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Questions and Answers
Match the following compounds with their roles in volumetric analysis:
Match the following compounds with their roles in volumetric analysis:
Potassium permanganate = Oxidising agent Iron(II) ions = Reducing agent Ammonium iron (II) sulfate = Primary standard Sulfuric acid = Source of H+ ions
Match the following descriptions with the respective compounds used in titration:
Match the following descriptions with the respective compounds used in titration:
KMnO4 = Acts as its own indicator Fe2+ = Converted to Fe3+ Ammonium iron (II) sulfate = High purity and stable in air
Match the following steps with their corresponding actions in the experiment:
Match the following steps with their corresponding actions in the experiment:
Rinse burette = With potassium manganate(VII) solution Fill pipette = With iron(II) solution Acidify conical flask = Add dilute sulfuric acid Adjust burette = To zero before titration
Match the following ions with their respective redox changes:
Match the following ions with their respective redox changes:
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Match the following laboratory equipment with their usage in the experiment:
Match the following laboratory equipment with their usage in the experiment:
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Match the following reactions with their appropriate electron transfer details:
Match the following reactions with their appropriate electron transfer details:
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Match the following factors with their relevance in the titration process:
Match the following factors with their relevance in the titration process:
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Match the following characteristics with the substances in the titration:
Match the following characteristics with the substances in the titration:
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Match the following laboratory techniques with their descriptions:
Match the following laboratory techniques with their descriptions:
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Match the reactants in the redox reaction with their roles:
Match the reactants in the redox reaction with their roles:
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Match the variables with their definitions in volumetric analysis:
Match the variables with their definitions in volumetric analysis:
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Match the chemical compound with its formula:
Match the chemical compound with its formula:
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Match the mass concentration values with their units:
Match the mass concentration values with their units:
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Match the steps in preparing a solution with their order:
Match the steps in preparing a solution with their order:
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Match the end-point observation with the technique used:
Match the end-point observation with the technique used:
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Match the term with its corresponding value in the titration:
Match the term with its corresponding value in the titration:
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Match the following solutions with their uses in the experiment:
Match the following solutions with their uses in the experiment:
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Match the following steps with their corresponding actions:
Match the following steps with their corresponding actions:
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Match the following indicators with their descriptions:
Match the following indicators with their descriptions:
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Match the following substances with their properties:
Match the following substances with their properties:
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Match the following measurements with their values:
Match the following measurements with their values:
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Match the following components with their associated calculations:
Match the following components with their associated calculations:
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Match the following chemical reactions with their products:
Match the following chemical reactions with their products:
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Match the following terms with their definitions:
Match the following terms with their definitions:
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Match the following formulas with their respective compounds:
Match the following formulas with their respective compounds:
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Match the following laboratory equipment with their uses:
Match the following laboratory equipment with their uses:
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Match the following calculation results with their corresponding parameters:
Match the following calculation results with their corresponding parameters:
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Match the substances with their roles in the titration procedure:
Match the substances with their roles in the titration procedure:
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Match the following volume measurements with their conversions:
Match the following volume measurements with their conversions:
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Match the following steps with their order in the titration process:
Match the following steps with their order in the titration process:
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Match the calculation tasks with their formulas:
Match the calculation tasks with their formulas:
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Match the following terms with their definitions related to the titration process:
Match the following terms with their definitions related to the titration process:
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Match the following compounds with their functions in the titration experiment:
Match the following compounds with their functions in the titration experiment:
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Match the following values with their respective calculations or outcomes:
Match the following values with their respective calculations or outcomes:
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Match the following chemical species with their roles in the titration reaction:
Match the following chemical species with their roles in the titration reaction:
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Match the following statements with their corresponding reasons during the titration procedure:
Match the following statements with their corresponding reasons during the titration procedure:
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Match the following concentrations with their corresponding types:
Match the following concentrations with their corresponding types:
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Match the following steps with their descriptions in the dilution process:
Match the following steps with their descriptions in the dilution process:
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Match the following chemical reactions with their respective products:
Match the following chemical reactions with their respective products:
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Match the following quantities with their calculated values:
Match the following quantities with their calculated values:
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Match the following steps with their outcomes in the titration process:
Match the following steps with their outcomes in the titration process:
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Match the following concentration types with their appropriate formula:
Match the following concentration types with their appropriate formula:
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Match the following titration components with their roles:
Match the following titration components with their roles:
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Match the following reactions with their respective reagents:
Match the following reactions with their respective reagents:
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Study Notes
Volumetric Analysis: Oxidation-Reduction
- Volumetric analysis determines oxidizing and reducing agent concentrations.
