Water and Aqueous Solutions Chapter Summary

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12 Questions

What type of interactions determine steric complementarity and stabilize biological macromolecules?

Van der Waals interactions

Which type of non-covalent interactions involve electrostatic interactions between permanently charged species?

Ionic interactions

What is the complex phenomenon associated with the ordering of water molecules around non-polar substances?

The hydrophobic effect

Which non-covalent interactions do not involve sharing a pair of electrons?

Van der Waals interactions

What is the geometry of the water molecule?

Tetrahedral

Why can water serve as both a hydrogen bond donor and acceptor?

As a result of its dipole moment

What induces a net dipole moment in the water molecule?

The electronegativity of the oxygen atom

How many other water molecules can each water molecule connect to due to its dipole moment?

4

What does the pH of the solution equal at the midpoint of the titration curve?

pKa of the acid

What characterizes the buffer region on the titration curve?

It is a flat line region around +/- 1 pH away from the pKa

At what point in the titration curve is the acid most readily able to give up protons?

At the lowest pH

How can the pKa of an acid be determined using titration?

By adding equivalents of a base with known concentration until reaching the midpoint where acid = base

This quiz provides a summary of the chapter 'Water and Aqueous Solutions', covering interactions between molecules, aggregation of nonpolar moieties in water, behavior of weak acids and bases in water, and the function of buffers.

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