Unit 6

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Questions and Answers

Excess sulfite is necessary to prevent:

  • pitting (correct)
  • acidity
  • carry over
  • hardness

Mixing ethylene glycol with propylene glycol can cause:

  • organic acids to form
  • biological fouling
  • premature freezing to occur
  • inhibitors to precipitate out (correct)

This type of corrosion occurs when two dissimilar metals are in electrical contact with one another and surrounded by an electrolyte:

  • high temperature corrosion
  • electrochemical corrosion
  • galvanic corrosion (correct)
  • intergranular corrosion

Solids fouling in a chiller system can usually be avoided by the use of:

<p>strainers or filters (D)</p> Signup and view all the answers

Two methods mostly used for cycle control are:

<p>makeup proportional blowdown and conductivity based blowdown (C)</p> Signup and view all the answers

This is a measure of the amount of calcium and magnesium ions present in the water:

<p>hardness (D)</p> Signup and view all the answers

A low cost way to remove suspended solids, normally associated with ground water, is by use of a:

<p>settling pond (A)</p> Signup and view all the answers

A method of treatment, which is often used in conjunction with settling tanks, is:

<p>filtration (D)</p> Signup and view all the answers

Scaling in cooling towers is not as severe as in boilers because:

<p>the operating temperatures are much lower (A)</p> Signup and view all the answers

Heat exchangers that use water to cool a process fluid are known as:

<p>chillers (C)</p> Signup and view all the answers

Foaming of water in the boiler:

<p>can be controlled by the continuous blow downs (B)</p> Signup and view all the answers

As water freezes, its volume expands by about:

<p>9% (D)</p> Signup and view all the answers

What type of chemical is fed into a boiler system using a gravity drip feeder:

<p>powdered or liquid (D)</p> Signup and view all the answers

Dissolved solids in raw water:

<p>can cause hot spots or scale (C)</p> Signup and view all the answers

Boiler water with a pH of 6 is considered:

<p>acidic (A)</p> Signup and view all the answers

Chemicals are usually fed to a water tube boiler:

<p>with a small positive displacement pump (A)</p> Signup and view all the answers

When cooling water evaporates it tends to:

<p>leave dissolved solids behind (B)</p> Signup and view all the answers

Neutralizing amines work by doing this:

<p>increasing the pH (B)</p> Signup and view all the answers

The addition of sulphites to remove oxygen in boiler water is known as:

<p>scavenging (C)</p> Signup and view all the answers

Which of the following is an example of suspended solids?

<p>sand (A)</p> Signup and view all the answers

The maintenance of the appropriate ratio of dissolved solids in the circulation water to the dissolved solids in the make-up feedwater is known as:

<p>Cycling control (B)</p> Signup and view all the answers

Mechanical deaeration:

<p>removes the dissolved gases from the water (B)</p> Signup and view all the answers

Corrosion coupons used in cooling and heating systems should be removed and tested every:

<p>one to three months (B)</p> Signup and view all the answers

When handling corrosion coupons it is important to:

<p>avoid touching them with your bare hands (D)</p> Signup and view all the answers

To prevent solids of chlorides, silica, and iron from entering the boiler system the condensate passes through a:

<p>condensate polisher (D)</p> Signup and view all the answers

This type of corrosion control is not volatile and is injected directly into the steam line:

<p>filming amines (A)</p> Signup and view all the answers

This is commonly added to water to prevent freezing during low temperatures:

<p>glycol (B)</p> Signup and view all the answers

Corrosion products in feedwater can cause:

<p>sludge formation (C)</p> Signup and view all the answers

Biological attacks on cooling tower wood mainly occurs as deterioration of the:

<p>cellulose (C)</p> Signup and view all the answers

Total alkalinity must be kept below a maximum level to avoid: (Select all that apply)

<p>corrosion (A), carryover (B), caustic embrittlement (C)</p> Signup and view all the answers

The two main types of glycol used to prevent freezing in operating plants are:

<p>ethylene and propylene (C)</p> Signup and view all the answers

Sludge conditioning in a boiler:

<p>prevents the sludge precipitates from adhering to the boiler plates and tubes (B)</p> Signup and view all the answers

One disadvantage of glycol in a system is:

<p>corrosion is increased in the presence of oxygen (A)</p> Signup and view all the answers

The regenerant used to regenerate an anion demineralizer is:

<p>caustic soda (sodium hydroxide) (D)</p> Signup and view all the answers

A common metal used for sacrificial anodes is:

<p>zinc (B)</p> Signup and view all the answers

This can be seen as a measure of how easily an electron can be removed from the metal:

<p>electrochemical potential (C)</p> Signup and view all the answers

A measure of the cloudiness of the water is known as:

<p>turbidity (C)</p> Signup and view all the answers

Which of the following are the primary condensate tests operators should perform? (Select all that apply)

<p>pH (A), corrosion byproducts (B), silica (C), conductivity (D)</p> Signup and view all the answers

Cooling towers by design use:

<p>lots of water (D)</p> Signup and view all the answers

In order to prevent the waste of steam through a deaerator vent, the component used is:

<p>a vent condenser (C)</p> Signup and view all the answers

Flashcards

Pitting Prevention

Excess sulfite prevents corrosion that creates small holes.

