A)</p> Signup and view all the answers

What is the range of the pH scale?

<p>1 to 14 (D)</p> Signup and view all the answers

The term 'pouvoir hydrogene' refers to what concept?

<p>The power of hydrogen, or pH. (C)</p> Signup and view all the answers

What is the pH of a solution with a hydronium ion concentration of $1 \times 10^{-7}$ M?

<p>7 (D)</p> Signup and view all the answers

Which of the following pH values indicates that a solution is acidic?

<p>pH = 3 (A)</p> Signup and view all the answers

What is the pH of a solution if the hydronium ion concentration [H+] is 1.4 x $10^{-5}$ M?

<p>4.85 (C)</p> Signup and view all the answers

Why is it important to calibrate a pH meter before use?

<p>To ensure accurate measurements by adjusting the meter against known standards. (A)</p> Signup and view all the answers

What are pH buffers used for when measuring pH?

<p>To calibrate the pH meter. (A)</p> Signup and view all the answers

In what industry is pH monitoring NOT typically crucial?

<p>Automotive (A)</p> Signup and view all the answers

Which application relies on maintaining specific pH levels to ensure product efficacy and prevent microbial contamination?

<p>Dairy manufacturing (B)</p> Signup and view all the answers

In the context of acid-base chemistry, what is a 'proton acceptor'?

<p>A base (A)</p> Signup and view all the answers

What is the chemical formula of acetic acid?

<p>CH3COOH (C)</p> Signup and view all the answers

What properties are associated with bases?

<p>Bitter taste and soapy texture (C)</p> Signup and view all the answers

Which of the following statements is true regarding bases?

<p>Bases are proton acceptors that produce OH- ions in water. (D)</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between hydronium and hydroxide ions in pure water?

<p>Pure water contains small, but equal, amounts of hydronium and hydroxide ions. (B)</p> Signup and view all the answers

Which of the following statements accurately describes the role of pH in the food and pharmaceutical industry?

<p>pH affects the quality, stability, solubility, and efficacy of pharmaceutical products. (D)</p> Signup and view all the answers

Flashcards

Acids

Substances that donate protons (H+ ions) in chemical reactions.

Bases

Substances that accept protons (H+ ions) or release hydroxide ions in a solution.

Hydronium ion (H3O+)

The combination of a hydrogen ion and a water molecule

pH

A value that indicates the acidity or basicity of a solution.

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Acidic solution

A solution that donates H+ ions, increasing the hydronium ion concentration.

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Basic solution

A solution that accepts H+ ions, increasing the hydroxide ion concentration.

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Neutral Solution

A solution with equal concentrations of hydronium and hydroxide ions.

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Acidic Water

Water is acidic if the concentration of [H3O+] > 1 x 10-7M

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Basic Water

Water is basic if the concentration of [OH-] > 1 x 10-7M

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Water Dissociation Constant (Kw)

The product of the concentrations of hydronium and hydroxide ions in water; it remains constant.

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pH Calibration

Calibration buffers are aqueous water with a specific pH value

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PH Applications

PH affects the quality, stability, solubility and efficacy of pharmaceutical products. Used in dairy manufacturing to monitor potential for microbial growth.

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Study Notes

  • Level 6 Certificate in Food Science and Technology provided by Megan Kelly at [email protected].
  • The session focuses on pH, acids, and bases.

Learning Objectives

  • Learn to write the chemical equations for acids and bases.
  • Learn to write chemical equations in water to show formation of acids and bases.
  • Learn to define when water is acidic or basic.
  • Learn to calculate acid and base concentrations using the pH scale.
  • Learn to use the pH scale to determine if a water solution is acidic or basic.
  • Learn about key calibration buffers of a pH meter.

Importance of Acids and Bases

  • Essential in biology.
  • Incorrect acid or base concentration impacts proteins and enzymes.
  • Proteins and enzymes will not function.
  • Biopharmaceutical medicines cannot be made.

