Water Quality and Environmental Chemistry Quiz

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Questions and Answers

The presence of only anthropogenic compounds can alter the color of water.

False (B)

Decreasing the temperature of water will increase the solubility of gases like oxygen.

True (A)

The synergistic effect of temperature on water quality solely inhibits the proliferation of water organisms.

False (B)

Organic matter from natural sources are primarily non-biodegradable

<p>False (B)</p> Signup and view all the answers

Surfactants in detergents, being inorganic compounds, reduce the chemical oxygen demand (COD) of water.

<p>False (B)</p> Signup and view all the answers

Polychlorinated biphenyls (PCBs) are known for their instability at high temperatures.

<p>False (B)</p> Signup and view all the answers

Saturated hydrocarbons (alkanes) typically have a higher density than water.

<p>False (B)</p> Signup and view all the answers

The saturation level of oxygen in superficial water at 25°C is typically around 5.1 mg O2/L.

<p>False (B)</p> Signup and view all the answers

A total of 97.2% of the world's water is readily usable by humans.

<p>False (B)</p> Signup and view all the answers

The hydrological cycle is primarily driven by water condensation followed by precipitation.

<p>False (B)</p> Signup and view all the answers

Over the oceans, precipitation is higher than evaporation by 9%.

<p>False (B)</p> Signup and view all the answers

Covalent bonds in water are intermolecular and occur between hydrogen and oxygen atoms of different molecules.

<p>False (B)</p> Signup and view all the answers

Hydrogen bonds in water have a strength of approximately 100 kcal/mol.

<p>False (B)</p> Signup and view all the answers

The high electronegativity of hydrogen is the reason that hydrogen bonds form in water.

<p>False (B)</p> Signup and view all the answers

When temperature is decreased, hydrogen bonds in liquid water start to break.

<p>False (B)</p> Signup and view all the answers

The specific heat of water refers to the amount of heat required to increase the temperature of 1 g of water by 10°C.

<p>False (B)</p> Signup and view all the answers

Grit sedimentation rate is slower than putrescent organic solids sedimentation rate.

<p>False (B)</p> Signup and view all the answers

Water flow rate in grit chambers should be below the precipitation limit for sand particles and beneath the organic material precipitation limit.

<p>False (B)</p> Signup and view all the answers

In aerated grit chambers, air injection elevates the settling speed of organic substances.

<p>False (B)</p> Signup and view all the answers

Degreasing and de-oiling processes rely on skimmers and occasionally on air to remove oils and grease.

<p>True (A)</p> Signup and view all the answers

The presence of grease and oil in wastewater can ease sedimentation by attracting small organic particles.

<p>False (B)</p> Signup and view all the answers

An increase in the wastewater channel section increases velocity and hinders precipitation of solids.

<p>False (B)</p> Signup and view all the answers

Colloids, sized between 1 and 0.01 μm, settle rapidly by physical processes.

<p>False (B)</p> Signup and view all the answers

Adding electrolytes is used to stabilize the colloids in wastewater during the coagulation process by enhancing the existing repulsive forces.

<p>False (B)</p> Signup and view all the answers

Bag filters exhibit low sensitivity to variations in particle loads from the effluent.

<p>True (A)</p> Signup and view all the answers

The risk of fire or explosion is increased when using wet scrubbers with flammable particles.

<p>False (B)</p> Signup and view all the answers

In absorption, the driving force of the process lies in the equilibrium between the liquid and solid phases.

<p>False (B)</p> Signup and view all the answers

A suitable absorption liquid should ideally have high viscosity to enhance the transfer rate.

<p>False (B)</p> Signup and view all the answers

Bag filters are generally suitable for applications involving temperatures above 300 ºC.

<p>False (B)</p> Signup and view all the answers

According to Henry’s law, the molar fraction of a pollutant in the gas, y, is equal to $K * x $ where $x$ is molar fraction of the pollutant in the liquid and $K$ is a constant.

<p>True (A)</p> Signup and view all the answers

Packed towers are a type of dry collector used for removing particulate matter and gaseous pollutants.

<p>False (B)</p> Signup and view all the answers

Methanol and ethanol are examples of volatile organic compounds that cannot be effectively removed by absorption using water as the absorbent.

<p>False (B)</p> Signup and view all the answers

Batteries are managed by regular recollection services.

<p>False (B)</p> Signup and view all the answers

Density of waste materials is used for determining the collection volume levels required.

<p>True (A)</p> Signup and view all the answers

Humidity does not affect incineration treatments of waste.

<p>False (B)</p> Signup and view all the answers

Particle size distribution is critical for the separation of waste using sieves and magnetic separators.

<p>True (A)</p> Signup and view all the answers

The C/N ratio is unimportant for biological processes like composting.

<p>False (B)</p> Signup and view all the answers

The heating value of waste is not a key consideration for energy production.

<p>False (B)</p> Signup and view all the answers

Composting is a process that transforms organic materials under anaerobic conditions.

<p>False (B)</p> Signup and view all the answers

Non-fermentable materials like glass are an essential component for composting.

