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Questions and Answers

الفرق في الكهربية السالبة بين الذرات في الرابط التساهمي غير القطبي يساوي صفر.

True

الرابطة الأيونية تتشكل بين الذرات ذات الفرق في الكهربية السالبة أقل من 2.

False

جميع الهالوجينات لها تأثير سالب (-I).

True

الكربوكاتيونات هي أنواع مشحونة إيجابياً ونوع الكربون مت hybridized sp2.

<p>False</p> Signup and view all the answers

تؤثر التأثيرات الاستقرائية عبر روابط سيغما على مسافات طويلة.

<p>False</p> Signup and view all the answers

Study Notes

Organic Chemistry I - Introduction & Alkanes

  • Course: Organic Chemistry I
  • Topic: Introduction & Alkanes
  • Content: Questions and answers related to organic chemistry concepts, particularly regarding alkanes.
  • Questions Type: True or False statements about various organic chemistry topics.

Questions & Answers

  • Question 1: The order of increasing electronegativity of halogens is F > Cl > Br > I.

  • Answer: False

  • Question 2: All metals are electropositive elements.

  • Answer: True

  • Question 3: The difference in electronegativity (EN) between atoms in a non-polar covalent bond is zero.

  • Answer: True

  • Question 4: Examples of -I effect atoms or groups include F, Cl, OH, NH2 etc.

  • Answer: True

  • Question 5: Mesomeric effect occurs in saturated systems.

  • Answer: False

  • Question 8: Carbanions are negatively charged species and Sp3 hybridized carbons.

  • Answer: True

  • Question 9: Alkyl groups exhibit +I effect.

  • Answer: True

  • Question 10: Inductive effect occurs via π bond orbital.

  • Answer: False

  • Question 11: In a non-polar covalent bond, the more electronegative atom acquires a partial negative charge.

  • Answer: True

  • Question 12: Van der Waals forces hold uncharged molecules together in liquids or solids.

  • Answer: True

  • Question 13: Organic Chemistry studies carbon compounds that affect all living things.

  • Answer: True

  • Question 14: EN is the ability of an atom to attract electrons.

  • Answer: True

  • Question 15: An ionic bond forms between atoms with a difference in EN less than 2.

  • Answer: False

  • Question 16: Electronegativity increases as you move down a group in the periodic table.

  • Answer: False

  • Question 17: The left column in the periodic table (Groups 1 & 2) are termed electronegative elements.

  • Answer: False

  • Question 18: The difference in EN between atoms in a polar covalent bond is zero.

  • Answer: False

  • Question 19: Examples of -I effect atoms include F, Cl, and alkyl groups.

  • Answer: True

  • Question 20: Inductive effect involves sigma bonds.

  • Answer: True

  • Question 21: Nucleophiles are electron-loving species.

  • Answer: True

  • Question 22: Carbanion stability follows the order: CH3 < RCH2 < R2CH < RC.

  • Answer: True

  • Question 23: Mesomeric effects can be transmitted through large conjugated systems.

  • Answer: True

  • Question 24: Free radical carbons are electrically neutral and highly reactive.

  • Answer: True

  • Question 25: In polar covalent bonds, the more electronegative atom gains a partial negative charge.

  • Answer: True

  • Question 26: Inductive effect depends on the electronegativity of atoms in the covalent bond.

  • Answer: True

  • Question 27: Electropositive elements exhibit -I effect.

  • Answer: False

  • Question 30: Nucleophiles attack carbons with high electron density.

  • Answer: True

  • Question 31: All halogens display -I effect.

  • Answer: True

  • Question 32: Mesomeric effect occurs in unsaturated molecules.

  • Answer: True

  • Question 34: Nucleophiles attack carbons with low electron density.

  • Answer: True

  • Question 35: Carbocations are positively charged species and are Sp3 hybridized.

  • Answer: False

  • Question 36: In heterolytic cleavage, each atom gains two electrons.

  • Answer: False

  • Question 37: Inductive effects are transmitted over short distances.

  • Answer: True

  • Question 38: Hydrogen bonds occur between a carbon atom and highly electronegative atoms (e.g., F, O, N).

  • Answer: True

  • Question 39: Electronegativity generally decreases across a period from left to right.

  • Answer: False

  • Question 40: Ionic bonds form between atoms with large differences in electronegativity (EN > 2).

  • Answer: True

  • Question 41: Electronegativity is the ability of an atom to attract electrons.

  • Answer: True

  • Question 43: Carbocation stability order: tertiary > secondary > primary.

  • Answer: True

  • Question 44: The bond angle for Sp3 hybridized carbons is 120 degrees.

  • Answer: False

  • Question 45: Free radical carbons are electrically neutral with low reactive species.

  • Answer: True

  • Question 46: In homolytic cleavage, each atom in the covalent bond gets one electron.

  • Answer: False

  • Question 47: Inductive effect occurs in unsaturated molecules.

  • Answer: False

  • Question 48: In polar covalent bonds, the less electronegative atom acquires a partial positive charge.

  • Answer: True

  • Question 49: Carbocations are positively charged species and are Sp2 hybridized.

  • Answer: True

  • Question 50: The bond angle for Sp2 hybridized carbons is 109.3 degrees.

  • Answer: False

  • Question 51: Electronegativity usually decreases down a group in the periodic table.

  • Answer: True

  • Question 52: The difference in EN between atoms in a polar covalent bond is greater than 2.

  • Answer: False

IUPAC Nomenclature (Page 5)

  • IUPAC names for various organic structures provided as example structures.

IUPAC Naming of Incorrect Structures (Page 6)

  • Correction of incorrectly named organic structures, with the correct IUPAC names given as answers.

Drawing Organic Structures (Page 6 & 7)

  • Step-by-step instructions to determine the structures for organic compounds.

Organic Reactions (Page 8 & 9):

  • Summary of reaction types: Types of organic reactions (e.g., elimination, substitution, addition, free radical) and reaction conditions are shown with examples.

Stability of Organic Structures (Page 10):

  • Stability of structures: Ranking organic structures in terms of their decreasing stability are provided.

Type Reaction: synthesis of Organic Molecules

  • Methods: Details for synthesis methods of specific organic molecules (Corey-House, Wolf-Kishner, Clemmensen)

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