Water Solutions and Solubility Factors

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Questions and Answers

A solution is a ______ mixture of two or more components.

homogenous

The ______ is the substance being dissolved in a solution.

solute

In a solution, the ______ is the dissolving medium.

solvent

An ______ solution is one in which the solvent is water (H2O).

<p>aqueous</p> Signup and view all the answers

Solubility refers to the ability of a solute to ______ with a given solvent.

<p>dissolve</p> Signup and view all the answers

Sodium chloride is ______ soluble in water.

<p>very</p> Signup and view all the answers

The structure and polarity of the ______ affect its solubility.

<p>solute</p> Signup and view all the answers

Temperature and pressure are factors that affect ______.

<p>solubility</p> Signup and view all the answers

A solution of HCl is considered to be ______.

<p>ACIDIC</p> Signup and view all the answers

Each time the pH decreases by 1 pH unit, the concentration of H+ increases by ______ times.

<p>10</p> Signup and view all the answers

Lemon juice is classified as ______.

<p>ACIDIC</p> Signup and view all the answers

Pure water has a pH level that is considered ______.

<p>NEUTRAL</p> Signup and view all the answers

A solution of NaOH is classified as ______.

<p>BASIC</p> Signup and view all the answers

Water is considered to be ______, which allows it to dissolve polar solutes.

<p>polar</p> Signup and view all the answers

Sodium chloride (NaCl) crystals consist of positive metal ions such as sodium (Na+) and negative non-metal ions like ______.

<p>chloride</p> Signup and view all the answers

Vitamin A is considered to be ______ because it is soluble in fats and consists mainly of non-polar C-H bonds.

<p>non-polar</p> Signup and view all the answers

Vitamin C contains several ______ bonds, making it water soluble.

<p>polar O-H</p> Signup and view all the answers

Compounds that dissolve in water are often described as ______ due to their affinity for water.

<p>hydrophilic</p> Signup and view all the answers

Ethanol is a polar solute that contains ______ bonds.

<p>polar O-H</p> Signup and view all the answers

Substances that are generally ______ do not mix well with water and are called non-polar.

<p>non-polar</p> Signup and view all the answers

Glucose is a sugar that is soluble in water because it includes ______ bonds.

<p>polar O-H</p> Signup and view all the answers

OCTANE is an important component in ______.

<p>gasoline</p> Signup and view all the answers

NON-POLAR SOLUTES are referred to as '______'.

<p>HYDROPHOBIC</p> Signup and view all the answers

Both benzoic acid and acetic acid have the same '______' (-COOH) group.

<p>carboxylic acid</p> Signup and view all the answers

Benzoic acid is NOT SOLUBLE IN WATER due to its larger non-polar '______'.

<p>benzene portion</p> Signup and view all the answers

Soaps consist of FATTY ACIDS, which have a hydrophilic head and a hydrophobic '______'.

<p>tail</p> Signup and view all the answers

FATTY ACIDS maximize hydrogen bonding between their hydrophilic heads and ______.

<p>water</p> Signup and view all the answers

Fatty acids form structures known as '______'.

<p>MICELLES</p> Signup and view all the answers

LARGER NON-POLAR components are less soluble in water compared to smaller ______ components.

<p>polar</p> Signup and view all the answers

Hydrophilic molecules have more favorable interactions with ______ than with non-polar substances.

<p>water</p> Signup and view all the answers

Hydrophobic molecules are primarily made up of C-C and C-H ______.

<p>bonds</p> Signup and view all the answers

Water's interaction with polar (hydrophilic) molecules is as favorable as its interaction with ______ itself.

<p>water</p> Signup and view all the answers

The solubility of solids in water often ______ with increasing temperature.

<p>increases</p> Signup and view all the answers

PH is a measure of how ______ or BASIC a solution is.

<p>ACIDIC</p> Signup and view all the answers

A pH value of less than 7 indicates an ______ solution.

<p>ACIDIC</p> Signup and view all the answers

The solubility of some solids like sodium sulfate decreases with increasing ______.

<p>temperature</p> Signup and view all the answers

Interactions between water and hydrophobic molecules are not as strong as ______-water interactions.

<p>water</p> Signup and view all the answers

A pH value greater than 7 indicates a ______ solution.

<p>BASIC</p> Signup and view all the answers

After an oil spill, the oil, which is made of C-C and C-H ______, does not mix with water.

<p>bonds</p> Signup and view all the answers

Water is said to be ______ when it has a pH equal to 7.

<p>NEUTRAL</p> Signup and view all the answers

To determine the impact of temperature on solubility, it is important to examine it ______.