<p>False (B)</p> Signup and view all the answers

Composting in a closed system typically results in a longer fermentation period compared to an open system.

<p>False (B)</p> Signup and view all the answers

Maintaining moisture content above 70% is crucial for optimal compost quality.

<p>False (B)</p> Signup and view all the answers

A C/N ratio of 60% is ideal for cell synthesis and energy supply during composting.

<p>False (B)</p> Signup and view all the answers

The pH range for optimal composting should be maintained between 3 and 4.

<p>False (B)</p> Signup and view all the answers

Recycled glass loses its inherent properties after undergoing the recycling process.

<p>False (B)</p> Signup and view all the answers

During glass recycling, the final processing stage involves melting it at 1200 °C in furnaces.

<p>False (B)</p> Signup and view all the answers

Thermostable plastics can be softened by heat and are easily recyclable.

<p>False (B)</p> Signup and view all the answers

Polyvinyl chloride (PVC) is commonly recycled into polyester fibers and pillows.

<p>False (B)</p> Signup and view all the answers

Flashcards

Hydrological Cycle

The movement of water through the Earth's systems, including evaporation, precipitation, runoff, and storage.

Hydrogen Bonds

The attraction between water molecules, caused by the sharing of electrons between hydrogen and oxygen atoms.

High Specific Heat

The property of water that makes it resist changes in temperature. It takes a lot of heat to change the temperature of water.

Mineralization

The amount of dissolved salts in water. Low mineralization means fewer dissolved salts.

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Water as a Solvent

The ability of water to dissolve many substances, leading to diverse compositions in natural waters.

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pH of Water

A measure of acidity or alkalinity in water. Pure water has a pH of 7, acidic waters have a pH below 7, and alkaline waters have a pH above 7.

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Contaminated Water

Contamination of water by harmful substances, such as chemicals, bacteria, or viruses.

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Scarcity of Usable Freshwater

The amount of usable freshwater on Earth is very limited, making it a precious resource.

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Water Color

Water color can be affected by the presence of organic and inorganic compounds, either naturally occurring or from human activities.

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Urban Wastewater Color

Wastewater that has recently been discharged often appears grey, but as microorganisms break down the waste, it can turn black.

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Industrial Wastewater Color

Depending on the type of contaminant, industrial wastewater can exhibit a variety of colors.

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Water Temperature

Water temperature significantly impacts water quality by affecting gas solubility and microbial activity.

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Temperature and Gas Solubility

Increased water temperature reduces the solubility of gases like oxygen, which is vital for aquatic life.

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Temperature and Microbial Activity

Higher water temperatures accelerate microbial activity, influencing the speed of chemical reactions.

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Organic Matter in Water

Organic matter (OM) in water can be naturally derived from plants and animals or originate from urban/industrial sources. Naturally occurring OM is typically biodegradable, while urban/industrial sources may include both biodegradable and non-biodegradable compounds.

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Detergents and Water Quality

Detergents contain active agents called surfactants that create foam and increase the chemical oxygen demand (COD) due to their organic nature. Other ingredients like anti-calcareous agents and additives also contribute to the overall water quality.

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Grit Removal

The process of removing small, heavy solids like sand and grit from wastewater.

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Horizontal Flux Grit Chamber

A type of grit chamber where water flows horizontally, allowing heavier particles to settle.

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Vertical Flux Grit Chamber

A type of grit chamber where water flows vertically, allowing heavier particles to settle.

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Induced Flux (Aerated) Grit Chamber

A type of grit chamber that uses air injection to reduce the settling rate of organic material, making grit separation more effective.

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Degreasing and De-oiling

The process of removing oily or greasy substances from wastewater, typically using air and skimmers.

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Primary Treatment

A type of treatment that focuses on removing very small, suspended solids that were not removed during pre-treatment.

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Colloids

Particles so small they don't settle naturally and cause turbidity and color in wastewater.

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Coagulation-Flocculation

The process of adding chemicals to neutralize the charges on colloids, causing them to clump together and settle out.

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Filtration

A separation process where a solid-liquid mixture is separated by passing the mixture through a filter medium. The solid particles are retained on the filter, while the liquid passes through.

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Centrifugation

A separation process where a solid-liquid mixture is separated using a centrifuge. The heavier solid particles are forced to the outside of the centrifuge, while the lighter liquid remains in the center.

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Condensation

A separation process involving a change in phase of a substance. Typically, a gas or vapor is condensed into a liquid, separating it from other gases.

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Bag Filters

A separation process where a solid-gas mixture is separated by passing the mixture through a filter medium. The solid particles are retained on the filter, while the gas passes through. This process is often used for dust removal.

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Absorption

A separation process where a gas stream is contacted with a liquid to remove pollutants from the gas. The pollutants dissolve into the liquid, resulting in cleaner gas.

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Adsorption

A separation process where a gas stream is contacted with a solid material to remove pollutants from the gas. The pollutants adhere to the solid surface, resulting in cleaner gas.

