Stoichiometry Calculations PDF

Summary

This document provides a series of calculations and an introduction example of stoichiometry. Calculations in chemistry are used to find the required amounts or products. Examples of calculations include finding the moles of CO2 produced by burning 5 moles of CH4, and how many moles of oxygen are required to form 12 moles of water from the reaction of hydrogen and oxygen. It then further delves into mole-mass calculations for various chemical reactions.

Full Transcript

Calculations from Chemical Equations (Stoichiometry) GENERAL CHEMISTRY 1 MOLE RATIO The combustion of methane, CH4 𝑪𝑯𝟒 + 𝟐𝑶𝟐 → 𝑪𝑶𝟐 + 𝟐𝑯𝟐 𝑶 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 1 𝑚𝑜𝑙𝑒 𝐶𝑂2 2 𝑚𝑜𝑙𝑒𝑠 𝐻2...

Calculations from Chemical Equations (Stoichiometry) GENERAL CHEMISTRY 1 MOLE RATIO The combustion of methane, CH4 𝑪𝑯𝟒 + 𝟐𝑶𝟐 → 𝑪𝑶𝟐 + 𝟐𝑯𝟐 𝑶 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 1 𝑚𝑜𝑙𝑒 𝐶𝑂2 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝑂2 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 MOLE RATIO The combustion of methane, CH4 𝑪𝑯𝟒 + 𝟐𝑶𝟐 → 𝑪𝑶𝟐 + 𝟐𝑯𝟐 𝑶 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒𝑠 𝐶𝑂2 1 𝑚𝑜𝑙𝑒𝑠 𝐶𝑂2 1 𝑚𝑜𝑙𝑒𝑠 𝐶𝑂2 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 2 𝑚𝑜𝑙𝑒𝑠 𝑂2 1 𝑚𝑜𝑙𝑒 𝐶𝑂2 MOLE RATIO The combustion of methane, CH4 𝐶𝐻4 + 2𝑂2 → 𝐶𝑂2 + 2𝐻2 𝑂 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 How many moles of carbon dioxide will be produced by burning 5 moles of methane? 𝑥 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑑𝑒𝑠𝑖𝑟𝑒𝑑 𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 𝑛𝑜. 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑑𝑒𝑠𝑖𝑟𝑒𝑑 𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 (𝑟𝑒𝑥 ′ 𝑛) = 𝑛𝑜. 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑜𝑡ℎ𝑒𝑟 𝑔𝑖𝑣𝑒𝑛 𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 𝑛𝑜. 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑡ℎ𝑒 𝑜𝑡ℎ𝑒𝑟 𝑔𝑖𝑣𝑒𝑛 𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 (𝑟𝑒𝑥 ′ 𝑛) MOLE RATIO The combustion of methane, CH4 𝐶𝐻4 + 2𝑂2 → 𝐶𝑂2 + 2𝐻2 𝑂 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 1 𝑚𝑜𝑙𝑒 2 𝑚𝑜𝑙𝑒𝑠 How many moles of carbon dioxide will be produced by burning 5 moles of methane? 1 𝑚𝑜𝑙𝑒 𝐶𝑂2 𝑛𝐶𝑂2 1 𝑚𝑜𝑙𝑒 𝐶𝑂2 𝑛𝐶𝑂2 = × 5 𝑚𝑜𝑙𝑒𝑠 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 = 5 𝑚𝑜𝑙𝑒𝑠 𝐶𝐻4 1 𝑚𝑜𝑙𝑒 𝐶𝐻4 𝒏𝑪𝑶𝟐 = 𝟓 𝒎𝒐𝒍𝒆𝒔 𝑪𝑶𝟐 MOLE RATIO Determine the number of moles of oxygen reacted with hydrogen to produce 12 moles of water. 