Water and Seawater Properties Quiz

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Questions and Answers

Which of the following ions contributes to water hardness?

  • Cl-
  • Na+
  • Mg2+ (correct)
  • Fe2+ (correct)

Temporary hardness can be removed by boiling the water.

True (A)

What is the formula for calculating total hardness in water?

CaCO3

Hard water can cause poor detergent performance, leading to residues known as ______.

<p>soap scum</p> Signup and view all the answers

Match the type of water hardness with its cause:

<p>Temporary hardness = Caused by bicarbonates Permanent hardness = Caused by sulphates Calcium hardness = Caused by calcium ions Magnesium hardness = Caused by magnesium ions</p> Signup and view all the answers

What is the primary method for removing permanent hardness in water?

<p>Water softening using ion exchange (D)</p> Signup and view all the answers

Calcium and magnesium chlorides are responsible for temporary hardness in water.

<p>False (B)</p> Signup and view all the answers

What effect does hard water have on diesel engines?

<p>Can cause scale deposits and reduce efficiency.</p> Signup and view all the answers

What is the main cause of corrosion in ship boilers due to hard water?

<p>Concentration of corrosion ions (B)</p> Signup and view all the answers

Sea water is classified as soft water.

<p>False (B)</p> Signup and view all the answers

What is the preferred type of water for cooling diesel engines with permanent hardness?

<p>Distilled water</p> Signup and view all the answers

The scale formed in boilers can reduce the ______ efficiency by impairing the flow of heat.

<p>heating</p> Signup and view all the answers

Match the water hardness classifications with their respective ranges:

<p>Soft = 0–75 mg/L Moderately hard = 75-150 mg/L Hard = 150-300 mg/L Very hard = &gt;300 mg/L</p> Signup and view all the answers

Which of the following methods is NOT a water softening technique?

<p>Boiling method (D)</p> Signup and view all the answers

The soda-lime method uses lime and soda to remove hardness from water by precipitation.

<p>True (A)</p> Signup and view all the answers

What is the general measurement unit for determining water hardness?

<p>ppm or mg/L of CaCO3</p> Signup and view all the answers

Which of the following correctly describes the polarity of water?

<p>It has a positive and negative end, making it polar. (C)</p> Signup and view all the answers

Water has a neutral pH of 7.5.

<p>False (B)</p> Signup and view all the answers

What is the significance of water's high specific heat?

<p>It allows water to absorb a large amount of heat without significantly changing temperature.</p> Signup and view all the answers

Water contracts until _____ °C before it starts to expand upon freezing.

<p>4</p> Signup and view all the answers

Match the following water properties with their effects:

<p>High heat of vaporization = Regulates climate High density at 4 °C = Supports aquatic life Universal solvent = Facilitates chemical reactions Resistance to temperature changes = Promotes stable environments</p> Signup and view all the answers

Which of the following substances will increase the electrical conductivity of water?

<p>Sodium chloride (D)</p> Signup and view all the answers

Water is the only natural substance that can exist in all three states of matter on Earth.

<p>True (A)</p> Signup and view all the answers

What is the impact of ice forming on the surface of lakes?

<p>It insulates the water below, allowing aquatic organisms to survive.</p> Signup and view all the answers

Flashcards

Hard water effects on boilers

Hard water in boilers reduces heating efficiency and causes metal overheating due to scale deposits.

Corrosion from hard water

Hard water can corrode ship boilers by concentrating corrosion ions and causing overheating.

Hard water in diesel engines

Hard water in diesel engines leads to piston head cracking (scab formation) and accelerated corrosion.

Water hardness measurement

Water hardness is measured in ppm (parts per million) or mg/L (milligrams per liter) of calcium carbonate (CaCO3).

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Soft water range in ppm

Water with 0-75 ppm calcium carbonate is considered soft.

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Hard water softening

Removing calcium, magnesium, and other metal ions from hard water.

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Soda-Lime method

A water softening process that uses lime and soda to precipitate calcium and magnesium.

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Acceptable hardness for cooling water

Cooling water in engines should ideally have less than 150 ppm hardness.

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Water's Polarity

Water is a polar molecule with a positive and negative end, making it an excellent solvent for many substances.

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Hydrogen Bonding in Water

Hydrogen bonds form between water molecules due to their polarity, giving water unique properties like high surface tension.

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Water's High Heat of Vaporization

Water requires a lot of energy to evaporate, helping to regulate temperature and keep organisms cool.

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Water's Density at 4°C

Water is most dense at 4°C, which is why ice floats and allows life to exist in frozen lakes.

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Water's Neutral pH

Pure water has a pH of 7, meaning it is neither acidic nor basic, making it ideal for biological processes.

