GEG 4101 Lecture 9

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Questions and Answers

What key factor limits chemical weathering in cold climates, overriding the direct influence of temperature?

The availability of moisture (water)

What type of weathering, often underestimated in periglacial environments, is found to be as effective as in non-periglacial areas?

Chemical weathering

How does the presence of permafrost specifically influence soil forming processes in periglacial regions?

It imparts a distinct character to soil forming processes.

What are the sources of acidity that are essential for promoting chemical weathering in periglacial regions?

<p>Carbonic acid, sulfuric acid, nitric acid, and organic acids</p> Signup and view all the answers

Explain how the oxidation of pyrite-rich rocks can drastically enhance weathering processes.

<p>It generates sulfuric acid</p> Signup and view all the answers

Describe the role of cold-adapted micro-organisms in weathering within periglacial regions.

<p>They play an important role.</p> Signup and view all the answers

How may warming permafrost affect the carbon sequestration ability of soils?

<p>It may increase this ability.</p> Signup and view all the answers

What is a primary influence of vegetation in periglacial regions on chemical weathering processes?

<p>Respired soil $CO_2$</p> Signup and view all the answers

Name a rock that produces sulfuric acids upon oxidation and greatly enhances weathering.

<p>Pyrite</p> Signup and view all the answers

What distinctive weathering characteristic is observed in polar desert environments like Devon Island, NU?

<p>Chemical weathering.</p> Signup and view all the answers

In the context of periglacial regions, differentiate between mechanical and chemical weathering concerning their importance.

<p>Mechanical weathering was thought to be more important, and chemical weathering was deemed minimal, though it is as effective as in non-periglacial regions.</p> Signup and view all the answers

What is the term used by Lozinski to describe a definitive element when he introduced the term "periglacial"?

<p>Frost shattering.</p> Signup and view all the answers

Based on the information, what role do bacteria and micro-organisms play in the $CO_2-CH_4$ cycle in cryotic soils?

<p>They facilitate the cycle.</p> Signup and view all the answers

What influence does cold climate have on the importance of moisture for chemical weathering?

<p>Moisture is the limiting factor.</p> Signup and view all the answers

Relate the oxidation of sulfide minerals with the formation of sulfuric acid, mentioning a specific mining area example.

<p>H2SO4 from the oxidation of sulfide minerals, FeS2 in particular in mining areas, contributes to the acidity</p> Signup and view all the answers

How do freeze-thaw cycles and radiation influence weathering in periglacial regions?

<p>They influence weathering frequency through the combination of solar radiation and surface offset.</p> Signup and view all the answers

How has the focus on microbiology in planetary science affected the research on biological weathering in periglacial regions?

<p>It has overshadowed it.</p> Signup and view all the answers

What process dominates soil forming processes in periglacial regions?

<p>The presence of permafrost.</p> Signup and view all the answers

What is the source of organic acids that contribute to the acidity required for chemical weathering?

<p>The generation of heterogeneous humic and fulvic acids as well low molecular weight fatty acids like acetic acid</p> Signup and view all the answers

What is the influence of dissolved carbon dioxide on the acidity required for chemical weathering?

<p>Carbonic acid is formed.</p> Signup and view all the answers

Describe a specific consequence of water limitation caused by permafrost on chemical weathering in soils.

<p>It inhibits chemical reactions.</p> Signup and view all the answers

Considering that "Time (there is lots of time...)" is a factor influencing weathering processes, in what way does this extended period specifically affect chemical weathering in periglacial regions?

<p>By allowing slow chemical processes to continue over extended durations.</p> Signup and view all the answers

How may an increase in microbial activity, potentially triggered by warming permafrost, influence a soil's properties about greenhouse gases?

<p>Increase the soils ability to function as a sink of GHGs.</p> Signup and view all the answers

What is meant by "Zonal Change in chemical weathering rates" in the context of cold climates, and what factors primarily influence this concept?

<p>It refers to expected variations in chemical weathering activity associated with climate and vegetation zones.</p> Signup and view all the answers

Define the term 'endolith' in the context of biological weathering of rocks, particularly in environments like the Dry Valleys.

