Water Hardness and Treatment Quiz
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Questions and Answers

What primarily causes temporary hardness in water?

  • Dissolved sulphates
  • Dissolved nitrates
  • Dissolved chlorides
  • Dissolved bicarbonates (correct)
  • Which process can effectively remove temporary hardness?

  • Filtering through zeolite
  • Adding sodium chloride
  • Chilling the water
  • Boiling the water (correct)
  • What is the primary characteristic of permanent hardness in water?

  • Presence of only magnesium salts
  • Presence of bicarbonates
  • Presence of dissolved chlorides and sulphates (correct)
  • Presence of organic compounds
  • Which of the following is a process to remove permanent hardness?

    <p>Lime soda process (C)</p> Signup and view all the answers

    What is the formula representing total hardness in water?

    <p>Temporary Hardness + Permanent Hardness (C)</p> Signup and view all the answers

    What impacts the crystallization of sugar during its refining process?

    <p>Presence of sulphates (D)</p> Signup and view all the answers

    Which salts are typically associated with permanent hardness?

    <p>Calcium chloride and magnesium sulphate (A)</p> Signup and view all the answers

    Why is calcium carbonate used as a standard in expressing hardness?

    <p>Its molecular weight is a whole number (B)</p> Signup and view all the answers

    What is a characteristic feature of secondary batteries?

    <p>They can be recharged by passing electricity. (C)</p> Signup and view all the answers

    Which type of battery acts both as a voltaic cell and as an electrolytic cell?

    <p>Lead acid storage battery (D)</p> Signup and view all the answers

    What material is the anode of a lead acid battery made of?

    <p>Lead (Pb) (C)</p> Signup and view all the answers

    During the discharging process, which ions are produced at the anode of a lead acid battery?

    <p>Pb2+ ions (D)</p> Signup and view all the answers

    What is formed at the anode when lead is oxidized during discharging?

    <p>PbSO4 (A)</p> Signup and view all the answers

    What component separates the lead plates in a lead acid battery?

    <p>Rubber or glass fiber (C)</p> Signup and view all the answers

    What solution are the electrodes of a lead acid battery immersed in?

    <p>20% H2SO4 (B)</p> Signup and view all the answers

    What happens to PbO2 during the charging process of a lead acid battery?

    <p>It is reduced to Pb2+ ions. (C)</p> Signup and view all the answers

    What chemical reaction occurs when dissolved oxygen attacks boiler material at high temperatures?

    <p>2Fe + 2 H2O + O2 → 2 Fe(OH)2 (B)</p> Signup and view all the answers

    Which compound is considered ideal for removing dissolved oxygen due to its product formation?

    <p>Hydrazine (A)</p> Signup and view all the answers

    Which method is used for the mechanical removal of dissolved gases like O2 and CO2?

    <p>Mechanical deaeration (A)</p> Signup and view all the answers

    What color does the solution turn when titrating with EDTA after adding EBT indicator to a standard hard water sample?

    <p>Steel blue (B)</p> Signup and view all the answers

    What happens to the solubility of gas in water when temperature increases?

    <p>Decreases (B)</p> Signup and view all the answers

    What is the purpose of boiling the water sample in the estimation of permanent hardness?

    <p>To reduce the volume to concentrate impurities (A)</p> Signup and view all the answers

    What is the process of removing common salt from water called?

    <p>Desalination (C)</p> Signup and view all the answers

    In the procedure for standardizing EDTA, what is mixed with the water sample before titration?

    <p>Buffer solution and EBT indicator (A)</p> Signup and view all the answers

    Which of the following is a reaction that forms carbonic acid from dissolved carbon dioxide?

    <p>CO2 + H2O → H2CO3 (D)</p> Signup and view all the answers

    What does the color change from wine red to steel blue indicate during the EDTA titration process?

    <p>The hardness has been fully titrated (A)</p> Signup and view all the answers

    What is the maximum ppm of dissolved solids that defines fresh water?

    <p>1000 ppm (A)</p> Signup and view all the answers

    What is one way of removing dissolved carbon dioxide from water?

    <p>Adding required amount of NH4OH (C)</p> Signup and view all the answers

    Which gas is released when bicarbonate salts decompose inside the boiler?