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Water's High Specific Heat

Water can absorb a lot of heat before its temperature changes significantly.

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Water's Electrical Conductivity

Pure water has low conductivity but it increases significantly with dissolved ions like sodium chloride.

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Water's Existence in Three States

Water is the only substance that naturally exists as solid (ice), liquid (water), and gas (vapor) on Earth.

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What is water hardness?

Water hardness is a measure of the concentration of dissolved calcium and magnesium ions, which can cause various problems.

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What are the types of hardness?

Water hardness can be categorized as total, calcium, magnesium, temporary (carbonate), and permanent (noncarbonate) hardness based on the dissolved minerals and their forms.

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How does temporary hardness occur?

Temporary hardness is caused by the presence of dissolved bicarbonates of calcium and magnesium. Boiling or adding lime can reduce it.

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How does permanent hardness occur?

Permanent hardness is caused by dissolved sulfates and chlorides of calcium and magnesium. It can't be removed by boiling.

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What are the sources of hard water?

Hard water originates from natural sources like groundwater or surface water that dissolve minerals like calcium and magnesium from rocks and soil.

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What are the effects of hard water?

Hard water can cause scale buildup in pipes and appliances, reduce soap and detergent efficiency, and form residues on skin.

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What is scale?

Scale is a hard deposit formed in pipes and appliances due to dissolved minerals in hard water, mainly calcium carbonate, magnesium hydroxide, and calcium sulfate.

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How do you remove hard water?

Water softeners or ion exchange columns can remove the minerals causing hardness by replacing them with other ions.

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Study Notes

Water Properties

  • Water is a polar molecule with hydrogen bonding, which leads to unique properties.
  • It's a universal solvent.
  • Water exhibits cohesion behaviour (high surface tension).
  • It has a high heat of vaporization.
  • Water's density is highest at 4°C (it expands upon freezing).
  • It resists temperature changes.
  • Water has a neutral pH (7-7.5).
  • Water has a high specific heat (c (J/g.°C)).
  • Water can dissolve many compounds due to its polarity.
  • Biochemical reactions often take place in water by dissolving.

Seawater Properties

  • Seawater is a significant substance on Earth.
  • Oceans absorb and reflect sunlight.
  • They store and transport heat and impact climate systems.
  • Oceans are the primary source of atmospheric water vapor.
  • Oceans exchange gases (e.g., CO2) with the atmosphere.
  • Average seawater density at the surface is 1.027 g/mL (denser than pure water).
  • Salinity of seawater is about 3.5% (35 g/L).
  • Freezing point of seawater is approximately -2°C (decreases with rising salinity).
  • Seawater has the highest surface tension among liquids.
  • The color of the ocean is blue because it absorbs other colors and reflects blue light most.

Seawater Composition

  • Contains more dissolved ions than other water types (2.5% salts).
  • Contains dissolved gases (nitrogen, oxygen, carbon dioxide).
  • Provides nutrients for marine life.
  • Salinity is the saltiness or dissolved salt content in water.
  • Salinity ranges between 3.1% and 3.8% but not uniformly.
  • Variations in ocean salinity due to evaporation and precipitation.

Water Hardness

  • Water hardness measures dissolved minerals (primarily calcium (Ca²⁺) and magnesium (Mg²⁺)).
  • High mineral content indicates hard water.
  • Limestone (CaCO₃) and gypsum (CaSO₄·2H₂O) are common sources of these minerals.
  • Dissolved calcium and magnesium increase hardness.
  • Hard water can be harmful in industrial applications.
  • Hardness is measured in ppm (mg/L) of calcium carbonate.

Types of Hardness

  • Temporary Hardness (Carbonate Hardness): Caused by dissolved bicarbonate minerals (HCO₃⁻). When heated, this hardness can be removed by boiling.
  • Permanent Hardness (Noncarbonate Hardness): Caused by dissolved sulphates and chlorides of calcium and magnesium. This type of hardness cannot be removed by boiling.

Effects of Hard Water

  • Hard water forms deposits called "scale".
  • Scale can impede heat transfer in boilers, leading to overheating.
  • Hard water can cause poor detergent/soap performance, forming residues.
  • Can cause corrosion in boilers and other equipment, leading to reduced efficiency and potential damage.

Water Softening Methods

  • Water softening removes or reduces calcium, magnesium, and other metal cations.
  • Soda-lime method (precipitation process): Uses lime (Ca(OH)₂) and soda (Na₂CO₃) to precipitate out the hardness ions.
  • Ion exchange resins: Use a resin to exchange the calcium and magnesium with sodium ions. This is a common method in households and industries.

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