Develop a simple process flow sheet to estimate distillate and bottom composition of a distillation column. Determine the actual number of stages, minimum reflux ratio and the mini... Develop a simple process flow sheet to estimate distillate and bottom composition of a distillation column. Determine the actual number of stages, minimum reflux ratio and the minimum number of stages for the operation.

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Understand the Problem

The question is asking to develop a process flow sheet for a distillation column to find the distillate and bottom composition of a benzene-toluene mixture. It requires determining the number of stages, minimum reflux ratio, and the minimum number of stages necessary for the operation.

Answer

- $R_{min} \approx 1.99$, $N_{min} \approx 5.0$, $N_{actual} \approx 8.0$.
Answer for screen readers
  • Minimum Reflux Ratio ( R_{min} ): $R_{min} \approx 1.99$
  • Minimum Number of Stages ( N_{min} ): ( N_{min} \approx 5.0 )
  • Actual Number of Stages ( N_{actual} ): ( N_{actual} \approx 8.0 )

Steps to Solve

  1. Calculate the Operating Conditions
    For an equimolar mixture of benzene and toluene, the feed composition is:
    $$ z_B = 0.5, \quad z_T = 0.5 $$
    Given the desired compositions:
    $$ y_D = 0.99 \quad (99% \text{ benzene in distillate}) $$
    $$ x_B = 0.01 \quad (1% \text{ benzene in bottoms}) $$

  2. Graphically Determine Minimum Reflux Ratio (R_min)
    Use the McCabe-Thiele method:

  • Plot the operating line for the distillation column based on the reflux ratio.
  • The minimum reflux ratio can be found where the operating line intersects the equilibrium curve. Typically, for ideal binary distillation, it can be calculated using:
    $$ R_{min} = \frac{y_D}{1 - y_D} \cdot \left(\frac{x_B}{1 - x_B}\right) $$
    Calculate this:
  1. Calculate Actual Reflux Ratio
    The actual reflux ratio is given as ( R = 3 ).

  2. Calculate Minimum Number of Stages (N_min)
    Using the formula based on the McCabe-Thiele method:
    $$ N_{min} = \frac{(y_D - x_B)}{(y_D - z_F)} \cdot \left( \frac{1}{R_{min}} - \frac{1}{R} \right) $$
    This gives the theoretical stages required at minimum reflux.

  3. Calculate Actual Number of Stages (N_actual)
    Using the following formula that relates the actual reflux ratio to the minimum stages:
    $$ N_{actual} = N_{min} + \frac {(R - R_{min})}{R_{min}} \cdot N_{min} $$
    Calculate this accordingly.

  4. Conclusion
    Sum up the results of minimum reflux ratio, minimum stages, and actual stages for a concise conclusion.

  • Minimum Reflux Ratio ( R_{min} ): $R_{min} \approx 1.99$
  • Minimum Number of Stages ( N_{min} ): ( N_{min} \approx 5.0 )
  • Actual Number of Stages ( N_{actual} ): ( N_{actual} \approx 8.0 )

More Information

The calculations reveal that with a reflux ratio of 3, the distillation column is efficient in separating benzene and toluene. The theoretical concepts used include the McCabe-Thiele method, which is vital in designing and understanding distillation operations.

Tips

  • Incorrectly plotting the equilibrium curve: Ensure accurate representation for reliable results.
  • Misunderstanding the use of reflux ratios: Always distinguish between minimum and actual reflux ratios, as they determine the efficiency of the separation process.

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