a) How many radial nodes will be present in 4d orbitals? b) What is the ratio of the radius of Bohr's first orbit in He+ and Li2+?

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Understand the Problem

The image contains two chemistry questions. The first requires calculating the number of radial nodes in a 4d orbital. The second asks for the ratio of the radii of Bohr's first orbit in He+ and Li2+ ions. We need to apply the formulas for radial nodes and Bohr's radius to solve these.

Answer

a) 1 radial node. b) 3/2 or 1.5.

a) A 4d orbital has 1 radial node. b) The ratio of the radius of Bohr's first orbit in He+ and Li2+ is 3/2 or 1.5.

Answer for screen readers

a) A 4d orbital has 1 radial node. b) The ratio of the radius of Bohr's first orbit in He+ and Li2+ is 3/2 or 1.5.

More Information

The number of radial nodes increases as the principal quantum number (n) increases for a given type of orbital. The radius of the Bohr orbit decreases with increasing nuclear charge (Z).

Tips

A common mistake is to confuse the values of n and l. Remember that for a 'd' orbital, l = 2.

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