X-ray Analysis of Ionic Crystals
10 Questions
0 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Atomic radii are the measure of the size of the ______.

atom

The wave mechanical picture of an atom depicts an atom as composed of a compact nucleus surrounded by an ______.

electron cloud

The radius of an atom can be defined as the distance from the centre of the nucleus to the point where the ______ density is virtually zero.

electron

We can not have one set of atomic radii applicable under all ______.

<p>conditions</p> Signup and view all the answers

Pertaining to the four major types of bonding, the atomic radii to be measured are: ______ radius.

<p>covalent</p> Signup and view all the answers

It is possible to determine the distance between the nuclei of bonded atoms by employing ______ and electron diffraction techniques.

<p>Spectroscopic or X-ray</p> Signup and view all the answers

The ______ radius is measured when an atom is occupying a lattice site of the crystal.

<p>crystal or metallic</p> Signup and view all the answers

The size of a neutral atom will be different from the one when it is present as a ______ or anion.

<p>cation</p> Signup and view all the answers

The ______ radius is measured when an atom is colliding with another atom in the gaseous state.

<p>Vander Waals</p> Signup and view all the answers

The atomic radii are important because other atomic properties like ______ energy, electron affinity and electronegativity are related to them.

<p>ionization</p> Signup and view all the answers

Study Notes

Ionic Radii

  • Ionic radii are estimated rather than measured accurately
  • There are two types of ionic radii: cation radii and anion radii
  • Cations are generally smaller than anions, except for rubidium and caesium cations
  • Ionic radii are influenced by the loss of electrons from the outer shell and the increase in overall positive charge

Factors Affecting Atomic Radii

  • The principal quantum number (n) affects atomic radii
  • The effective nuclear charge (Z*) also affects atomic radii
  • A higher effective nuclear charge results in a smaller radius

Atomic Radii

  • Atomic radii are the measure of the size of an atom
  • Atomic radii are important because they relate to other atomic properties like ionization energy, electron affinity, and electronegativity
  • The wave mechanical picture of an atom depicts an atom as a compact nucleus surrounded by an electron cloud

Measurement of Atomic Radii

  • Atomic radii can be defined as the distance from the centre of the nucleus to the point where the electron density is virtually zero
  • Measuring atomic radii is problematic due to variations in bonding conditions
  • Four types of atomic radii can be measured: covalent radius, crystal or metallic radius, van der Waals radius, and ionic radius

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Description

This quiz covers the analysis of ionic crystals using X-ray technology to determine ionic radii and internuclear distances.

More Like This

Use Quizgecko on...
Browser
Browser