Wave Motion and Heisenberg's Uncertainty Principle

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Questions and Answers

What mathematical relationship is established between group velocity and phase velocity?

  • Group velocity is the square of phase velocity.
  • Group velocity is inversely proportional to phase velocity.
  • Group velocity and phase velocity are independent of each other.
  • Group velocity is directly proportional to phase velocity. (correct)

What is the result of differentiating the equation $ rac{2 ext{π}}{k}$ with respect to $k$?

  • 2\text{π}
  • 0
  • -\frac{2 ext{π}}{k^2} (correct)
  • -\frac{2 ext{π}}{k}

In the equation $\omega = k.v$, what does $v$ represent?

  • Phase velocity of the wave (correct)
  • Wave number
  • Frequency of the wave
  • Wavelength of the wave

Which equation correctly expresses the substitution of wave number into the velocity equation?

<p>v = v - \lambda \frac{d\lambda}{dk} (B)</p> Signup and view all the answers

What does $d\lambda$ represent in the context of these equations?

<p>Change in wavelength (C)</p> Signup and view all the answers

What effect does an increase in group velocity have on phase velocity according to the content?

<p>Phase velocity increases proportionately. (C)</p> Signup and view all the answers

Which variable is NOT mentioned as being part of the relationships derived in the equations?

<p>Frequency (D)</p> Signup and view all the answers

What is the maximum uncertainty in position (Δx) of an electron within the nucleus?

<p>10 × 10^-15 m (D)</p> Signup and view all the answers

What is the overall conclusion derived from the equations about phase velocity and group velocity?

<p>They have a direct proportionality relationship. (B)</p> Signup and view all the answers

What is the derived minimum momentum (p) of the electron?

<p>0.527 × 10^-22 kg.s (B)</p> Signup and view all the answers

What is the mass of the proton and neutron as given in the content?

<p>1.67 × 10^-27 kg (A)</p> Signup and view all the answers

What is the calculated energy (E) of the electron needed to exist inside the nucleus?

<p>95.37 MeV (A)</p> Signup and view all the answers

Why can't electrons exist within the nucleus?

<p>Their energy is insufficient. (B)</p> Signup and view all the answers

What is the relation between eV and MeV as presented in the content?

<p>1 MeV = 1,000 eV (C)</p> Signup and view all the answers

What physical principle is applied when discussing the uncertainty in the position and momentum of the electron?

<p>Uncertainty Principle (A)</p> Signup and view all the answers

What is the significance of the value $h$ in the context of uncertainty?

<p>It is Planck's constant. (D)</p> Signup and view all the answers

What condition defines a free particle in the Schrödinger wave equation?

<p>V = 0 (D)</p> Signup and view all the answers

Which equation represents the relationship of energy in terms of frequency?

<p>E = hν (B)</p> Signup and view all the answers

In the time-dependent Schrödinger equation, what is represented by Ψ?

<p>The wave function of the particle (A)</p> Signup and view all the answers

What does the variable k represent in the context of wave properties?

<p>Wave number (D)</p> Signup and view all the answers

Upon rearranging the energy equation, what form does the wave function ψ take for a free particle?

<p>Ψ = A.e^(iωt) (D)</p> Signup and view all the answers

What is the relationship between angular frequency ω and energy E?

<p>ω = E/h (C)</p> Signup and view all the answers

In the context of particle motion, what does the equation ℏ = pλ indicate?

<p>Wavelength is inversely proportional to momentum (A)</p> Signup and view all the answers

What role does the constant A play in the wave function Ψ = A.e^(i(ωt - kx))?

<p>It indicates the amplitude of the wave function (D)</p> Signup and view all the answers

What does Heisenberg's uncertainty principle state about the relationship between position and momentum?

<p>An accurate measurement of one leads to uncertainty in the other. (C)</p> Signup and view all the answers

According to the uncertainty principle, if the position of a particle is known with zero uncertainty, what happens to the uncertainty in momentum?

<p>It cannot be measured. (B)</p> Signup and view all the answers

What is the mathematical expression representing Heisenberg's uncertainty principle?

<p>$Δx.Δp ≥ h / 4π$ (D)</p> Signup and view all the answers

What does the Heisenberg uncertainty principle imply about electrons in relation to atomic nuclei?

<p>Electrons cannot reside within the nucleus. (D)</p> Signup and view all the answers

When group velocity increases, what happens to phase velocity according to the principles discussed?