<p>Endoliths are microorganisms that live inside rocks.</p> Signup and view all the answers

Given permafrost's role, describe how surface thaw might amplify specific chemical reactions near the active layer in periglacial contexts.

<p>It releases previously frozen water that can then act as a medium for chemical reactions.</p> Signup and view all the answers

In periglacial regions, how does cryoturbation, combined with the formation of organic acids, influence soil composition and weathering?

<p>They mix the soil and increase chemical activity.</p> Signup and view all the answers

What are some methods of removal of the sediments, which influence weathering processes in periglacial regions?

<p>Wind and water</p> Signup and view all the answers

In what kind of soils is formation of segregation ice more likely and why does it happen?

<p>Fine-grained soils; for reasons of ice grain sizes and ice formation processes</p> Signup and view all the answers

Briefly explain how the characteristics of lithology and porosity affect the weathering in periglacial regions.

<p>By dictating the pathways of water movement and its interactions with rock materials for both physical and chemical decay processes.</p> Signup and view all the answers

Summarize how the distribution of ground temperature influences weathering processes in periglacial environments.

<p>It dictates depth and rate of thaw which influences mechanical and chemical weathering processes.</p> Signup and view all the answers

What kind of gases do bacteria and micro-organisms in cryotic soils interact with?

<p>$CO_2-CH_4$</p> Signup and view all the answers

Is thermal conductivity high or low in periglacial regions?

<p>Low.</p> Signup and view all the answers

In what way does solar radiation influence weathering processes in periglacial regions?

<p>Solar radiation affects number of freeze-thaw cycles.</p> Signup and view all the answers

In the context of periglacial regions and weathering, what zone has the most mechanical weathering?

<p>Ground surface zone.</p> Signup and view all the answers

In the context of periglacial regions and weathering, what zone has a more balanced distribution of mechanical and chemical weathering?

<p>A zone just below the ground surface.</p> Signup and view all the answers

What is the name for an organism growing on sandstone in dry valleys?

<p>Endoliths.</p> Signup and view all the answers

How could microbial activity be useful in dealing with greenhouse gases?

<p>Microbial activity may increase soil's ability to function as a sink of greenhouse gases.</p> Signup and view all the answers

What are the three major categories of weathering?

<p>Physical, chemical and biological.</p> Signup and view all the answers

What are some of the components of physical weathering?

<p>Freezing process, ice segregation, frost heaving, frost wedging</p> Signup and view all the answers

Flashcards

What is Weathering?

The disintegration of rocks, soils, and minerals through direct contact with the atmosphere.

What is Weathering in periglacial regions?

Weathering processes that occur in regions with cold climates near glaciers.

What is physical weathering?

Physical disintegration of rocks without chemical change.

What is chemical weathering?

Chemical alteration of rocks through reactions with water, acids, and gases.

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What is biological weathering?

Breakdown of rocks by living organisms.

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What is the freezing process in weathering?

Water freezes and expands in cracks, breaking rocks.

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What is Ice segregation?

Growth of ice crystals that push soil and rocks apart.

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What is frost heaving?

Lifting of soil or rocks due to ice accumulation underneath.

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What is frost weathering?

Disintegration of rocks by repeated cycles of freezing and thawing of water in cracks.

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What limits chemical weathering in cold climates?

Moisture availability, not temperature, limits chemical weathering in cold climates.

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Acidity in Chemical Weathering

A source of acidity (H+) is needed to dissolve rock-forming minerals.

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What is carbonic acid's role in chemical weathering?

H2CO3 from dissolution of CO2 in soils.

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What is sulfuric acid in chemical weathering?

H2SO4 from oxidation of sulfide minerals.

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What is nitric acid in weathering?

HNO3 from NOx emissions.

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What are organic acids in chemical weathering?

Humic and fulvic acids, and low molecular weight fatty acids.

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How does PCO2 affect pH in soil water?

Partial pressure of CO2 in soil water affects pH and weathering rates.