<p>experimentally</p> Signup and view all the answers

If the concentration of ______+ increases, the pH decreases.

<p>H</p> Signup and view all the answers

Each time pH decreases by 1 unit, the solution becomes ______ more acidic.

<p>10X</p> Signup and view all the answers

An acidic solution is one with a pH less than ______.

<p>7</p> Signup and view all the answers

PH is calculated using the formula pH = -log[H+], where ______+ represents the concentration of hydrogen ions.

<p>H</p> Signup and view all the answers

Flashcards

Solution

A homogeneous mixture of two or more components, where the components can be liquids, gases, or solids.

Solvent

The dissolving medium in a solution, usually the major component.

Solute

The substance being dissolved in a solution.

Aqueous Solution

A solution where water (Hâ‚‚O) is the solvent.

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Solubility

The ability of a solute to dissolve in a given solvent.

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Polarity (in solutions)

Similar polarity (both polar or both nonpolar) between solute and solvent creates better solubility.

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Factors affecting solubility

Solute structure, temperature, and pressure.

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Example of a solution

A combination of substances that mix evenly and are uniform throughout.

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Hydrophobic Molecule

A molecule that does not dissolve in water due to lacking attraction to water molecules.

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Polarity and Solubility

Polar substances dissolve well in polar solvents, and non-polar substances dissolve well in non-polar solvents. This is due to similar intermolecular forces.

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Benzoic Acid

A carboxylic acid with a large non-polar benzene portion, making it insoluble in water.

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Acetic Acid

A carboxylic acid with a smaller non-polar portion, making it soluble in water.

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Fatty Acid

A long-chain carboxylic acid with a polar head (-COOH) and a non-polar hydrocarbon tail.

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Micelle

A spherical structure formed by fatty acids in water, where the hydrophobic tails cluster together and the hydrophilic heads face outward.

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Hydrocarbon

A molecule made up of only carbon and hydrogen atoms, typically non-polar.

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Why do soaps work?

Soaps are made of fatty acids, which form micelles in water. The hydrophobic tails trap dirt and grease, while the hydrophilic heads interact with water, allowing the dirt to be washed away.

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What makes water a good solvent?

Water is a polar molecule, meaning it has a slightly positive and slightly negative end. This allows it to attract and dissolve other polar molecules and ionic compounds.

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Why are sugars soluble in water?

Sugars are polar molecules because they contain many polar hydroxyl (OH) groups. This makes them compatible with water's polarity, allowing them to dissolve.

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Why are salts soluble in water?

Salts are ionic compounds, meaning they are made up of positively charged ions (cations) and negatively charged ions (anions). Water molecules surround and separate these ions, dissolving the salt.

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What is a non-polar molecule?

A non-polar molecule has a balanced distribution of electrons, making it lack a positive and negative end. It doesn't have a strong attraction to water.

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Why is Vitamin A fat-soluble?

Vitamin A is mainly composed of non-polar C-H bonds, making it non-polar. It can only dissolve in other non-polar substances, like fats and oils.

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Why is Vitamin C water-soluble?

Vitamin C has several polar O-H bonds, making it a polar molecule. These polar bonds attract water molecules, enabling it to dissolve in water.

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What does 'hydrophilic' mean?

Hydrophilic means 'water-loving'. Substances that are hydrophilic dissolve easily in water due to their attraction to water molecules.

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What does 'hydrophobic' mean?

Hydrophobic means 'water-fearing'. Substances that are hydrophobic don't dissolve in water due to their lack of attraction to water molecules.

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Why Do Oils Float on Water?

Oil, composed largely of C-C and C-H bonds, is a hydrophobic molecule. Its interactions with water are weaker than water-water or water-polar solute interactions, causing it to float rather than mix.

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Impact of Temperature on Solubility

Temperature significantly affects the solubility of solids, liquids, and gases in water. Generally, increasing temperature increases solubility, but there are exceptions.

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Solubility of Solids with Temperature

The solubility of most solids in water increases with increasing temperature. However, specific solids like Na2SO4 and Ce2(SO4)3 exhibit decreased solubility with increasing temperature.

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Experimental Determination of Solubility

Determining the impact of temperature on solid solubility requires experimental observation. There's no universal prediction, so experiments are essential.

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Micelle Formation

Hydrophobic hydrocarbon tails of molecules cluster together within a micelle, while hydrophilic heads interact with surrounding water.

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Micelle Structure

Micelles form spherical structures where hydrophobic tails are shielded from water by hydrophilic heads, allowing for the solubilization of non-polar substances in water.