    <p>Carbon dioxide (C)</p> Signup and view all the answers

    What happens to the Ca2+ and Mg2+ when they form a complex with EBT?

    <p>They remain unstable and wine red (D)</p> Signup and view all the answers

    Which method is NOT commonly used for desalination of brackish water?

    <p>Evaporation (D)</p> Signup and view all the answers

    What volume of the water sample is typically used for titration in the total hardness estimation?

    <p>20 ml (D)</p> Signup and view all the answers

    How does reverse osmosis work?

    <p>By using a semi-permeable membrane under pressure (C)</p> Signup and view all the answers

    What effect does dissolved carbon dioxide have on boiler materials?

    <p>Forms carbonic acid with a corrosive effect (D)</p> Signup and view all the answers

    What type of water is brackish water compared to fresh water?

    <p>It has more than 1000 ppm to less than 35000 ppm of dissolved solids (B)</p> Signup and view all the answers

    Which indicator is used in the procedure to detect the endpoint of the titration?

    <p>EBT (Eriochrome Black T) (B)</p> Signup and view all the answers

    What is the driving force behind the process of osmosis?

    <p>Osmotic pressure (A)</p> Signup and view all the answers

    When performing the titration of the boiled water sample, what does the final stable color indicate?

    <p>EDTA has reacted completely (C)</p> Signup and view all the answers

    What is typically used as the membrane in reverse osmosis?

    <p>Cellulose acetate (A)</p> Signup and view all the answers

    Which of the following statements is true about sea water?

    <p>It contains more than 35000 ppm of dissolved solids (A)</p> Signup and view all the answers

    What is produced at the anode during the discharge of a lithium battery?

    <p>Li+ and e- (B)</p> Signup and view all the answers

    What is the voltage of a lithium battery?

    <p>3.0V (B)</p> Signup and view all the answers

    What is one advantage of lithium batteries over other types of cells?

    <p>Solid state constituents (D)</p> Signup and view all the answers

    What is the main benefit of direct conversion in a fuel cell?

    <p>Higher efficiency (B)</p> Signup and view all the answers

    What reaction occurs in a hydrogen-oxygen fuel cell?

    <p>Hydrogen is oxidized to water (A)</p> Signup and view all the answers

    What materials can be used for the electrodes in a hydrogen-oxygen fuel cell?

    <p>Carbon with a catalyst (D)</p> Signup and view all the answers

    What is an example of a fuel used in fuel cells?

    <p>Methanol (C)</p> Signup and view all the answers

    What is the function of the electrolyte in a fuel cell system?

    <p>To facilitate the oxidation and reduction reactions (D)</p> Signup and view all the answers

    Flashcards

    How does hard water impact the dyeing industry?

    The dissolved salts in hard water react with the dyes, forming precipitates. This leads to wastage of dyes and affects the quality of the final product.

    How does hard water affect sugar refining?

    The dissolved salts in hard water can interfere with the crystallization process, making it difficult to obtain pure sugar crystals. This results in lower-quality sugar and reduced efficiency.

    What is the impact of hard water on the paper industry?

    Hard water can affect the quality of paper. The dissolved salts can react with the paper fibers, leading to weaker, discolored, and less durable paper. This can be problematic in industries that rely on high-quality paper.

    Explain the impact of hard water on the pharmaceutical industry.

    Hard water can cause the formation of undesirable products, affecting the purity and effectiveness of medications. This can impact the pharmaceutical industry's production of drugs and other products.

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    Explain what temporary hardness is.

    Temporary hardness is caused by the presence of dissolved bicarbonates of calcium and magnesium. It is called temporary because it can be removed through boiling or by adding lime to the water.

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    Explain what permanent hardness is.

    Permanent hardness is caused by dissolved chlorides and sulfates of calcium, magnesium, iron, and other metals. It is called permanent because it cannot be removed by boiling. It requires methods like the lime soda process or the zeolite process.

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    Why is the concentration of hardness expressed in terms of CaCO3?

    The concentration of hardness-causing salts is often expressed as an equivalent amount of CaCO3. This standard is used because CaCO3 is insoluble and its molecular weight makes calculations simpler.

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    What is the relationship between temporary hardness, permanent hardness, and total hardness?

