Chemistry Chapter 1 PDF
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Western Kentucky University
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This document is a chapter on chemistry, covering states of matter, physical and chemical properties. Concepts of pure substances and mixtures, as well as detailed examples and calculations related to significant figures and density are included.
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Chemistry Chapter 1 Three states of matter: solid, liquid, and gas Solid ○ Has a definite volume ○ Maintains its shape regardless of its container ○ Has particles that lie close together in a regular three-dimensional array Liquid ○ Has a definite vo...
Chemistry Chapter 1 Three states of matter: solid, liquid, and gas Solid ○ Has a definite volume ○ Maintains its shape regardless of its container ○ Has particles that lie close together in a regular three-dimensional array Liquid ○ Has a definite volume ○ Takes the shape of its container ○ Has particles that are close together that can randomly move around, sliding past one another Gas ○ Has no definite shape or volume ○ Expands to fill the volume and assumes the shape of its container ○ Has particles that are very far apart and move around randomly Physical/chemical properties and changes Physical properties: can be observed or measured without changing the composition of the material ○ Examples: boiling point, melting point, solubility, color, odor Physical change: alters the material without changing its composition ○ Examples: melting ice to form liquid water, boiling liquid water to form steam Chemical properties: determine how a substance can be converted into another ○ Does it dissolve or react with a certain chemical Chemical change/chemical reaction: converts one substance into another; usually not reversible ○ Examples: a piece of paper burning, metabolizing an apple for energy, or oxygen and hydrogen combining to form water Pure substances and mixtures Pure substance ○ Composed of a single component ○ Has a constant composition, regardless of sample size and origin of sample Ex: water is always H2O ○ Cannot be broken down to other pure substances by a physical change ○ Table sugar (C12H22O11) and water (H2O) are both pure substances Mixture ○ Composed of more than one substance ○ Can have varying composition (any combination of solid, liquid, and gas) depending on the sample ○ Can be separated into its components by a physical change Ex: can pull ice out of water, can pull marshmallows out of lucky charms ○ Sugar dissolves in water=mixture Elements and compounds Element: a pure substance that cannot be broken down by a chemical change Compound: a pure substance formed by chemically joining two or more elements Matter Matter: anything that has mass and takes up volume ○ Stuff is volume Chemistry Chemistry: the study of matter- its composition, properties, and transformations Significant Figures Definition: all the digits in a measured number including one estimated digit All nonzero digits are always significant ○ 65.2= 3 Sig Figs ○ 255.345= 6 Sig Figs Rule 1: A zero COUNTS as a sig fig when it occurs: ○ Between two nonzero digits, as in 29.05= 4 sig figs, 1.0087= 5 sig figs ○ At the end of a number with a decimal place 3.7500= 5 sig figs, 620= 3 sig figs Rule 2: A zero DOESN’T COUNT as a sig fig when it occurs: ○ At the beginning of a number 0.00245= 3 sig figs, 0.008= 1 sig fig ○ At the end of a number that does not have a decimal 2570= 3 sig figs, 1245500= 5 sig figs Scientific Notation y x 10^x ○ Y: coefficient: number between 1-10 ○ X: exponent: any pos or neg whole number Ex: 500= 5x10^2 Ex: 0.00453= 4.53x10^-3 Scientific notation on calculator: Use EE in place of x10, and follow with exponent value Sig Figs Rules for multiplication and division The answer has the same number of sig figs as the original number with the fewest significant figures Ex: 351.2 x 5.5 = 193.16 ○ Round to two sig figs, answer is 190 Sig Figs rules for addition and subtraction The answer has the same number of sig figs as the original number with the fewest decimal places Ex: 10.11- 3.6= 6.5 3.6 has the 2 amount of decimal places, so answer should have 2 decimal places Density A physical property that relates the mass of a substance to its volume Density = mass (g)/ volume (mL or cc) To convert volume (mL) to mass (g) ○ mL x g/mL =g To convert mass (g) to volume (mL) ○ g x mL/g = mL Ice floats in water because the density of water is less than water Water density = 1.00 g/mL Volume displacement Final volume - initial volume = volume of object Specific gravity Ratio between density of substance and density of water Density of substance g/mL/ density of water 1.00 g/mL Normal urine has a specific gravity of 1.003-1.030 Conversion factor Definition: term that converts a quantity in one unit to another unit Original quantity x conversion factor = desired quantity Written as equalities with units that cancel each other out Percents Percent factor gives the ratio of the parts to the whole (parts per 100 parts) % = parts/whole x100 ○ Uses same unit in num and denom Temperature conversions Three temperature scales used: degrees Fahrenheit, degrees Celsius, and Kelvin To convert from C to F: F= 1.8(C)+32 To convert from F to C: C= F-32/1.8 To convert from C to K: K= C+273 To convert from K to C: C= K-273 Chapter 2 Nucleus Central region of the atom where protons and neutrons are concentrated Electrons Outside the nucleus and orbit about it because they are attracted to the positive charge in the nucleus Extremely tiny Negative electrical charge Symbol: e- Relative mass: 0.00055 Relative charge: -1 Protons Has the same amount of charge as an electron, but its charge is positive not negative Symbol: p+ Relative mass: 1 Relative charge: +1 Located in the nucleus of an atom Neutrons Particle with about the same mass as a proton but with no electrical charge Symbol: n^0 Relative mass: 1 Relative charge: 0 (neutral) Located in the nucleus of an atom Mass number The sum of the number of protons and neutrons Atomic number Defines the identity of an element Elements are listed in order of atomic number The number above the atomic symbol The number of protons in the atom is called the atomic number The atomic number of an element also gives the number of electrons of that neutral element 1 amu = 1.6606 x 10^-24g Atomic mass A weighted average mass (commonly referred to as the atomic weight) of an element An atomic mass unit is 1/12th the mass of a 12C atoms Based largely on the number of protons and neutrons in their nucleus Metals Solids at room temperature (except mercury) Shiny Good conductors of heat and electricity Malleable (can be shaped) Ductile (can be drawn into wires) High melting point and density Readily combine with nonmetals to form compounds but rarely combine with other metals Nonmetals Not shiny Daily low melting points and densities Poor conductors of heat and electricity Solid nonmetals are very brittle Combine with nonmetals to form molecular compounds and with metals to form ionic compounds Metalloids Metalloids have properties between metals and nonmetals Positioned diagonally on the periodic table, separating the metals and nonmetals Alkali metals The first column of elements Alkaline earth metals The second column of elements Halogens The next to last column of elements Noble gases The last column of elements Isotope Atoms of an element with the same atomic number but different numbers of neutrons Isotop symbol: mass number in top left subscript, atomic number (protons) in bottom left subscript, element symbol after Electron arrangement (electron configuration) Electrons are organized according to their energies into sets called shells Shells are divided into subshells, labeled s, p, d, and f ○ S can hold up to 2 electrons, p:6, d:10, f:14 Electron configurations: shorthand descriptions of the arrangements of electrons in atoms Valence electrons Electrons in the highest-numbered shell Equal to the group number (vertical column) For groups 1-2, the number of valence electrons is equal to the group number For transition metals (groups 3-12), use the modified d electron count method For groups 13-18, the number of valence electrons is the group number minus 10 Number of electron levels Atomic size Ionization energy Measure of strength by which an electron is held in place The amount of energy required to remove an electron from an isolated atom or molecule Electron dot symbols Diatomic elements Important elements that exist as two atom combinations Have no fear of ice cold beer: ○ Hydrogen (H2), Nitrogen (N2), Fluorine (F2), Oxygen (O2), Iodine (I2), Chlorine (Cl2), Bromine (Br2) Atomic Radius Largest radius = close to Francium Smallest radius = close to Fluorine Increases as you move down a group Decreases as you move across a period