Naming Compounds

Section 7.1 Part 1 Naming Ions  OBJECTIVES: –Identify the charges on monatomic ions by using the periodic table, and name the ions.  Section 7.1 Part 1 Naming Ions  OBJECTIVES: –Define a polyatomic ion and write the names and formulas of the most common polyat...

Section 7.1 Part 1 Naming Ions  OBJECTIVES: –Identify the charges on monatomic ions by using the periodic table, and name the ions.  Section 7.1 Part 1 Naming Ions  OBJECTIVES: –Define a polyatomic ion and write the names and formulas of the most common polyatomic ions.  Section 7.1 Part 1 Naming Ions  OBJECTIVES: –Identify the two common endings for the names of most polyatomic ions.  Atoms and Ions  Atoms are electrically neutral. – Because there is the same number of protons (+) and electrons (-).  Ionsare atoms, or groups of atoms, with a charge (positive or negative) – They have different numbers of protons and electrons.  Only electrons can move, and ions are made by gaining or losing electrons.  An Anion is… A negative ion.  Has gained electrons.  Nonmetals can gain electrons.  Charge is written as a superscript on the right. 1- Has gained one electron (-ide F is new ending = fluoride) O2- Gained two electrons (oxide)  A Cation is…  A positiveion.  Formed by losing electrons.  More protons than electrons.  Metals can lose electrons K1+ Has lost one electron (no name change for positive ions) Ca2+ Has lost two electrons  Predicting Ionic Charges Group 1A: Lose 1 electron to form 1+ ions H1+ Li1+ Na1+ K1+ Rb1+  Predicting Ionic Charges Group 2A: Loses 2 electrons to form 2+ ions Be2+ Mg2+ Ca2+ Sr2+ Ba2+  Predicting Ionic Charges Group 3A: Loses 3 B3+ Al3+ Ga3+ electrons to form 3+ ions  Predicting Ionic Charges Neither! Group 4A Group 4A: Do they elements rarely form lose 4 electrons or ions (they tend to share) gain 4 electrons?  Predicting Ionic Charges N3- Nitride Group 5A: Gains 3 P3- Phosphide electrons to form As3- Arsenide 3- ions  Predicting Ionic Charges O2- Oxide Group 6A: Gains 2 S2- Sulfide electrons to form Se2- Selenide 2- ions  Predicting Ionic Charges Group 7A: Gains F1- Fluoride Br1- Bromide 1 electron to form Cl1- Chloride I1- Iodide 1- ions Predicting Ionic Charges Group 8A: Stable noble gases do not form ions!  Predicting Ionic Charges Group B elements: Many transition elements have more than one possible oxidation state. Note the use of Roman Iron (II) = Fe2+ numerals to show charges Iron (III) = Fe3+  Naming cations  Two methods can clarify when more than one charge is possible: 1) Stock system – uses roman numerals in parenthesis to indicate the numerical value 2) Classical method – uses root word with suffixes (-ous, -ic) Does not give true value  Naming cations  We will use the Stock system.  Cation - if the charge is always the same (like in the Group A metals) just write the name of the metal.  Transition metals can have more than one type of charge. – Indicate their charge as a roman numeral in parenthesis after the name of the metal (Use your Ion Sheet)  Predicting Ionic Charges Some of the post-transition elements also have more than one possible oxidation state. Tin (II) = Sn2+ Lead (II) = Pb2+ Tin (IV) = Sn4+ Lead (IV) = Pb 4+  Predicting Ionic Charges Group B elements: Some transition elements have only one possible oxidation state, such as these three: Silver = Ag1+ Zinc = Zn2+ Cadmium = Cd2+  Exceptions:  Some of the transition metals have only one ionic charge: –Do not need to use roman numerals for these: –Silver is always 1+ (Ag1+) –Cadmium and Zinc are always 2+ (Cd2+ and Zn2+)  Practice by naming these:  Na1+  Ca2+  Al3+  Fe3+  Fe2+  Pb2+  Li1+  Write symbols for these:  Potassium ion  Magnesium ion  Copper (II) ion  Chromium (VI) ion  Barium ion  Mercury (II) ion  Naming Anions Anions are always the same charge Change the monatomic element ending to – ide F1- a Fluorine atom will become a Fluoride ion.  