2 𝑯𝟐 + 𝑶𝟐 → 2 𝑯𝟐 𝑶 𝟐 𝒎𝒐𝒍𝒆𝒔 𝟏 𝒎𝒐𝒍𝒆 𝟐 𝒎𝒐𝒍𝒆𝒔 𝑛𝑂2 1 𝑚𝑜𝑙𝑒 𝑂2 = 12 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 1 𝑚𝑜𝑙𝑒 𝑂2 𝑛𝑂2 = × 12 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 2 𝑚𝑜𝑙𝑒𝑠 𝐻2 𝑂 𝒏𝑶𝟐 = 𝟔 𝒎𝒐𝒍𝒆𝒔 𝑯𝟐 𝑶 How many moles of binary acid must react with a base to produce 15 moles of aluminum bromide in a neutralization reaction. 𝑎𝑙𝑢𝑚𝑖𝑛𝑢𝑚 𝑏𝑟𝑜𝑚𝑖𝑑𝑒, 𝐴𝑙𝐵𝑟3 (𝑠𝑎𝑙𝑡) ℎ𝑦𝑑𝑟𝑜𝑏𝑟𝑜𝑚𝑖𝑐 𝑎𝑐𝑖𝑑, 𝐻𝐵𝑟(𝑎𝑐𝑖𝑑) 𝑎𝑙𝑢𝑚𝑖𝑛𝑢𝑚 ℎ𝑦𝑑𝑟𝑜𝑥𝑖𝑑𝑒, 𝐴𝑙(𝑂𝐻)3 (𝑏𝑎𝑠𝑒) 𝟑𝑯𝑩𝒓 + 𝑨𝒍(𝑶𝑯)𝟑 → 𝑨𝒍𝑩𝒓𝟑 + 𝟑𝑯𝟐 𝑶 𝑛𝐻𝐵𝑟 3 𝑚𝑜𝑙𝑒𝑠 𝐻𝐵𝑟 = 15 𝑚𝑜𝑙𝑒𝑠 𝐴𝑙𝐵𝑟3 1 𝑚𝑜𝑙𝑒 𝐴𝑙𝐵𝑟3 3 𝑚𝑜𝑙𝑒𝑠 𝐻𝐵𝑟 𝑛𝐻𝐵𝑟 = × 15 𝑚𝑜𝑙𝑒𝑠 𝐴𝑙𝐵𝑟3 1 𝑚𝑜𝑙𝑒 𝐴𝑙𝐵𝑟3 𝒏𝑯𝑩𝒓 = 𝟒𝟓 𝒎𝒐𝒍𝒆𝒔 𝑯𝑩𝒓 Mole-Mass Calculation Mole to mass Mass to mole Mass to mass Mole to Mass Calculation mole ratio  mole of desired substance mass of desired substance Mole-Mass Calculation Mole to mass Mass to mole Mass to mass Mass to Mole Calculation mass to mole mole ratio  mole of desired substance Mole-Mass Calculation Mole to mass Mass to mole Mass to mass Mass to Mass Calculation mass to mole mole ratio  mole of desired substance  mass of desired substance Mole-Mass Calculation A complete combustion of 10 moles of ethyl alcohol, C2H5OH, is done producing carbon dioxide and water. Determine the mass of carbon dioxide produced. mole ratio mole of desired substance mass of desired substance 𝟐𝑪𝟐 𝑯𝟓 𝑶𝑯 + 𝟕𝑶𝟐 → 𝟒𝑪𝑶𝟐 + 𝟔𝑯𝟐 𝑶 2 𝑚𝑜𝑙𝑒𝑠 7 𝑚𝑜𝑙𝑒𝑠 4 𝑚𝑜𝑙𝑒𝑠 6 𝑚𝑜𝑙𝑒𝑠 𝑛𝐶𝑂2 4 𝑚𝑜𝑙𝑒𝑠 𝐶𝑂2 = 10 𝑚𝑜𝑙𝑒𝑠 𝐶2 𝐻5 𝑂𝐻 2 𝑚𝑜𝑙𝑒𝑠 𝐶2 𝐻5 𝑂𝐻 𝒏𝑪𝑶𝟐 = 𝟐𝟎 𝒎𝒐𝒍𝒆𝒔 Mole-Mass Calculation A complete combustion of 10 moles of ethyl alcohol, C2H5OH, is done producing carbon dioxide and water. Determine the mass of carbon dioxide produced. mole ratio mole of desired substance mass of desired substance 𝟐𝑪𝟐 𝑯𝟓 𝑶𝑯 + 𝟕𝑶𝟐 → 𝟒𝑪𝑶𝟐 + 𝟔𝑯𝟐 𝑶 𝒏𝑪𝑶𝟐 = 𝟐𝟎 𝒎𝒐𝒍𝒆𝒔 𝑚𝑎𝑠𝑠𝐶𝑂2 = 𝑛𝐶𝑂2 × 𝑀𝑊𝐶𝑂2 𝑔 𝑀𝑊𝐶𝑂2 = 12 + (16 × 2) 𝑚𝑎𝑠𝑠𝐶𝑂2 = 20 𝑚𝑜𝑙𝑒𝑠 × 44 𝑔 𝑚𝑜𝑙𝑒 𝑀𝑊𝐶𝑂2 = 44 𝑚𝑜𝑙𝑒 𝒎𝒂𝒔𝒔𝑪𝑶𝟐 = 𝟖𝟖𝟎 𝒈 Mass to Mole Calculation If 50 grams of sodium is completely synthesized with chlorine to form sodium chloride, how many moles of salt was formed? 𝟐𝑵𝒂 + 𝑪𝒍𝟐 → 𝟐𝑵𝒂𝑪𝒍 𝟐 𝒎𝒐𝒍𝒆𝒔 𝟏 𝒎𝒐𝒍𝒆 𝟐 𝒎𝒐𝒍𝒆𝒔 mass to mole mole ratio  mole of desired substance 𝑚𝑎𝑠𝑠 𝑁𝑎 𝑛𝑁𝑎 = 𝑛𝑁𝑎 = 2.17 𝑚𝑜𝑙𝑒𝑠 𝐴𝑊𝑁𝑎 50 𝑔 𝑛𝑁𝑎𝐶𝑙 2 𝑚𝑜𝑙𝑒𝑠 𝑁𝑎𝐶𝑙 𝑛𝑁𝑎 = 𝑔 = 23 2.17 𝑚𝑜𝑙𝑒𝑠 𝑁𝑎 2 𝑚𝑜𝑙𝑒𝑠 𝑁𝑎 𝑚𝑜𝑙𝑒 𝒏𝑵𝒂𝑪𝒍 = 𝟐. 𝟏𝟕 𝒎𝒐𝒍𝒆𝒔

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