Vapor-Liquid Equilibrium (VLE) Explained
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Questions and Answers

What was a unifying force during the Middle Ages?

  • Feudalism
  • The Church (correct)
  • Monarchies
  • Trade guilds

Which of the following was administered by the Church?

  • Military service
  • Tax collection
  • Elections
  • Sacraments (correct)

Who was at the top of the Church hierarchy?

  • Cardinals
  • Archbishops
  • Pope (correct)
  • Bishops

What is the name for Church law?

<p>Canon Law (A)</p> Signup and view all the answers

What was excommunication?

<p>Banishment from the Church (C)</p> Signup and view all the answers

What was the selling of Church offices called?

<p>Simony (C)</p> Signup and view all the answers

What was lay investiture?

<p>The appointment of religious officials by secular leaders (D)</p> Signup and view all the answers

The Schism resulted in the separation between which two Churches?

<p>Roman Catholic Church and Eastern Orthodox Church (D)</p> Signup and view all the answers

In the context of the relationship between the Church and state, what did monarchs desire?

<p>To control the Church (C)</p> Signup and view all the answers

Which agreement was a compromise about lay investiture?

<p>The Concordat of Worms (A)</p> Signup and view all the answers

Flashcards

Canon Law

A system of justice that guided people's conduct during the Middle Ages.

Excommunication

Banishment from the Church; one of the harshest punishments.

Interdict

When sacraments and religious services could not be performed in a specific region.

Simony

The selling of Church offices, a problem in the Church.

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Lay Investiture

Appointment of religious officials by secular leaders.

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The Schism

The split in Christianity between the Roman Catholic and Eastern Orthodox Churches.

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Concordat of Worms

A compromise: The church alone could appoint a bishop, but the emperor could veto the appointment.

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Study Notes

Vapor-Liquid Equilibrium (VLE) Introduction

  • Phase equilibrium signifies a stable state where multiple phases coexist
  • Vapor-liquid equilibrium (VLE) is a common focus in Chemical Engineering Thermodynamics, involving equilibrium between liquid and vapor phases

Equilibrium Criteria

  • Temperature equilibrium means all phases share the same temperature: (T^{\alpha} = T^{\beta} = T^{\gamma} =...)
  • Pressure equilibrium means all phases share the same pressure: (P^{\alpha} = P^{\beta} = P^{\gamma} =...)
  • Chemical Potential Equilibrium implies each species has the same chemical potential across all phases: (\mu_{i}^{\alpha} = \mu_{i}^{\beta} = \mu_{i}^{\gamma} =...), where (\alpha, \beta, \gamma) denote different phases and (i) indicates a specific species

The Phase Rule

  • The phase rule, defined by J. Willard Gibbs, relates degrees of freedom, components, and phases at equilibrium
  • The formula is: (F = 2 - \pi + N)
  • (F) signifies degrees of freedom (independent variables that can change without altering the number of phases)
  • (\pi) is the quantity of phases in equilibrium
  • (N) is the quantity of components in the system

Understanding the Phase Rule

  • Degrees of Freedom ((F)): Intensive variables (temperature, pressure, composition) that can vary independently without changing the number of phases
  • Phases ((\pi)): Physically distinct and homogenous parts of the system
  • Components ((N)): Minimum count of independent chemical constituents needed to define each phase's composition

Examples

  • Single Component System (e.g., Water): At water's triple point, ice, liquid water, and steam coexist
    • (N = 1) (water)
    • (\pi = 3) (ice, liquid water, steam)
    • (F = 2 - 3 + 1 = 0), indicating no degrees of freedom, with fixed temperature and pressure
  • Binary System with Vapor and Liquid Phases: Ethanol and water in vapor-liquid equilibrium
    • (N = 2) (ethanol and water)
    • (\pi = 2) (vapor and liquid)
    • (F = 2 - 2 + 2 = 2), meaning two intensive properties can vary independently

Importance

  • The phase rule guides the design and operation of chemical engineering separation processes like distillation and crystallization
  • It assists in determining conditions to achieve desired separations and purifications

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Description

Understanding Vapor-Liquid Equilibrium (VLE), a key concept in Chemical Engineering Thermodynamics, involves phases coexisting in a stable state. Equilibrium is achieved when temperature, pressure, and chemical potential are uniform across all phases. The phase rule, defined by J. Willard Gibbs, relates degrees of freedom, components, and phases at equilibrium.

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