Practice by naming these: Cl 1- N3- Br1- O2- Ga3+  Write symbols for these: Sulfide ion Iodide ion Phosphide ion Strontium ion  Polyatomic ions are…  Groups of atoms that stay together and have an overall charge, and one name.  Usually end in –ate or -ite  Acetate: C2H3O21-  Nitrate: NO31-  Nitrite: NO21-  Permanganate: MnO41- 1- 1-  Hydroxide: OH and Cyanide: CN ?  Know Common Polyatomic Ions  Sulfate: SO4 2-  Phosphate: PO43- 2-  Phosphite: PO3 3-  Sulfite: SO3  Carbonate: CO32- 1+  Chromate: CrO4 2-  Ammonium: NH4 (One of the few positive  Dichromate: Cr2O7 2- polyatomic ions) If the polyatomic ion begins with H, then combine the word hydrogen with the other polyatomic ion present: H1+ + CO32- → HCO31- hydrogen + carbonate → hydrogen carbonate ion  Now start your Practice Naming and Writing Anions and Cations worksheet FINISH FOR HOMEWORK!  Section 7.1 Part 2 Naming and Writing Formulas for Ionic Compounds  OBJECTIVES: –Apply the rules for naming and writing formulas for binary ionic compounds.  Section 7.1 Naming and Writing Formulas for Ionic Compounds  OBJECTIVES: –Apply the rules for naming and writing formulas for compounds containing polyatomic ions.  Writing Ionic Compound Formulas Example: Barium nitrate (note the 2 word name) Ba ( NO3- ) 2 1. Write the formulas for the cation and anion, including 2+ CHARGES! 2. Check to see if charges are Now balanced. balanced. Not balanced! = Ba(NO3)2 3. Balance charges , if necessary, using subscripts. Use parentheses if you need more than one of a polyatomic ion. Use the criss-cross method to balance subscripts.  Writing Ionic Compound Formulas Example: Ammonium sulfate (note the 2 word name) 1. Write the formulas for the ( NH4+) SO42- cation and anion, including CHARGES! 2 2. Check to see if charges Now balanced. are balanced. Not balanced! = (NH4)2SO4 3. Balance charges , if necessary, using subscripts. Use parentheses if you need more than one of a polyatomic ion. Use the criss-cross method to balance the subscripts.  Writing Ionic Compound Formulas Example: Iron (III) chloride (note the 2 word name) Fe3+ Cl- 1. Write the formulas for the cation and anion, including CHARGES! 3 Now balanced. 2. Check to see if charges Not balanced! are balanced. = FeCl3 3. Balance charges , if necessary, using subscripts. Use parentheses if you need more than one of a polyatomic ion. Use the criss-cross method to balance the subscripts.  Writing Ionic Compound Formulas Example: Aluminum sulfide (note the 2 word name) Al S 1. Write the formulas for the cation and anion, including 3+ 2- CHARGES! 2 3 2. Check to see if charges Now balanced. are balanced. Not balanced! = Al2S3 3. Balance charges , if necessary, using subscripts. Use parentheses if you need more than one of a polyatomic ion. Use the criss-cross method to balance the subscripts.  Writing Ionic Compound Formulas Example: Magnesium carbonate (note the 2 word name) 1. Write the formulas for the cation and anion, including Mg2+ CO32- CHARGES! 2. Check to see if charges They are balanced! are balanced. = MgCO3  Writing Ionic Compound Formulas Example: Zinc hydroxide (note the 2 word name) Zn ( OH- )2 1. Write the formulas for the cation and anion, including 2+ CHARGES! 2. Check to see if charges are Now balanced. balanced. Not balanced! = Zn(OH)2 3. Balance charges , if necessary, using subscripts. Use parentheses if you need more than one of a polyatomic ion. Use the criss-cross method to balance the subscripts.  