    The total hardness of water is the sum of temporary hardness and permanent hardness.

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    Ca-EBT Complex

    A complex formed between calcium ions (Ca2+) and Eriochrome Black T (EBT) indicator. It is unstable and appears wine red in color.

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    Mg-EBT Complex

    A complex formed between magnesium ions (Mg2+) and Eriochrome Black T (EBT) indicator. Like the Ca-EBT complex, it is also unstable and appears wine red.

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    Ca-EDTA Complex

    A complex formed between calcium ions (Ca2+) and EDTA (ethylenediaminetetraacetic acid). This complex is stable and colorless.

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    Mg-EDTA Complex

    A complex formed between magnesium ions (Mg2+) and EDTA (ethylenediaminetetraacetic acid). This complex is also stable and colorless.

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    Standardization of EDTA

    The process of determining the exact concentration of a solution, such as EDTA, by reacting it with a known amount of a standard substance.

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    Total Hardness of Water

    The total amount of calcium and magnesium ions present in a water sample. It is measured by titrating the water sample with a standardized EDTA solution.

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    Permanent Hardness

    The hardness of water caused by dissolved calcium and magnesium salts that remain even after boiling. This is also known as non-carbonate hardness.

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    Eriochrome Black T (EBT)

    A type of chemical indicator used in complexometric titrations. It changes color in the presence of calcium and magnesium ions, indicating the endpoint of the titration.

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    What happens when dissolved oxygen reacts with iron in a boiler?

    Dissolved oxygen in boiler water reacts with iron to form rust. This reaction is accelerated at high temperatures, leading to corrosion of boiler materials.

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    How is dissolved oxygen removed from boiler water?

    To remove dissolved oxygen from boiler water, chemical methods like adding sodium sulfite, hydrazine, or sodium sulfide are employed. These chemicals react with the oxygen, preventing it from causing corrosion.

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    Why is hydrazine a preferred choice for removing dissolved oxygen?

    Hydrazine is considered an ideal compound for removing dissolved oxygen because it forms water and inert nitrogen gas, which don't harm the boiler.

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    How does mechanical deaeration remove dissolved gases?

    Mechanical deaeration involves using a tower to remove dissolved gases, including oxygen and carbon dioxide. Water is sprayed through perforated plates under reduced pressure and heated. This encourages the gases to leave the water, preventing corrosion.

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    How does dissolved carbon dioxide contribute to corrosion?

    Dissolved carbon dioxide in boiler water forms carbonic acid, which slowly corrodes boiler materials. Bicarbonate salts also release carbon dioxide when they are heated, further contributing to corrosion.

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    How is dissolved carbon dioxide removed from boiler water?

    To remove dissolved carbon dioxide, ammonia (NH4OH) can be added to the water. This neutralizes the carbonic acid and prevents corrosion.

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    What is the relationship between gas solubility and pressure/temperature?

    The solubility of a gas in a liquid is directly proportional to pressure and inversely proportional to temperature. In mechanical deaeration, high temperature and low pressure decrease oxygen solubility in water, promoting its removal.

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    Why is deaeration performed at high temperatures?

    The solubility of gases in water decreases with increasing temperature. That's why deaeration is often performed at high temperatures, driving off dissolved gases like oxygen and carbon dioxide.

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    What is desalination?

    The process of removing dissolved salts from water, often used to make seawater or brackish water drinkable.

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    What is brackish water?

    Water with a salty or brackish taste, unsuitable for drinking due to high salt content.

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    What is a semi-permeable membrane?

    A type of membrane used in reverse osmosis that allows water molecules to pass through while blocking dissolved salts.

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    What is osmotic pressure?

    The pressure difference between two solutions separated by a semi-permeable membrane, driving the movement of water from a dilute solution to a concentrated solution.

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    What is reverse osmosis?

    A process that forces water through a semi-permeable membrane from a concentrated solution to a dilute solution by applying pressure greater than the osmotic pressure.

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    What is electrodialysis?

    A method of desalination where an electric current is applied to separate dissolved salts from water using ion-selective membranes.

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    What is fresh water?

    Water containing less than 1000 ppm of dissolved solids, suitable for drinking.

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    What is membrane filtration?

