Acid-Base Reactions

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Questions and Answers

Which of the following statements correctly describes the behavior of ampholytes?

  • They can only donate protons in a solution.
  • They neither accept nor donate protons.
  • They can either accept or donate protons. (correct)
  • They can only accept protons in a solution.

According to the Brønsted-Lowry definition, what characterizes a base?

  • A substance that increases the concentration of hydronium ions in water.
  • A substance that donates protons (H+).
  • A substance that accepts protons (H+). (correct)
  • A substance that donates hydroxide ions (OH-).

Which of these aqueous solutions would be considered alkaline?

  • A solution with a pH of 8. (correct)
  • A solution with a pH of 0.
  • A solution with a pH of 6.
  • A solution with a pH of 7.

In the following reaction: HBr + H2O → Br- + H3O+, which species acts as the Brønsted-Lowry acid?

<p>HBr (D)</p> Signup and view all the answers

Which of the following is the conjugate base of sulfuric acid (H2SO4)?

<p>HSO4- (C)</p> Signup and view all the answers

Which of the following best describes the behavior of water in the autoprotolysis process?

<p>Water acts as both an acid and a base. (A)</p> Signup and view all the answers

Which of the following is a strong base that forms a kalilauge (potash lye) when dissolved in water?

<p>KOH (A)</p> Signup and view all the answers

Which of the following acids is commonly known as Essigsäure?

<p>CH3COOH (B)</p> Signup and view all the answers

How do acids influence the concentration of hydrogen ions (H+) in an aqueous solution, according to Arrhenius?

<p>Acids increase the H+ concentration. (D)</p> Signup and view all the answers

What characterizes the pH value of a neutral solution?

<p>It is equal to 7. (C)</p> Signup and view all the answers

Flashcards

What is a Bronsted acid?

A substance that donates protons (H⁺ ions) in a chemical reaction.

What is a Bronsted base?

A substance that accepts protons (H⁺ ions) in a chemical reaction.

What are ampholytes?

Substances that can act as both acids and bases by either donating or accepting protons.

What is the pH value?

A measure to characterize if a solution is acidic, baic or neutral. It indicates the concentration of hydronium ions (H3O⁺).

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What is the pH value of an acidic solution?

0 to 6.9

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What is the pH value of a basic solution?

7.1 to 14

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What are conjugate acid-base pairs?

Acid-Base pairs in that when an acid loses a proton, it forms its conjugate base, and when a base gains a proton, it forms its conjugate acid.

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What is Sodium Hydroxide (NaOH)?

NaOH. When dissolved in water. it forms a strong alkaline solution.

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How do acids affect H+ ion concentration?

Acids increase the concentration of H+ ions in water.

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How do bases affect OH- ion concentration?

Bases increase the number of OH- ions in water.

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Study Notes

  • These are notes on acid-base reactions.

Important Molecular Ions

  • SO42- is a sulfate ion.
  • PO43- is a phosphate ion.
  • NO3 is a nitrate ion.
  • CO32- is a carbonate ion.
  • OH- is a hydroxide ion.
  • NH4+ is an ammonium ion.
  • H3O+ is an oxonium ion.
  • Na+ is a sodium ion.
  • K+ is a potassium ion.
  • Cl- is a chloride ion.

Important Acids

  • H2SO4 is sulfuric acid.
  • H3PO4 is phosphoric acid.
  • HNO3 is nitric acid.
  • H2CO3 is carbonic acid.
  • HCN hydrocyanic acid.
  • HCl is hydrochloric acid.
  • CH3COOH is acetic acid.
  • HBR is hydrogen bromide.

Important Bases

  • NaOH sodium hydroxide becomes sodium hydroxide solution in water.
  • KOH potassium hydroxide becomes potassium hydroxide solution in water.
  • Ca(OH)2 calcium hydroxide becomes limewater in water.
  • NH3 ammonia becomes ammonia water (NH4OH) in water.
  • Na2CO3 is sodium carbonate.

Ampholytes

  • Ampholytes can both accept and donate protons (H+ ions).
  • Examples of ampholytes include H2O (water), CH3COOH (acetic acid), and NH3 (ammonia).

PH Value

  • The pH value is a measure for characterizing an acidic, basic, or neutral solution; pH indicates the concentration of hydroxide ions.
  • pH values range from 0 to 6.9 representing acidic.
  • pH value of 7 is neutral.
  • pH values range from 7.1 to 14, which is basic.

Acids

  • According to Arrhenius, acids are substances that release protons (H+ ions) in aqueous solutions; this only applies to aqueous solutions.
  • Acids increase the H+ ion concentration in water.
  • According to Brønsted, acids are substances that release protons (H+ ions), and bases are substances that accept protons.
  • Acids dissociate (break down) in aqueous solution into positively charged hydrogen ions (protons) and negatively charged acid residue ions.
  • Acids are proton donors.
  • Bases are proton acceptors; this also applies in gases and other solvents, not just water.

Bases

  • Bases are substances that accept protons (proton acceptors).
  • In solutions, bases are alkaline and have a higher pH value than 7.
  • Bases dissociate in aqueous solution into positively charged metal ions and negatively charged hydroxide ions (OH-).

Autoprotolysis of Water

  • Water can both accept and donate protons.
  • In most cases, water accepts protons to form oxonium ions (H3O+).

Acid-Base Pairs

  • Each time an acid releases a proton, it forms a conjugate base.
  • Conversely, when a base accepts a proton, it forms a conjugate acid.
  • HBr + H2O → Br- + H3O+
  • Hydrogen bromide (HBr) is acid 1.
  • Water (H2O) is base 2.
  • Bromide ion (Br-) is base 1.
  • Oxonium ion (H3O+) is acid 2.
  • Acid 1 transforms into base 1.
  • Acid 2 transforms into base 2.

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