X-ray Photoelectron Spectroscopy Basic Theory
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Questions and Answers

In X-ray Photoelectron Spectroscopy (XPS), what does the kinetic energy of the emitted electron depend on?

  • The chemical environment and the X-ray photon energy
  • The photon energy and the binding energy (correct)
  • The elemental composition of the surface and the chemical composition
  • The X-ray source and the energy required to remove the electron

What is the purpose of using a monochromatic X-ray source of a known energy in an XPS spectrometer?

  • To determine the chemical environment of the parent atom
  • To facilitate the chemical analysis using ESCA
  • To measure the binding energy of the emergent electron (correct)
  • To quantify the elemental composition of the surface

What does Kα in XPS refer to?

  • Chemical composition analysis
  • X-ray energy range
  • Electron transition to a vacancy in the innermost 'K' shell (correct)
  • Quantifying the chemical environment of the parent atom

What is the basis for quantifying not only the elemental composition of the surface, but also the chemical composition in XPS?

<p>Binding energy and photon energy (B)</p> Signup and view all the answers

Which concept from physics does X-ray Photoelectron Spectroscopy rely upon?

<p>Einstein's photoelectric effect (B)</p> Signup and view all the answers

What is the primary purpose of XPS (X-ray photoelectron spectroscopy)?

<p>To measure the kinetic energy of emitted electrons from the top surface of a material (C)</p> Signup and view all the answers

Why is ultra-high vacuum (UHV) required for XPS?

<p>To increase the photoelectron path length (A)</p> Signup and view all the answers

What type of analyzer is used for measuring the kinetic energy of emitted photoelectrons in XPS?

<p>Concentric hemispherical electron analyzer (A)</p> Signup and view all the answers

Why are the physical and chemical properties of the surface different from those of the bulk material?

<p>The surface atoms have more reactive bonding potential (B)</p> Signup and view all the answers

What types of samples are suitable for XPS analysis?

<p>Solid samples, powders, coatings, and thin films (B)</p> Signup and view all the answers

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