    A membrane filtration technique that uses a semi-permeable membrane to separate water molecules from dissolved salts and other impurities.

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    Secondary Battery

    A type of battery that can be recharged by passing electricity through it, reversing the chemical reactions that occur during discharge.

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    Difference between Primary and Secondary Batteries

    A primary battery cannot be recharged, while a secondary battery can.

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    Lead-Acid Battery

    A lead-acid battery is a type of secondary battery that uses lead and lead dioxide as electrodes in an electrolyte solution of sulfuric acid.

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    Discharge Reaction in Lead-Acid Battery

    In a lead-acid battery, during discharge, lead is oxidized to lead sulfate at the anode, while lead dioxide is reduced to lead sulfate at the cathode.

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    Charging Reaction in Lead-Acid Battery

    In a lead-acid battery, during charging, the lead sulfate at both electrodes is converted back to lead and lead dioxide.

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    Lead-Acid Battery as a Voltaic and Electrolytic Cell

    The process of using a lead-acid battery as a voltaic cell involves converting chemical energy into electrical energy, while using it as an electrolytic cell means converting electrical energy into chemical energy during recharging.

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    Construction of Lead-Acid Battery

    A lead-acid battery is made up of several cells connected in series. Each cell has lead plates as anodes and lead dioxide plates as cathodes, immersed in sulfuric acid.

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    Density of Electrolyte in Lead-Acid Battery

    The density of the electrolyte solution in a lead-acid battery can be used to determine the state of charge. A higher density indicates a higher charge level.

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    Li-ion Battery Discharge Reaction

    A chemical reaction that occurs in a lithium battery when it is discharging (releasing energy). Lithium atoms lose an electron and become lithium ions (Li+), which move from the anode (negative electrode) to the cathode (positive electrode). The cathode accepts the electrons and gains lithium ions, forming a lithium-containing compound (for example, LiTiS2).

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    Li-ion Battery Recharge Reaction

    A chemical reaction that occurs during the recharging of a lithium battery. Lithium ions (Li+) move from the cathode back to the anode. The energy needed to drive this process is supplied by an external current source.

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    Fuel Cell

    A device that directly converts chemical energy (from a fuel's oxidation) into electrical energy. It's more efficient than conventional systems that involve multiple energy conversions (thermal to mechanical, then mechanical to electrical).

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    Hydrogen-Oxygen Fuel Cell

    A fuel cell that uses hydrogen as the fuel and oxygen as the oxidant. The reaction between hydrogen and oxygen produces electricity and water.

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    Anode and Cathode in a Fuel Cell

    The electrodes in a fuel cell. The anode is where the fuel is oxidized, releasing electrons. The cathode is where the oxidant is reduced, accepting the electrons.

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    Electrolyte in a Fuel Cell

    An electrolyte solution in a fuel cell that allows the movement of ions (charged particles) between the anode and cathode. This facilitates the electrochemical reaction.

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    Oxidation in Fuel Cells

    The chemical process where a substance loses electrons, gaining a more positive oxidation state. In a fuel cell, the fuel is oxidized at the anode.

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    Reduction in Fuel Cells

    The chemical process where a substance gains electrons, becoming more negatively charged. In a fuel cell, the oxidant (often oxygen) is reduced at the cathode.

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    Study Notes

    Water Science

    • Water is crucial for life and human society's development, playing a vital role in life's evolution.
    • Water purity is an indicator of societal maturity.
    • Water is vital for all living organisms and extensively used in various industries, including drinking. bathing, sanitation, irrigation, firefighting, air conditioning, and the production of industrial materials.
    • Inadequate and contaminated water supplies pose significant health risks.
    • Water conservation and quality management are complex issues arising from unplanned industrialization.
    • River pollution is a major consequence of improper waste disposal.
    • Global water scarcity is a growing concern.

    Sources of Water

    • Surface water includes rainwater, river water, lake water, and seawater, which are readily available on the Earth's surface.
    • Groundwater is well water and spring water, which are rich in minerals but contain minimal organic impurities.

    Impurities in Water

    • Water is vital for life but is often contaminated by pollutants.
    • Water pollution is the alteration of water's physical, chemical, and biological features.
    • Pollutants include suspended impurities (affecting turbidity, color, odor), colloidal impurities (from organic waste), dissolved impurities (salts, gases), and microorganisms (bacteria, fungi).
    • Human activities are the primary cause of water contamination.