<p>Phase velocity increases proportionately. (C)</p> Signup and view all the answers

Which of the following scenarios illustrates the concept of uncertainty in the measurement of physical variables?

<p>Simultaneously determining the exact speed and position of a moving car. (D)</p> Signup and view all the answers

What does the $Δp$ represent in the context of Heisenberg’s principle?

<p>The uncertainty in the particle's momentum. (D)</p> Signup and view all the answers

If the uncertainty in momentum ($Δp$) is extremely small, what can be inferred about the uncertainty in position ($Δx$)?

<p>It will be infinitely large. (C)</p> Signup and view all the answers

What does the equation $\frac{\partial \Psi}{\partial x} = \frac{p}{\hbar} \Psi$ represent?

<p>The wave function's response to spatial changes (C)</p> Signup and view all the answers

Which term represents the total energy $E$ of a particle according to the content provided?

<p>The sum of kinetic energy and potential energy (D)</p> Signup and view all the answers

In the equation $E\Psi = -\frac{i\hbar}{\partial t}\Psi$, what does the $i$ signify?

<p>The imaginary unit indicating phase velocity (B)</p> Signup and view all the answers

What happens to the wave function when differentiating with respect to time?

<p>It demonstrates a change in energy with respect to time (B)</p> Signup and view all the answers

What role does the potential energy $U(x, t)$ play in the equation $E = \frac{p^2}{2m} + U(x, t)$?

<p>It varies based on position and time (D)</p> Signup and view all the answers

The rearranged equation $\frac{\partial \Psi}{\partial x} = -\frac{\hbar}{p}\Psi$ suggests what about the wave function?

<p>The wave function decreases with increasing momentum (C)</p> Signup and view all the answers

How does differentiating the wave function with respect to $x$ contribute to understanding the particle's behavior?

<p>It indicates the spatial distribution of the wave function (C)</p> Signup and view all the answers

What is the relationship defined by $E\Psi = \frac{p^2}{2m} \Psi + U(x, t)\Psi$?

<p>It relates energy and momentum to the wave function (D)</p> Signup and view all the answers

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Study Notes

Wave Motion and Velocity Relations

  • Rearrangement of ω = k.v leads to differentiation with respect to k.
  • Derivative results in the equation: ( \frac{d\omega}{dk} = v + k \frac{dv}{dk} ).
  • Utilizing the relationship between wave speed (v) and wave number (k) simplifies the equation.
  • Group velocity (v_g) relates directly to phase velocity (v_p): ( v_g = v_p - \lambda \frac{dv}{d\lambda} ).

Heisenberg's Uncertainty Principle

  • Proposed by Werner Heisenberg in 1927, it states that precise simultaneous measurement of position (Δx) and momentum (Δp) is impossible.
  • Mathematically represented as ( \Delta x \Delta p \geq \frac{h}{4\pi} ).
  • If the position is known precisely (Δx = 0), momentum becomes indeterminate (Δp = ∞).
  • Conversely, if momentum is accurately measured (Δp = 0), then position is uncertain.

Implications of the Uncertainty Principle

  • Implies challenges in experimental design to confirm wave-particle duality since measuring one variable affects the other.
  • Reinforces the probabilistic nature of quantum mechanics, focusing on likelihood rather than certainty.

Applications of the Uncertainty Principle

  • Non-existence of Electrons in Nuclei:

    • For an electron to reside in a nucleus (approximately 5 × 10⁻¹⁵ m), bounds on momentum lead to required energies (greater than 95.4 MeV), conflicting with observed energy limits (3-4 MeV).
  • Existence of Protons and Neutrons:

    • Similar calculations for protons and neutrons suggest stability within the nucleus despite constraints from uncertainty.

Schrödinger's Wave Equation

  • The one-dimensional time-independent Schrödinger equation connects kinetic energy, potential energy, and wavefunction Ψ.
  • The time-dependent equation relates an electron's movement to associated wave characteristics, represented as ( \Psi = A e^{i(kx - \omega t)} ).
  • Total energy (E) includes both kinetic and potential energy in a quantum context: ( E = \frac{p^2}{2m} + U(x, t) ).

Overall Concepts

  • The study of wave motion emphasizes the relationships between frequency, velocity, and wave number through differential equations.
  • The uncertainty principle lays the foundation for quantum mechanics, highlighting limitations in measurement and the nature of particles.
  • The Schrödinger equation forms a cornerstone of quantum theory, providing a mathematical framework for predicting particle behavior and interactions.

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