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What limits chemical weathering in periglacial regions?

Limited by presence of water in thawed soils and vegetation.

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Chemical weathering: acid drainage

Pyrite-rich rocks produce sulfuric acids, enhancing weathering.

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Biological weathering in periglacial regions

Cold-adapted micro-organisms play a role in weathering.

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Microbial role in Cryotic Soils

Studies on bacteria and micro-organisms at low temperature to CO2-CH4 cycle in cryotic soils.

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Factors Influencing Weathering in Periglacial Regions

Lithology, porosity, water content, freeze-thaw cycles, water, organic acids, and time.

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Study Notes

Weathering in Periglacial Regions

  • The three weathering types are physical, chemical, and biological.

Physical Weathering

  • Includes the freezing process, ice segregation, frost heaving, and frost weathering with some geomorphic examples.

Chemical Weathering

  • Chemical weathering in periglacial climates is underestimated.
  • Cold regions were believed to be dominated by mechanical processes, since low temperatures inhibit chemical reactions.
  • Lozinski introduced "periglacial" and invoked frost shattering as a definitive element.
  • The presence of permafrost imparts a distinct character to soil forming processes.
  • Chemical weathering is just as effective as in non-periglacial regions.
  • In cold climates, moisture(water) availability is the limiting factor, not temperature.
  • Zonal changes in chemical weathering rates are apparent, associated with climate/vegetation zones.
  • Glacier, Barren land, Mountain Tundra, Lowland Tundra, and Northern Boreal forest are all climate/vegetation zones.
  • For chemical weathering to occur, a source of acidity (H+) is required to dissolve rock forming minerals.
  • Major sources of acidity in waters include carbonic acid (H2CO3), sulfuric acid (H2SO4), nitric acid (HNO3), and organic acids.
  • Carbonic acid comes from the dissolution of CO2gas in soils (oxidation of organics) or from geogenic sources including mantle and metamorphic CO2 in tectonic areas, pH @ 50% dissociation: 6.35.
  • Sulfuric acid comes from the oxidation of sulfide minerals, FeS2 in particular in mining areas, and from the oxidation of atmospheric SO2 from industrial sources and coal-fired power plants, pH @ 50% dissociation: <1.
  • Nitric acid comes from NOx emissions from industrial, automotive and power generating sources, pH @ 50% dissociation: <1.
  • Organic acids come from the generation of heterogeneous humic and fulvic acids in soils as well as low molecular weight fatty acids such as acetic [CH3COOH], pH @ 50% dissociation: 4.74.
  • In periglacial regions, chemical weathering is limited by presence of water in thawed soils (seasonal limitation) and vegetation (respired soil CO2).
  • Pyrite-rich rocks produce sulfuric acids that enhance weathering upon oxidation in acid drainage.
  • Formula: 2FeS2 + 7O2 + H2O = 4SO4 + 2Fe2+ + 4H+.
  • Chemical weathering occurs in a polar desert environment on Devon Island, NU.

Biological Weathering

  • Biological aspects of weathering in periglacial environments are thought to involve cold-adapted micro-organisms.
  • Few studies examine the role of life in weathering and geomorphic processes.
  • There is an increased number of studies that investigate the role played by bacteria and micro-organisms at low temperature to CO2-CH4 cycle in cryotic soils.
  • Examples include endoliths growing in sandstone in the Dry Valleys.

Summary of Weathering Processes

  • Includes the effects of lithology, porosity, thermal conductivity and water content, freeze/thaw cycles (solar radiation and surface offset), formation of segregation ice (fine grained soils), water, organic acids, and time.
  • Influenced by: Lithology / Porosity / thermal conductivity / water content, # freeze/thaw cycles (solar radiation and surface offset), Formation of segregation ice (fine grained soils), Water, organic acids, and Time .
  • Wind and water remove fine sediments
  • Cryoturbation also influences weathering
  • The ground near the surface is dominated by mechanical weathering; zone that is equally influenced by mechanical & chemical weathering.
  • The deeper ground is dominated by chemical weathering and the permafrost table.

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