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Questions and Answers

What property of water allows it to dissolve polar molecules effectively?

  • Its small molecular size (correct)
  • Its adhesive properties
  • Its hydrogen bonds
  • Its high viscosity
  • Which process describes the movement of water across a selectively permeable membrane?

  • Adhesion
  • Capillary action
  • Osmosis (correct)
  • Diffusion
  • What happens to the density of water as the temperature decreases below 4°C?

  • It becomes less dense than warmer water (correct)
  • It remains constant
  • It becomes more dense than most liquids
  • It solidifies immediately
  • Which statement about capillary action is true?

    <p>It allows water to climb against gravity.</p> Signup and view all the answers

    What is the term for the attraction of water to other surfaces or substances?

    <p>Adhesion</p> Signup and view all the answers

    What percentage of Earth's surface is covered by water?

    <p>75%</p> Signup and view all the answers

    What unique structural feature characterizes a water molecule?

    <p>It has a widened 'V' shape</p> Signup and view all the answers

    Why is water considered a polar molecule?

    <p>Due to the unequal sharing of electrons between hydrogen and oxygen</p> Signup and view all the answers

    What property of water is primarily responsible for its high specific heat?

    <p>Weak hydrogen bonds</p> Signup and view all the answers

    What is the effect of cohesion in relation to surface tension in water?

    <p>It enhances surface tension</p> Signup and view all the answers

    Study Notes

    Water Statistics

    • Covers 75% of Earth’s surface
    • 97% of water on Earth is found in oceans
    • 3% is freshwater
      • 2% of water on Earth is in ice caps and glaciers
      • 1% is found in lakes, underground, or in the atmosphere (usable by humans)
    • Makes up 70% of the human body
      • 92% of blood plasma
      • 80% of muscle tissues
      • 60% of red blood cells

    Molecular Structure of Water

    • For every water molecule, two hydrogen atoms bond to one oxygen atom by a covalent bond.
    • Water molecules are not symmetrical
    • Shape resembles a widened “V”
    • Electrons spend more time closer to oxygen (O) and less time near hydrogen (H)

    Polarity of Water

    • Oxygen atom is larger than hydrogen atoms, meaning oxygen atoms tend to “share” electrons more than hydrogen atoms.
    • Oxygen is more electronegative, so the region around oxygen has a partial negative charge.
    • The region around the two hydrogen atoms has a partial positive charge.
    • Water molecules are polar molecules, meaning opposite ends of the molecule have opposite charges.

    Hydrogen Bonding

    • The slightly negative regions of one water molecule are attracted to the slightly positive regions of nearby molecules.
    • This creates a hydrogen bond.
    • Hydrogen bonds hold water molecules together.
    • Each water molecule can form a maximum of 4 hydrogen bonds.
    • Hydrogen bonds are weak, about 1/20th as strong as covalent bonds.
    • Hydrogen bonds constantly form, break, and reform.
    • This provides water with its extraordinary properties

    Cohesion

    • Attraction between water molecules through hydrogen bonds.
    • Leads to:
      • Surface Tension: Attraction between water molecules at the surface of the liquid.
      • High Specific Heat: Water requires a large amount of energy to warm up and a long time to cool down.
      • Viscosity: Resistance to flow, caused by cohesion between molecules.

    Surface Tension

    • Resistance of a liquid to an increase in surface area.
    • Caused by hydrogen bonds in H2O.
    • Example: A paperclip can float on water due to surface tension.
    • Water has the highest surface tension of all liquids except mercury.

    Adhesion

    • Attraction of water to other surfaces/substances.
    • Leads to:
      • Water as a "Universal Solvent." Water only dissolves polar molecules.
      • Capillary Action Water's ability to climb objects against gravity.

    Universal Solvent

    • Solvent: substance that dissolves other substances.
    • Water dissolves more substances than any other natural substance.
    • Properties of Solvents:
      • Interacts with other polar compounds
      • Is repelled by non-polar compounds
      • Small size allows for saturation of areas
      • Can convey other substances in solutions

    Capillary Action

    • Water "climbs" objects against gravity.
    • Wettable surfaces cause a film of water to cling to the surface.
    • Capillary action is important for soil and plant/water relations.

    Diffusion

    • Movement of a substance from an area of high concentration to an area of lower concentration.

    Osmosis

    • The net movement of water across a selectively permeable membrane driven by a difference in solute concentrations on the two sides of the membrane.
    • Water moves from the area of low solute concentration to the area of high solute concentration until equilibrium is reached.

    Heat Effect on Water Density

    • As heat decreases, kinetic energy of molecules decreases, causing molecules to come closer together.
    • Most liquids become denser as they cool.
    • However, water becomes slightly less dense at 4°C and below.
    • This is because as water molecules get closer together, they begin to repel each other.
    • Water molecules "organize" with hydrogen bonds as it freezes, forming hexagon shapes.
    • The temperature of a substance is a measure of the average kinetic energy of the particles in a sample of matter.

    Zeroth Law of Thermodynamics

    • Two systems are in thermal equilibrium only if they have the same temperature.
    • Two systems in thermal equilibrium with a third system are also in thermal equilibrium with each other.

    Heat is Defined as Energy

    • Heat is thermal energy absorbed or released.
    • Unit of heat is the calorie (1 cal). It’s the quantity of heat required to raise the temperature of 1 g of water by 1°C.
    • In an enclosed system, the amount of heat lost is equal to the amount of heat gained (Conservation of Energy).

    Heat Capacity

    • Quantity of heat required to raise the temperature of the entire body by one degree.

    Specific Heat Capacity (C)

    • Amount of heat (Q) needed to raise the temperature (t) of a unit mass (m) by a unit degree.
    • Specific Heat Capacity formula: C = Q / (m Δt) or Q = m c Δt
    • Unit is cal/g °C

    Change of Phase

    • When a change of phase occurs, there is only a change in the potential energy of the molecules.
    • Temperature remains constant during the phase change.
    • The quantity of heat Q required to change the phase of a substance is given as Q = m L.
    • Latent heat (L) is the quantity of heat per unit mass needed to change a substance from one phase to another.
    • L = Q / m

    Hydrotherapy

    • Treatment of disease by using water at different temperatures and in different ways.
    • Encompasses various approaches and therapeutic methods that utilize the physical properties of water (temperature, pressure) for therapeutic purposes.
    • Important physical laws of water for physiotherapists to understand: buoyancy and hydrostatic pressure.
    • Therapeutic uses: superficial heating and cooling, wound care, water exercise, pain control, edema control.

    Benefits of Water Therapy

    • Low impact, unlike land exercises.
    • Can be done even with injuries or pain.
    • Supportive for the body.
    • Reduced risk of falling.
    • Healing properties that aid in recovery.
    • Reduces swelling.
    • All exercises engage the whole body.
    • No soreness or stiffness after sessions.
    • Turbulence provides a massage.
    • Increased resistance, resulting in harder work and slower, more precise movements.
    • More efficient muscle use.
    • Great for back pain.
    • Safe environment, especially for those with balance problems.

    Quiz (1):

    • Problem 1: Calculate the heat required to heat a 500g copper coffee mug and 200g of coffee from 20 °C to 96 °C.
    • Problem 2: Determine the mass of copper shot heated to 90°C and dropped into 80g of water at 10°C, if the equilibrium temperature is 18°C.
    • Problem 3: Calculate the heat needed to convert 10g of ice at -20°C to steam at 100°C.
    • Problem 4: Determine how much ice at 0°C must be mixed with 4g of steam at 100°C to produce water at 60°C.

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