Common Acids

  • Hydrochloric Acid (HCI).
  • Nitric Acid (ΗΝΟ3).
  • Phosphoric Acid (H3PO4).
  • Sulfuric Acid (H2SO4).
  • Acetic Acid (CH3COOH).

Acids and Bases Chemical Reactions

  • Acids and bases chemical reactions create an acid or base in aqueous solutions in water.
  • Acid: HCI + H₂O → H₃O+ + Cl-.
  • Base: NaOH + H₂O → Na + OH-.
  • Acids donate protons(H+ ions) in a chemical reaction.
  • Bases accepts protons (H+ ions) or releases hydroxide ions in a solution.

Acids in Water

  • Acids make H₃O+ in water.
  • H+ in water does not exist by itself.
  • If H+ is in water it must make hydronium ion.
  • Hydronium ion is made by adding H+ to H₂O to make H₃O+.
  • Water receiving H+ is classified as a base.
  • Base is a proton acceptor.
  • The combination of a hydrogen ion and a water molecule forms H₃O+.

Water Dissociation Constant

  • Kw value remains a constant.
  • If H+ increases, then OH- decreases.
  • If OH- increases, then H+ decreases.
  • Normally, H+ and OH- = 1.0x10-7.
  • Kw = [H3O+][OH-] = [H+][OH-] = 1.0 × 10⁻¹⁴.

Properties of Acids

  • H+ ions are produced when dissolved in water.
  • Acids exist in ionic form in solutions.
  • Acids are known for their sour taste.
  • Acids can corrode metals upon contact.

Acids as Proton Donors

  • Increase hydronium ions like H3O+.
  • HCI (I) H3O+ (aq) + Cl-(aq) means more [H3O+] than normally in water.
  • [H3O+] > 1 x 10-7M
  • When H3O+ increases, OH- decreases.
  • Water is now acidic.

Properties of Bases

  • Serve as proton acceptors to produce OH- ions in water.
  • Exist as ions in solution.
  • Bases are typically bitter with a chalky taste.
  • Bases are feel soapy and slippery to the touch.

Bases

  • Increase the hydroxide ions (OH-).
  • NaOH (s) converts to Na+(aq) + OH-(aq), means more [OH-] than in water.
  • [OH-] > 1 x 10-7M.
  • When OH- increases, H3O+ decreases.
  • Water is now basic.

Acidity and Basicity

  • Water is acidic if [H3O+] > 1 x 10-7M.
  • Water is basic if [OH-] > 1 x 10-7M.
  • When acid reacts with a base a salt is formed.

Pure Water

  • Pure water contains small but equal amounts of ions of H3O+ and OH-.
  • H2O + H2O <==> H3O+ + hydrodium and OH- + hydroxide.
  • 1 x 10-7 level.

Water Acidity Range

  • In water acid concentration can range from 1 to 14.
  • pH = - log [H+].
  • "pH" called pouvoir hydrogene (“hydrogen power" or power of hydrogen) is expressed from 0 to 14, and in a log value.

pH Scale

  • A pH from 0-6 is represents acidic, 7 is neutral and 8-14 is alkaline.

pH Calculations

  • Solution is acidic for pH 3 and 5.
  • Solution is neutral at pH 7.
  • Solution is basic when pH is 9 and 12.
  • To calculate pH given [H+] = -log10[H+].
  • For example [H+] = 1.4 x 10-5 M, the pH = -log10(1.4 x 10-5) = 4.85.

Measuring PH

  • Measurement can be made with a meter.
  • Ensure to calibrate as the electrode is fragile.
  • Use aqueous water buffers to calibrate with a specific pH value.

Applications of pH in Food and Pharma

  • pH affects the quality, stability, solubility and efficacy of pharmaceutical products.
  • Monitoring potential for microbial growth in dairy manufacturing.
  • Used to monitor quality of water.
  • Used in rinse tests for cleaning.
  • Plays a crucial role in beer and wine production.

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