- Potassium permanganate (KMnO4) is a crucial oxidizing agent.
- KMnO4 is a purple solid, but not a primary standard due to purity issues.
- It needs standardization via titration against a primary standard.
- KMnO4 gains 5 electrons in acidic solution.
- MnO4- + 8H+ + 5e- → Mn2+ + 4H2O
- H+ ions are needed for the reaction; dilute acid is added.
- KMnO4 acts as its own indicator.
- Fe2+ ions can be used to determine KMnO4 concentration.
- KMnO4 oxidizes Fe2+ to Fe3+.
- MnO4- + 8H+ + 5Fe2+ → Mn2+ + 5Fe3+ + 4H2O
- Ammonium iron(II) sulfate (a primary standard) provides Fe2+ ions.
- It's crucial for preparing a standard FeSO4 solution to standardize KMnO4.
- Titration procedures are needed to standardize KMnO4 solution using a standardized Fe2+ solution.
Mandatory Experiment: Preparing Standard Solution
- Materials: Deionized water, burette, conical flask, pipette
-
Procedure:
- Wash glassware. Rinse burette and pipette with KMnO4 and Fe2+ solutions.
- Pipette measured Fe2+ solution into the conical flask. Add sulfuric acid.
- Fill burette with KMnO4 solution, ensuring below the tap is filled before zero adjustment.
- Add standard KMnO4 to the conical flask to detect endpoint (first persisting pale pink color). Titrating must be consistent, use a wash bottle to wash down the walls of the flask. Record results.
Solving Volumetric Problems in Redox Reactions
- Formulae for calculating concentration of oxidizing and reducing agents
- Vox, Mox, nox
- Vred, Mred, nred
Mandatory Experiment: Determining Iron content in an Iron Tablet
- Find the total mass of five iron tablets
- Crush the tablets and dissolve in sulfuric acid
- Transfer solution to a 250-cm³ volumetric flask and dilute
- Use a pipette to take a known volume of the solution
- Titrate against a standard KMnO4 solution until the endpoint
- Calculate iron concentration and mass
- Calculate the percentage of iron in an iron tablet
Mandatory Experiment: Determining Sodium Thiosulfate Concentration
- Standard solution of sodium thiosulfate and standard iodine solution is needed.
- Using a pipette: fill a pipette with potassium iodate solution and transfer to conical flask.
- Add sulfuric acid.
- Add potassium iodide solution.
- Fill burette with sodium thiosulfate solution, ensuring the portion below the tap is filled before adjusting to zero.
- Add sodium thiosulfate to the conical flask to detect endpoint.
- Calculate sodium thiosulfate concentration
Mandatory Experiment: Determining Percentage of Sodium Hypochlorite in Household Bleach
- Dilute bleach solution first.
- Wash and rinse pipette. Wash burette with sodium thiosulfate.
- Add 1 g potassium iodide and 10 cm³ of dilute sulfuric acid to conical flask.
- Titrate with the standard sodium thiosulfate solution.
Exam Questions (2011)
- Questions on dilutions, calculations, descriptions of procedures, color changes, etc. for determining sodium hypochlorite concentration in bleach.
- Using a titration procedure to identify and determine the concentration of a solution.
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Description
This quiz delves into the principles of volumetric analysis focusing on oxidation-reduction reactions. It highlights the role of potassium permanganate (KMnO4) as an oxidizing agent and its interaction with Fe2+ ions. Test your understanding of titration techniques and the use of primary standards in determining concentrations!