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Questions and Answers

Which of the following correctly lists the sublevels with their maximum number of electrons?

  • s2, p6, d10, f14 (correct)
  • s2, p4, d6, f8
  • s1, p2, d3, f4
  • s1, p3, d5, f7

What is the number of orbitals found within the d sublevel?

  • 5 (correct)
  • 3
  • 1
  • 7

According to quantum mechanics, how many electrons can occupy a single orbital within any sublevel?

  • Depends on the sublevel.
  • Two, if they have the same spin.
  • Two, if they have opposite spins. (correct)
  • One.

How many total electrons are required to completely fill the fourth energy level?

<p>32 (A)</p> Signup and view all the answers

Which of the following orbital designations is not allowed according to the principles of quantum mechanics?

<p>$3f$ (B)</p> Signup and view all the answers

An atom has the following incorrect orbital notation:

  • $1s^2: ↑↓$
  • $2s^2: ↑↓$
  • $2p^6: ↑↓ ↑↓ ↑↓$
  • $3s^2: ↑↓$
  • $3p^4: ↑↓ ↑ ↑$

Which rule or principle of electron configuration is broken in the $3p^4$ configuration, and why?

<p>Pauli Exclusion Principle; both electrons in the first $3p$ orbital need to have the same spin. (C)</p> Signup and view all the answers

Which principle dictates that electrons first occupy the lowest energy levels available in an atom before filling higher energy levels?

<p>Aufbau Principle (B)</p> Signup and view all the answers

Which sublevel is characterized by a spherical electron cloud?

<p><em>s</em> sublevel (C)</p> Signup and view all the answers

Which rule or principle is violated in the provided orbital notation for Diagram 3?

<p>Aufbau Principle (D)</p> Signup and view all the answers

An element has the following abbreviated orbital notation: [Ne] 3s² 3p³. Which element is it?

<p>Phosphorus (C)</p> Signup and view all the answers

Which of the following orbital notations correctly represents Argon (Ar)?

<p><code>1s² 2s² 2p⁶ 3s² 3p⁶</code> (D)</p> Signup and view all the answers

Which of the following electron configurations corresponds to an element in the third period (row) of the periodic table with 6 valence electrons?

<p>$1s^22s^22p^63s^23p^4$ (C)</p> Signup and view all the answers

How many valence electrons does Cobalt (Co) possess, according to the provided information?

<p>2 (D)</p> Signup and view all the answers

An element has the electron configuration $1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^24d^{10}5p^66s^2$. Which element is it?

<p>Barium (B)</p> Signup and view all the answers

What is the expected number of electrons in the outermost shell (valence electrons) for Krypton (Kr)?

<p>8 (C)</p> Signup and view all the answers

Given the incomplete electron configuration $1s^22s^22p^63s^23p^64s^23d^1$, which element does it represent?

<p>Scandium (C)</p> Signup and view all the answers

Elements located within the same group on the periodic table exhibit similarities in which characteristics?

<p>Valence electron configuration and chemical properties. (D)</p> Signup and view all the answers

What feature do elements within the same period of the periodic table share?

<p>Number of electron shells. (D)</p> Signup and view all the answers

A period in the periodic table in which only the s and p sublevels are being filled contains how many elements?

<p>8 (A)</p> Signup and view all the answers

Which set of sublevels are being filled in a period that contains 32 elements?

<p><em>s</em>, <em>p</em>, <em>d</em>, <em>f</em> (D)</p> Signup and view all the answers

How can you determine the number of valence electrons in elements belonging to groups 13 through 18?

<p>Subtract 10 from the group number. (D)</p> Signup and view all the answers

Which of the following elements is located in period 5, group 14 of the periodic table?

<p>Tin (Sn) (A)</p> Signup and view all the answers

Which properties are characteristic of metals?

<p>Lose electrons and are good conductors (B)</p> Signup and view all the answers

Which group contains the most reactive nonmetals, often used in disinfectants and water treatment?