Glycol Mixing Issues

Mixing these glycols can cause corrosion inhibitors to come out of solution.

Galvanic Corrosion

Corrosion caused by electrical contact between different metals in an electrolyte.

Preventing Solids Fouling

Strainers or filters in a chiller system prevent solids fouling.

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Cycle Control Methods

Two methods used for cycle control are makeup proportional blowdown and conductivity-based blowdown.

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Water Hardness

A measure of calcium and magnesium ions; causes scale.

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Sedimentation

Settling ponds are a low-cost method for ground water suspended solids removal.

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Filtration

A treatment method with settling tanks, that removes suspended solids in water.

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Cooling Tower Scaling

Lower temps mean scale forms less in cooling towers compared to boilers.

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Chillers

Heat exchangers that use water to cool process fluids.

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Boiler Anti-Foaming Strategy

Foaming can be controlled by using repeated or steady blowdowns.

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Water Expansion on Freezing

As water freezes, it expands by approximately 9% in volume.

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Gravity Drip Feeder Chemicals

Chemicals used are either powdered or liquid.

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Effects of Dissolved Solids

Dissolved solids in raw water can form scale and cause hot spots.

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Condensate Tests

The primary condensate water tests are conductivity and pH.

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Study Notes

Preventing Issues with Sulfite

  • Excess sulfite prevents pitting.

Glycol Mixtures

  • Mixing ethylene glycol with propylene glycol causes inhibitors to precipitate out.

Galvanic Corrosion

  • Galvanic corrosion occurs when two dissimilar metals are in electrical contact in the presence of an electrolyte.

Avoiding Solid Fouling

  • Using strainers or filters avoids solids fouling in a chiller system.

Cycle Control Methods

  • Makeup proportional blowdown and conductivity based blowdown are used for cycle control.

Hardness Measurement

  • Hardness measures the amount of calcium and magnesium ions in water.

Suspended Solids Removal

  • Using a settling pond is a low-cost way to remove suspended solids, usually from groundwater.

Treatment Methods with Settling Tanks

  • Filtration is often used with settling tanks.

Scaling Differences

  • Scaling is less severe in cooling towers than in boilers because the operating temperatures are much lower.

Heat Exchangers

  • Heat exchangers that use water to cool a process fluid are chillers.

Boiler Foaming

  • Foaming of water in the boiler can be controlled by continuous blowdowns.

Water Expansion Upon Freezing

  • As water freezes, its volume expands by about 9%.

Chemical Feed Method

  • Powdered or liquid chemicals are fed into a boiler system using a gravity drip feeder.

Effects of Dissolved Solids

  • Dissolved solids in raw water can cause hot spots or scale.

pH of Boiler Water

  • Boiler water with a pH of 6 is acidic.

Chemical Feeding in Water Tube Boilers

  • Chemicals are usually fed to a water tube boiler using a small positive displacement pump.

Effects of Cooling Water Evaporation

  • When cooling water evaporates, it leaves dissolved solids behind.

Neutralizing Amines

  • Neutralizing amines work by increasing the pH.

Oxygen Removal in Boiler Water

  • Adding sulfites to remove oxygen in boiler water is known as scavenging.

Suspended Solids Example

  • Sand is an example of suspended solids.

Ratio Maintenance

  • Maintaining the appropriate ratio of dissolved solids in the circulation water to the dissolved solids in the make-up feedwater is cycling control.

Mechanical Deaeration

  • Mechanical deaeration removes dissolved gases from the water.

Corrosion Coupon Testing

  • Corrosion coupons in cooling and heating systems should be tested every one to three months.

Handling Corrosion Coupons

  • When handling corrosion coupons, avoid touching them with bare hands.

Prevention in Boiler Systems

  • To prevent solids of chlorides, silica, and iron from entering the boiler system, condensate passes through a condensate polisher.

Corrosion Control

  • Film-forming amines are a type of corrosion control that is not volatile and are injected directly into the steam line.

Preventing Freezing

  • Glycol is commonly added to water to prevent freezing during low temperatures.

Feedwater Corrosion Products

  • Corrosion products in feedwater can cause caustic embrittlement.

Biological Attacks on Cooling Towers

  • Biological attacks on cooling tower wood mainly occur as deterioration of the cellulose.

Avoiding Total Alkalinity

  • Total alkalinity must be kept below a maximum level to avoid corrosion, caustic embrittlement, and carryover.

Types of Glycol

  • The two main types of glycol used to prevent freezing in operating plants are ethylene and propylene.

Conditioning Boilers

  • Sludge conditioning in a boiler prevents sludge precipitates from adhering to the boiler plates and tubes.

Concerns in Systems

  • One disadvantage of glycol in a system is that corrosion is increased in the presence of oxygen.

Demineralizers

  • Sodium hydroxide (caustic soda) regenerates an anion demineralizer.

Sacrificial Anodes

  • Zinc is a common metal used for sacrificial anodes.

Electron Removal

  • Electrochemical potential measures how easily an electron can be removed from a metal.

Water CLoudiness

  • Turbidity measures the cloudiness of water.

Condensate Tests

  • Conductivity and pH are primary condensate tests operators should perform.

Cooling Towers

  • Cooling towers by design use lots of water.

Preventing Steam Waste

  • In order to prevent the waste of steam through a deaerator vent, a vent condenser is used.

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