Writing Ionic Compound Formulas Example: Aluminum phosphate (note the 2 word name) 1. Write the formulas for the cation and anion, including CHARGES! Al 3+ PO43- 2. Check to see if charges are balanced. They ARE balanced! = AlPO4  Naming Ionic Compounds  1. Name the cation first, then anion  2.Monatomic cation = name of the element Ca2+ = calcium ion  3. Monatomic anion = root + -ide Cl- = chloride CaCl2 = calcium chloride  Naming Ionic Compounds (Metals with multiple oxidation states)  some metals can form more than one charge (usually the transition metals)  use a Roman numeral in their name: PbCl2 – use the anion to find the charge on the cation (chloride is always 1-) Pb2+ is the lead (II) cation PbCl2 = lead (II) chloride  Things to look for: 1) If cations have ( ), the number in parenthesis is their charge. 2) If anions end in -ide they are probably off the periodic table (Monoatomic) 3) If anion ends in -ate or –ite, then it is polyatomic  Practice by writing the formula or name as required…  Iron(II) Phosphate  Stannous Fluoride  Potassium Sulfide  Ammonium Chromate  MgSO4  FeCl3  Section 7.1 Part 3 Naming and Writing Formulas for Molecular Compounds  OBJECTIVES: –Interpret the prefixes in the names of molecular compounds in terms of their chemical formulas.  Section 7.1 Part 3 Naming and Writing Formulas for Molecular Compounds  OBJECTIVES: –Apply the rules for naming and writing formulas for binary molecular compounds.  Molecular compounds are…  made of just nonmetals  smallest piece is a molecule  can’t be held together by opposite charge attraction  can’t use charges to figure out how many of each atom (there are no charges present) Molecular compounds are easier!  Ioniccompounds use charges to determine how many of each. –You have to figure out charges. –May need to criss-cross numbers.  Molecularcompounds: the name tells you the number of atoms. – Uses prefixes to tell you the exact number of each element present!  Prefixes (Table 9.4, p.269)  1 = mono-  2 = di-  3 = tri-  4 = tetra-  5 = penta-  6 = hexa-  7 = hepta-  8 = octa-  Prefixes  9 = nona-  10 = deca-  To write the name, write two words: Prefix & name Prefix & name -ide  Prefixes  9 = nona-  10 = deca-  To write the name, write two words: Prefix name Prefix name -ide  One exception is we don’t write mono if there is only one of the first element.  Prefixes  9 = nona-  10 = deca-  To write the name, write two words: Prefix name Prefix name -ide  One exception is we don’t write mono if there is only one of the first element.  Normally, we do not have double vowels when writing names (oa oo)  Practice by naming these:  N 2O = dinitrogen monoxide (also called nitrous oxide or laughing gas)  NO2 = nitrogen dioxide  Cl2O7 = dichlorine heptoxide  CBr4 = carbon tetrabromide  CO2 = carbon dioxide  BaCl2 (This one will not use prefixes, since it is an ionic compound!)  Write formulas for these:  diphosphorus pentoxide  tetraiodine nonoxide  sulfur hexafluoride  nitrogen trioxide  carbon tetrahydride  phosphorus trifluoride  aluminum chloride (Ionic compound)  Section 7.1 Part 4 Naming and Writing Formulas for Acids and Bases  OBJECTIVES: –Apply three rules for naming acids.  Section 7.1 Part 4 Naming and Writing Formulas for Acids and Bases  OBJECTIVES: –Apply the rules in reverse to write formulas of acids.  Section 7.1 Part 4 Naming and Writing Formulas for Acids and Bases  OBJECTIVES: –Apply the rules for naming bases.  Acids are…  Compounds that give off hydrogen ions (H1+) when dissolved in water (the Arrhenius definition)  Will start the formula with H.  