<p>Halogens (D)</p> Signup and view all the answers

An element has the electron configuration $1s^22s^22p^63s^23p^64s^23d^{10}4p^65s^24d^2$. Which element does this represent?

<p>Zirconium, Zr (C)</p> Signup and view all the answers

Which of the following noble gas configurations corresponds to antimony (Sb)?

<p>$[Kr]5s^24d^{10}5p^3$ (D)</p> Signup and view all the answers

What is the noble gas configuration for technetium (Tc)?

<p>$[Kr]5s^24d^5$ (C)</p> Signup and view all the answers

Which of the following ions is isoelectronic with argon (Ar)?

<p>$S^{2-}$ (A)</p> Signup and view all the answers

What would be the noble gas configuration of $Rb^+$?

<p>$[Ar]4s^23d^{10}4p^6$ (D)</p> Signup and view all the answers

Who is credited with arranging elements by atomic number, which resolved inconsistencies in Mendeleev's table?

<p>Henry Moseley (B)</p> Signup and view all the answers

The periodic law states that the chemical and physical properties of elements are periodic functions of what?

<p>Atomic number (B)</p> Signup and view all the answers

What is the significance of valence electrons in determining the properties of an element?

<p>They are involved in chemical bonding. (A)</p> Signup and view all the answers

Why does atomic radius generally increase when moving down a group of elements?

<p>The number of occupied energy levels increases. (C)</p> Signup and view all the answers

Considering only nitrogen (N), phosphorus (P), and arsenic (As), which atom is the largest?

<p>Arsenic (A)</p> Signup and view all the answers

Which element requires more energy to remove its first electron: sodium (Na) or aluminum (Al)?

<p>Aluminum (B)</p> Signup and view all the answers

How does the first ionization energy generally change as you move from left to right across a period on the periodic table?

<p>It generally increases. (C)</p> Signup and view all the answers

Which of the following orders of first ionization energy is correct?

<p>Cl &gt; S &gt; P &gt; Si &gt; Al (D)</p> Signup and view all the answers

Why is the third ionization energy of magnesium (Mg) significantly higher than its second ionization energy?

<p>Removing the third electron disrupts a stable, full electron shell configuration. (A)</p> Signup and view all the answers

Considering chlorine (Cl), potassium (K), and zinc (Zn), which list correctly orders these atoms from highest to lowest electronegativity?

<p>Cl, Zn, K (B)</p> Signup and view all the answers

Which of the following options correctly identifies the smallest species?

<p>A lithium ion ($Li^+$) (B)</p> Signup and view all the answers

Flashcards

Orbital

Region of space around the nucleus where an electron is likely to be found.

Sublevel

A grouping of orbitals with similar energy levels within an electron shell.

Aufbau Principle

Electrons fill the lowest energy levels/orbitals first.

Hund's Rule

Electrons prefer to occupy orbitals singly before pairing up in the same orbital.

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Pauli Exclusion Principle

No two electrons in an atom can have the same set of quantum numbers; if they occupy the same orbital, they must have opposite spins.

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s sublevel

The s sublevel has 1 orbital, which means that the s sublevel can contain a maximum of 2 electrons.

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p sublevel

The p sublevel has 3 orbitals, which means the p sublevel can contain a maximum of 6 electrons.

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d sublevel

The d sublevel has 5 orbitals, which means the d sublevel can contain a maximum of 10 electrons.

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Orbital Notation

A visual representation showing how electrons are arranged within an atom's orbitals.

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Electron Configuration

Shows the distribution of electrons among the different energy levels and sublevels in an atom.

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Valence Electrons

Electrons in the outermost shell or energy level of an atom.

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Bohr Model

A simplified model of an atom with electrons orbiting the nucleus in specific paths.

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Argon Orbital Notation

Argon's (Ar) electron configuration using orbital notation.

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Selenium Orbital Notation

Selenium's (Se) electron configuration using orbital notation.