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pH

A measure of how acidic or basic a solution is. It is a scale ranging from 0 to 14, with 0 being the most acidic and 14 being the most basic.

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Acidic Solution

A solution with a pH value less than 7. It contains a higher concentration of hydrogen ions (H+).

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Basic Solution

A solution with a pH value greater than 7. It contains a lower concentration of hydrogen ions (H+).

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Neutral Solution

A solution with a pH value of 7. It contains an equal concentration of hydrogen ions (H+) and hydroxide ions (OH-).

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What is the effect of increasing [H+] on pH?

Increasing the concentration of hydrogen ions ([H+]) decreases the pH of a solution, making it more acidic.

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What is the effect of decreasing [H+] on pH?

Decreasing the concentration of hydrogen ions ([H+]) increases the pH of a solution, making it more basic.

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pH Scale is logarithmic

Each 1 unit change in pH represents a 10x change in the concentration of hydrogen ions.

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Ocean Acidification

The decrease in the pH of ocean water due to the absorption of carbon dioxide (CO2) from the atmosphere.

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pH Scale

A logarithmic scale used to express the acidity or basicity of a solution, with a range from 0 to 14. Lower pH values indicate a higher concentration of hydrogen ions (H+), making the solution acidic. Higher pH values indicate a lower concentration of H+, making the solution basic (alkaline). A pH of 7 is considered neutral.

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pH and Acidity/Basicity

A change in pH by 1 unit represents a tenfold change in the concentration of hydrogen ions (H+). For example, a solution with a pH of 2 is 10 times more acidic than a solution with a pH of 3.

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Examples of Acidic/Basic Substances

Substances can be classified as acidic, basic (alkaline), or neutral based on their pH. Examples of acidic substances include lemon juice, vinegar, and HCl solutions. Examples of basic substances include soap, NaOH solutions, and seawater. Pure water is considered neutral.

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pH Scale Advantage

The pH scale provides a convenient way to express acidity or basicity using simple numbers, rather than dealing with extremely large or small concentrations of hydrogen ions (H+).

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Logarithmic Scale

The pH scale is a logarithmic scale, meaning each whole number change represents a tenfold change in the concentration of hydrogen ions (H+).

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Study Notes

Water: Solutions

  • Solutions are homogeneous mixtures of two or more components.
  • Solution components can be liquids, gases, or solids.
  • Solvent is the dissolving medium (usually the major component).
  • Solute is the substance being dissolved.
  • An aqueous solution is a solution where the solvent is water.
  • Water is a common solvent.
  • Solubility is the ability of a solute to dissolve/mix with a given solvent.
  • Factors affecting solubility include solute molecule structure/polarity, temperature, and pressure.
  • Polar solutes dissolve in polar solvents (like water).
  • Non-polar solutes dissolve in non-polar solvents.

Water: Factors Affecting Solubility

  • Molecule structure/polarity affects solubility.
  • Polar solutes and solvents can form solutions. Examples include sugar and water.
  • Salt crystals (e.g., sodium chloride) dissolve in water because they're composed of positive and negative ions, surrounded by water molecules.
  • Non-polar solutes dissolve in non-polar solvents. Vitamin A is an example, as it's primarily composed of non-polar C-H bonds.
  • Fats and oils are primarily composed of C-H bonds.
  • Solubility of solids in water often increases with increasing temperature, but this is not always the case.
  • Solubility of gases in water generally decreases with increasing temperature.

Water: The pH Scale

  • pH is a measure of how acidic or basic a solution is.
  • The pH scale generally ranges from 0 to 14.
  • Acids have a pH < 7.
  • Bases have a pH > 7.
  • Water is neutral (pH = 7)
  • pH = -log[H+]
  • Each time pH decreases by 1 unit, the concentration of H+ increases by 10 times (or 10x more acidic).
  • Each time pH increases by 1 unit, the concentration of H+ decreases by 10 times (or 10x more basic).

Additional information

  • Soaps are composed of fatty acid molecules.
  • Fatty acids have a hydrophilic head (polar -COOH group) and a hydrophobic tail (non-polar hydrocarbon chain).
  • Fatty acids align to form micelles, maximizing interactions between hydrophilic heads and water and hydrophobic tails.
  • Pressure affects gas solubility. Increasing the pressure of a gas above a liquid increases the amount of gas dissolved in the liquid.
  • The amount of CO2 in the atmosphere affects the pH of the oceans, as higher CO2 levels lead to more acidic oceans.

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