New Mansoura University Organic Chemistry CHE 111 Lecture 1 PDF

New Mansoura University Faculty of Science Organic Chemistry CHE 111 Lecture 1 Prepared by: Dr. Eslam Abdelghaffar  Lecture Outlines. ILOS (Intented Learning outcoums) Definition Of Organic ATOMS, ELECTRONS, AND...

New Mansoura University Faculty of Science Organic Chemistry CHE 111 Lecture 1 Prepared by: Dr. Eslam Abdelghaffar  Lecture Outlines. ILOS (Intented Learning outcoums) Definition Of Organic ATOMS, ELECTRONS, AND 1 Chemistry. 2 ORBITALS Chemical bonds and 3 Chemical parameters Dipole moment 4 and electronegativity 5 Classification of carbon atoms  Organic Chemistry: The chemistry of carbon and carbon- based compounds. (Carbon is the backbone of the of the life)  Organic compounds are compounds that contain carbon atoms. What makes carbon so special? Why are there so many carbon-containing compounds? 2 ATOMS, ELECTRONS, AND ORBITALS  Atom ic Structure: Orbitals Shapes o f A t o m i c Orbitals f o r Electrons ▪ Four different kinds of orbitals for electrons based on those derived for a hydrogen atom ▪ Denoted s, p, d, and f ▪ s and p orbitals most important in organic and biological chemistry ▪ s orbitals: spherical, nucleus at center ▪ p orbitals: dumbbell-shaped, nucleus at middle ▪ d orbitals: cloverleaf-shaped, nucleus at center  Filling Rules f o r Electron Orbitals Aufbau Principle: Electrons are added one at a time to the lowest energy orbitals available until all the electrons of the atom have been accounted for. Pauli Exclusion Principle: Each orbital is allowed a maximum of two electrons must spin in opposite directions. Hund’s Rule: Electrons first occupy each orbital singly with parallel spins before pairing  Energy Level Diagram o f a Many-Electron A to m 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p 6s 4f 5d 6p 7s 5f 6d 7p Valence Electrons: Valence electrons are electrons in the outermost shell. The most important electrons: because the electrons of this shell are the ones that an atom uses in making chemical bonds with other atoms to form compounds. Valence electrons is equal to the group number of the atom. For example, carbon is in group IVA and carbon has four valence electrons; oxygen is in group VIA and oxygen has six valence electrons. The halogens of group VIIA all have seven electrons.  Ans For practice: https://terpconnect.umd.edu/~wbreslyn/chemistry/electron-configurations/configurationPotassium.html  IONIC AND COVALENT BONDS Why atoms come together to form bonds? ❖An atom is most stable if its outer shell is either filled (contains eight electrons (octet rule) except 1s (2 e)) or empty. ❖ A hydrogen atom has one valence electron. Therefore, it can achieve a completely empty shell by losing an electron or a filled outer shell by gaining an electron. ❖ Lithium (Li) has a single electron in its 2 s orbital. If it loses this electron, the lithium atom ends up with a filled outer shell—a stable configuration. Lithium, therefore, loses an electron relatively easily ❖ Sodium (Na) has a single electron in its 3 s orbital, so it too loses an electron easily. ❖Fluorine has seven valence electrons Consequently, it readily acquires an electron in order to have an outer shell of eight electrons, thereby forming F-, a fluoride ion. F9 1s22s22p5 ❖Chlorine has seven valence electrons Consequently, it readily acquires an electron in order to have an outer shell of eight electrons, thereby forming Cl-, a chloride ion. Cl17 1s22s22p63s23p5  Chemical bonds Types of bonds. 1 Ionic bonds. 2 Covalent bonds.  Ionic bond ▪ Ionic bonds are formed between molecules or between ions with opposite charges. ▪ The negatively charged anion will electrostatically attract the positively charged cation. ▪ This is present in salts. ▪ Ionic compounds are formed when an element on the left side of the periodic table transfers one or more electrons to an element on the right side of the periodic table. ▪ A bond formed as a result of the electrostatic attraction between ions of opposite charge ▪ Are formed always between metal (lose electron) cations and non-metals anions (gain electron) so they exchange electrons to form the bond. ▪ Cation (+Ve charge) is formed when atom lose electron ▪ Anion ( -Ve charge is formed when atom gain electrons)  Properties o f Ionic Compounds Hard solid High mp temperatures Nonconductors of electricity in solid phase Good conductors in liquid phase or dissolved in water (aq)  ▪ Covalent bonds ▪ Formed when a pair of electrons is shared between two atoms. ▪ Covalent bonding like Ionic bonding results in a more stable compound, because the atoms involved meet the “octet rule”. ▪ Occurs between NON-METALS (ex. H, C, O, N…), which need to gain electrons to get a stable octet of electrons or a filled outer shell. ▪ The tendency for an atom to achieve a configuration where its valence shell contains eight electrons is called the octet rule Properties of Molecular Substances Low m.p. temp and b.p. temps Covalent bonding Relatively soft solids as compared to ionic compounds Poor conductors of electricity A “shared” pair of electrons makes a SINGLE BOND (2 total e-). 2 “shared” pairs makes a DOUBLE BOND (4 total e-). 3 “shared” pairs makes a TRIPLE BOND (6 total e-). C O V A L E N T BONDS and I O N I c bond ⚫ Unlike ionic bonds with transferred electrons, covalent bonds Sharing electrons. IONIC BOND COVALENT BOND  Electronegativity is the attraction an atom has for a shared pair of electrons.  Increases from left to right going across a period on the periodic table. Increases from the bottom to the top of the periodic table. (F > O > N, Cl > Br > I > S, C > H)  Electronegativity and Dipole moment. Polarity of Bonds is based on the electronegativity between the bonded atoms. If the electronegativity difference is Between 0 and 0.4, the bond is nonpolar covalent. Between 0.5 and 1.8, the bond is polar covalent. Greater than 1.8, the bond is ionic, and the electrons are considered transferred.  Does anyone have any questions? Thank you!