Summary

This document contains examples of gas law stoichiometry problems that can be used for practice. The examples include reactions between nitrogen, hydrogen and ammonia gases under standard ambient temperature and pressure(SATP).

Full Transcript

Gas Law Stoichiometry This is the same as any other stoichiometry 3 Steps - What do you think they are? This is the same as any other stoichiometry – Convert to mole – Convert mole of known to mole of unknown – Convert to desired unit (with gas stoichiometry, a shortcut can...

Gas Law Stoichiometry This is the same as any other stoichiometry 3 Steps - What do you think they are? This is the same as any other stoichiometry – Convert to mole – Convert mole of known to mole of unknown – Convert to desired unit (with gas stoichiometry, a shortcut can sometimes be used) The ideal gas law just gives you another way to convert to mole amounts (under any condition, not just STP) Summary of the last 3 units of SCH3U0 (ways to convert to/from moles): Using: Unit-Conversion Factor/Method: Particles Mass (of a pure substance): Volume (for solutions): Volume, Pressure & Temperature (for gases): Summary of the last 3 units of SCH3U0 (ways to convert to/from moles): Using: Unit-Conversion Factor/Method: Avogadro’s number: (6.022x1023 particles) Particles 1mol Mass (of a pure substance): Molar mass (g/mol) Volume (for solutions): Concentration (mol/L) Volume, Pressure & PV = nRT Temperature (for gases): Unit 3 particles Avogadro’ s number Unit 5 mol Unit 3 Gases PV=nRt Molar mass mass Concentration and Volume Solutions Unit 4 Eg. 1: Nitrogen and hydrogen gas react to form ammonia. If 1.00 L of nitrogen reacts with excess hydrogen gas how many liters of ammonia gas are produced under SATP? N + 3H → 2NH 2(g) 2(g) 3(g) Eg. 1: Nitrogen and hydrogen gas react to form ammonia. If 1.00 L of nitrogen reacts with excess hydrogen gas how many liters of ammonia gas are produced under SATP? N + 3H → 2NH 2(g) 2(g) 3(g) 2molNH3 0.0404molN2 x = NH3 1molN2 0.0808mol PV=nRT n= PV PV=nRT RT V= nRT n= (100kPa) (1.00L) P (8.314kPa L) (298K) V = (0.0808mol) (8.314kPa L/mol K)(298K) 100kPa mol K V = 2.00LNH3 n= 0.0404molN2 Therefore 2.00L of ammonia are produced Eg. 1: Nitrogen and hydrogen gas react to form ammonia. If 1.00 L of nitrogen reacts with excess hydrogen gas how many liters of ammonia gas are produced under SATP? (NOTE: With gasses, mols α volume (thank you Avogadro) so the volume ratio will follow the mol ratio) Eg. 1: Nitrogen and hydrogen gas react to form ammonia. If 1.00 L of nitrogen reacts with excess hydrogen gas how many liters of ammonia gas are produced under SATP? (NOTE: With gasses, mols α volume (thank you Avogadro) so the volume ratio will follow the mol ratio) N + 3H → 2NH 2(g) 2(g) 3(g) 2molNH3 1.00 LN2 x = NH3 1molN2 2.00L Therefore 2.00L of ammonia are produced (If conditions changed, we would have to use combined or ideal gas law) E.g. 3 What volume of hydrogen gas is produced when excess sulfuric acid reacts with 40.0 g of iron at 18.0 °C and 100.3 kPa? E.g. 3 What volume of hydrogen gas is produced when excess sulfuric acid reacts with 40.0 g of iron at 18.0 °C and 100.3 kPa? Solution mFe = 40.0 g T = 18.0 °C P = 100.3 kPa MFe = 55.85 g/mol Fe + H SO →H + (s) 2 4(aq) 2(g) FeSO 4(aq) V = 17.3 L Pg. 603, Q. 1-5

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