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Incineration

A separation process where flammable or combustible gas is controlled by introducing excess oxygen and burning the gas at a high temperature.

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Catalytic Reduction

A separation process where a catalyst is used to promote a chemical reaction to remove pollutants from a gas stream.

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Special Waste Collection Points

Wastes that cannot be managed through regular collection services due to their potential for causing serious pollution problems.

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Waste Density

The measure of how compact a material is. It influences the size needed for collection vehicles and landfills.

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Waste Humidity

The amount of moisture in a waste material. It affects how the waste transforms and can cause issues with processes like incineration or leachate production.

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Waste Particle Size Distribution

The distribution of particle sizes in a waste material. This is important for separating different materials during recycling processes.

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Waste Biodegradability

The ability of organic materials in waste to break down naturally through biological processes.

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Waste Recycling

The process of recovering materials from waste to be used again in their original form or for a different application.

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Composting

The conversion of organic waste into a nutrient-rich soil amendment through biological processes under controlled aerobic conditions.

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Waste Heating Value

The amount of heat released during the complete combustion of a waste material. This is relevant for energy production.

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Fermentation Time in Composting

The time it takes for organic waste to break down into compost, influenced by the method used. Open systems, like piles, take longer (3-4 weeks) due to natural decomposition, while closed systems, like tumblers, are faster (1-2 weeks) because they control conditions.

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Temperature in Composting

A crucial factor in composting, temperature influences microbial activity and eliminates harmful organisms. The ideal range is between 50-70°C.

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Moisture in Composting

The amount of water in compost, essential for microbial activity and breakdown. Ideal moisture content is 40-60%.

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C/N Ratio in Composting

The ratio of carbon-rich materials (brown) to nitrogen-rich materials (green) in compost. It balances energy supply and nutrient availability for microbes, crucial for healthy decomposition.

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pH in Composting

The acidity or alkalinity of compost, affecting microbial activity. Ideal pH range is 5-7, similar to most soils.

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Compost Ripening

The process of storing composted material to refine its quality by promoting further decomposition and stabilization.

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Recyclability of Glass

The ability of glass to be recycled without degrading its properties. It can be processed repeatedly without losing quality.

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Thermoplastics

Materials that can be softened with heat, allowing them to be re-molded and recycled. Examples include PET and PVC.

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Study Notes

Unit 1: Water Pollution - Lecture 1

  • Characteristics of Natural Water: Over 97.2% of Earth's water is found in oceans, not usable by humans. Only about 0.6% of water is usable by humans (8.4 km3).
  • Hydrological Cycle: Water evaporates and later precipitates (approximately 5.2 x 105 km3/year) . 20% of the precipitation falls on continents.
  • Human Impact: Human activities, pollution and diseases can affect the water cycle's various areas (atmosphere, soil).
  • Covalent Bonds (H2O): Covalent bonds exist between hydrogen and oxygen atoms within a water molecule (approximately 100 kcal/mol).
  • Hydrogen Bonds (H2O): Hydrogen bonds form between water molecules (approximately 1-40 kcal/mol)

Characteristics and parameters of contaminated waters

  • Water Pollution: Water is contaminated when human activity alters its physical or chemical composition, preventing its use in its original natural state.
  • Types of Water Pollution:
    • Concentrated: pollution in a specific point source (e.g., industrial discharge).
    • Diffuse: pollution from multiple sources (e.g., agricultural runoff).
  • Physical Contaminants:
    • Total Matter: Matter in suspension or substances can be filtered out of the water.
      • Colour: affects sunlight penetration, causing sediment deposition.
      • Salinity, O2 solubility, Toxicity quantified by Matter in Suspension (MS), Solids in Suspension (SS), Dry Residue (DR) or Total Dissolved Solids (TDS), Fixed Residue.
    • Odour: Due to the breakdown of organic matter.
    • Colour: Due to the presence of organic or inorganic matter (natural or anthropogenic) - examples include wastewater (urban and industrial).
    • Temperature: Affects gas solubility and biological activity of microorganisms, influencing other properties of the water.

Chemical Contaminants

  • Organic Matter (OM): Sources are naturally occurring or due to human activities (urban/industrial). Some are biodegradable, some are not.
  • Examples: detergents, pesticides (e.g., DDT, chlorobenzene), organophosphates, carbamates, polychlorinated biphenyls (PCBs), and hydrocarbons (saturated and unsaturated).
  • Hydrocarbons: General characteristics including: low solubility in water, lower density than water and biodegradability, are toxic, and can form a layer on the water surface inhibiting oxygen diffusion. (Saturated alkane, unsaturated olefin, aromatic etc).

Biological Contaminants

  • Biological Contaminants: Microscopic and macroscopic organisms (animal, vegetal, protist).
    • Bacteria: are heterotrophic; they consume organic carbon (e.g. O.M., oxygen and water).
    • Algae: eutrophication.
    • Virus: parasites.
  • Biological Contamination Indicators: Coliform bacteria in animal/human intestines, microorganisms determination in water samples (biotic indices), Toxicity essays.

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