There will always be some Hydrogen next to an anion.  The anion determines the name. Rules for Naming acids: Name it as a normal compound first 1) If the anion attached to hydrogen ends in -ide, put the prefix hydro- and change -ide to -ic acid HCl - hydrogen ion and chloride ion = hydrochloric acid H2S hydrogen ion and sulfide ion = hydrosulfuric acid  Naming Acids If the anion has oxygen in it, then it ends in -ate or -ite 2) change the suffix -ate to -ic acid (use no prefix) Example: HNO3 Hydrogen and nitrate ions = Nitric acid 3) change the suffix -ite to -ous acid (use no prefix) Example: HNO2 Hydrogen and nitrite ions = Nitrous acid  Naming Acids Normal ending Acid name is… ____-ide hydro-___-ic acid ____-ate _____-ic acid ____-ite _____-ous acid  2 additional rules (not mentioned in the book) 4) If the acid has 1 more oxygen than the –ic acid, add the prefix per- a. HClO3 is chloric acid (Hydrogen Chlorate) b. HClO4 would be perchloric acid 5) If there is 1 less oxygen than the -ous acid, add the prefix hypo- HClO2 (Hydrogen Chlorite) is chlorous acid, then HClO would be hypochlorous acid  Practice by naming these:  HF  H3P  H2SO4  H2SO3  HCN  H2CrO4  Writing Acid Formulas – in reverse! Hydrogen will be listed first The name will tell you the anion Be sure the charges cancel out. Starts with prefix hydro?- there is no oxygen, -ide ending for anion no prefix hydro? 1) -ate anion comes from –ic ending 2) -ite anion comes from –ous ending  Write formulas for these:  hydroiodic acid  acetic acid  carbonic acid  phosphorous acid  hydrobromic acid Names and Formulas for Bases A base is an ionic compound that produces hydroxide ions (OH1-) when dissolved in water (the Arrhenius definition)  Bases are named the same way as other ionic compounds: –The name of the cation (which is a metal) is followed by the name of the anion (which will be hydroxide). Names and Formulas for Bases  NaOH is sodium hydroxide  Ca(OH)2 is calcium hydroxide  To write the formula: 1) Write the symbol for the metal cation 2) followed by the formula for the hydroxide ion (OH1-) 3) then use the criss-cross method to balance the charges. Practice by writing the formula for the following: Magnesium hydroxide Iron (III) hydroxide Zinc hydroxide  Section 7.1 Part 5 The Laws Governing Formulas and Names  OBJECTIVES: –Define the laws of definite proportions and multiple proportions.  Section 7.1 Part 5 The Laws Governing Formulas and Names  OBJECTIVES: –Apply the rules for naming chemical compounds by using a flowchart.  Section 7.1 Part 5 The Laws Governing Formulas and Names  OBJECTIVES: –Apply the rules for writing the formulas of chemial compounds by using a flowchart.  Some Laws:  1. Law of Definite Proportions- in a sample of a chemical compound, the masses of the elements are always in the same proportions.  H2O (water) and H2O2 (hydrogen peroxide)  Some Laws:  2.Law of Multiple Proportions- Dalton stated that whenever two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers. Same mass of oxygen  Summary of Naming and Formula Writing  For naming, follow the flowchart- Figure 9.20, page 277  For writing formulas, follow the flowchart from Figure 9.22, page 278  Helpful to remember... 1. In an ionic compound, the net ionic charge is zero (criss-cross method) 2. An -ide ending generally indicates a binary compound 3. An -ite or -ate ending means there is a polyatomic ion that has oxygen 4. Prefixes generally mean molecular; they show the number of each atom  Helpful to remember... 5. A Roman numeral after the name of a cation is the ionic charge of the cation  Use the handout sheets provided by your teacher!