    Types of Water

    • Water is classified based on its lather-forming property with soap solution into soft water and hard water.
    • Soft water readily produces lather with soap.
    • Hard water does not produce lather with soap; it forms an insoluble precipitate.

    Hardness of Water

    • Hardness is the characteristic of water that prevents soap lathering.
    • It is caused by the presence of salts of calcium, magnesium, and other heavy metals.
    • Hard water forms insoluble soap precipitates, causing problems like wasted soap, uncleanliness, and potentially health issues.

    Types of Hardness

    • Temporary Hardness or Carbonate hardness is caused by dissolved bicarbonates of calcium and magnesium.
    • It can be removed by boiling or adding lime to water.
    • Permanent Hardness or Non-carbonate hardness is due to chlorides and sulfates of calcium, magnesium, iron, and other metals.
    • It can be removed through lime soda process or zeolite process.

    Disadvantages of Hardness

    • Hardness has several drawbacks in domestic and industrial water usage, such as reduced cleaning efficiency, increased cooking time and fuel consumption, digestive problems, and risks of urinary tract problems.

    Boiler Feed Water

    • Water used in steam engines and boilers should be free from hardness, dissolved salts, and impurities.

    Boiler Troubles

    • Scale and sludge formation, priming and foaming, caustic embrittlement, and boiler corrosion can occur due to hard water.
    • Prevention of scale formation and corrosion is important for boiler efficiency.

    Removal of Dissolved Oxygen

    • Dissolved oxygen in water attacks the boiler material, which can be removed using chemical methods (e.g., sodium sulfite or hydrazine) or mechanical deaeration.

    Dissolved Carbon Dioxide

    • Dissolved carbon dioxide in water forms carbonic acid, slowly corroding boiler material.
    • It's removed through the addition of ammonia or via mechanical deaeration alongside oxygen removal.

    Water Softening

    • The processes used to remove hardness-causing salts from water are called water softening or conditioning methods, including external conditioning (such as zeolite or permutit process or ion exchange process) or internal conditioning.

    Desalination of Water

    • Removing common salt (sodium chloride) from water is called desalination.
    • Brackish water, with dissolved salts, can be made drinkable through desalination techniques, like reverse osmosis.

    Batteries and Sensors

    • Batteries store electrical energy, converting chemical energy into electrical energy through electrochemical reactions.
    • Two key battery parameters are potential (voltage) and current.

    Primary Cells

    • Primary cells or primary batteries are non-rechargeable.
    • Once discharged, they cannot be brought back to their original state by passing electricity through them.

    Secondary Cells

    • Secondary cells or secondary batteries are rechargeable and can be brought back to their original state.

    Fuel Cells

    • Fuel cells generate electricity through an electrochemical process converting chemical energy directly into electrical energy.
    • Hydrogen-oxygen fuel cells are an example converting hydrogen and oxygen into water, producing electricity.

    Solar Cells

    • Solar cells (photovoltaic cells) convert light energy into electrical energy.
    • The p-n junction diode structure creates a voltage with light.

    Biosensors

    • Biosensors use biological components coupled with transducers to detect and quantify target molecules or chemicals.
    • They are used in healthcare, industry, and environmental monitoring applications.

    Organic Electronic Materials

    • Organic materials have shown great potential for use in flexible and lightweight electronics, due to their conductivity.
    • Types include Intrinsically conducting polymers and Extrinsically conducting polymers.

    Fullerenes

    • Fullerenes are allotropes of carbon with cage-like structures.
    • Uses include medical and other applications.

    Polystyrene

    • Polystyrene is a thermoplastic polymer with notable properties including transparency, hard yet brittle, poor heat resistance, high impact resistance and electrical insulation.

    PMMA

    • Polymethyl methacrylate (also known as acrylic glass or plexiglass) is a transparent thermoplastic polymer.
    • It is known for its clarity, impact resistance, and weather resistance.

    Liquid Crystal Displays (LCDs)

    • LCDs are flat-panel displays that use liquid crystals to modulate light.
    • They are based on the principle of polarizing light.

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