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Tin Orbital Notation

Tin's (Sn) electron configuration using orbital notation.

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Isoelectronic

Atoms of different elements with the same number of electrons.

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Dmitri Mendeleev

Arranged elements by chemical/physical properties.

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Mendeleev's Empty Spaces

Undiscovered elements.

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Henry Moseley

Arranged elements by atomic number.

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Periodic Law

Physical and chemical properties repeat when elements are arranged by increasing atomic number.

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Groups

Vertical columns in the periodic table.

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Periods

Horizontal rows in the periodic table.

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Atomic Radius

The distance from the nucleus to the outermost electron of an atom.

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Ionization Energy

The energy required to remove one electron from an atom.

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Ionization Energy Trend (Period)

As you move across a period from left to right on the periodic table, the first ionization energy increases.

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Ionization Energy Trend (Group)

Ionization energy decreases as you move down a group.

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Electronegativity

A measure of the ability of an atom to attract electrons in a chemical bond.

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Electronegativity Trend (Group)

Electronegativity decreases as you move down a group.

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Most Electronegative Element

Fluorine (F)

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Alkali Metal Reactivity

Reactivity increases going down the group.

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Periodic Group Similarity

Elements in the same group have the same valence configuration and similar chemical properties.

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Periodic Period Similarity

Elements in the same period have the same number of occupied energy levels.

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Elements in s and p block

There are 8 elements in a period where only s and p sublevels are filled.

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Period with 32 elements

A period with 32 elements contains s, p, d, f sublevels.

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Valence Electrons in Group 17

Group 17 elements have 7 valence electrons.

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Valence Electrons Calculation

For groups 13-18, valence electrons equal the group number minus 10.

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Metals vs Nonmetals

Metals lose electrons; nonmetals gain electrons.

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Reactive Groups

Alkali metals are the most reactive metals (Group 1), halogens are the most reactive nonmetals (Group 17), and noble gases are unreactive (Group 18).

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Study Notes

  • Study notes on Electron Configuration, Periodic Table Trends, and Periodic Table

Sublevels & Orbitals

  • The sublevels are listed with the correct number of maximum electrons per sublevel: s2, p6, d10, f14.
  • The d sublevel has 5 orbitals.
  • An orbital in any sublevel can occupy a maximum of two electrons if they have opposite spins
  • The fourth energy level needs 32 electrons to be completely filled.
  • Number of orbitals for sublevels: s sublevel is 1, p sublevel is 3, d sublevel is 5, f sublevel is 7
  • The maximum number of electrons for sublevels: s sublevel is 2, p sublevel is 6, d sublevel is 10, f sublevel is 14
  • 3f orbital can never exist according to quantum theory
  • The sublevel associated with a spherical (ball shaped) electron cloud identified as the "s sublevel"

Principles that Govern Electron Configuration

  • The Aufbau Principle governs electron configuration: Electrons fill the lowest energy levels first.
  • Hund's Rule is the rule that orbitals complete with single electrons before pairing up electrons in a single orbital
  • Pauli Exclusion Principle governs the spin, two electrons can share an orbital if they have opposite spin.
  • 3p4 electron should show an opposite spin, due to the Pauli Exclusion Principle
  • The last electron should go in the 2nd orbital, and not paired in the 1st as described by Hund's Rule
  • The 3s2 energy level should be completed before filling the 3p orbital according to the Aufbau Principle.

Orbital Notation

  • Carbon's orbital notation is shown in a.
  • Phosphorus is the element with orbital notation b.

Bohr Model

  • Dmitri Mendeleev is attributed with arranging elements by chemical and physical properties
  • Henry Moseley arranged the periodic table of elements in order of atomic number
  • Scientist above predicted undiscovered elements would fill the empty spaces
  • Periodic law states repetition of physical/chemical properties of elements when arranged in order of increasing atomic number

The Periodic Table

  • Groups are vertical columns in the periodic table
  • Each period in the periodic table corresponds to an energy level.
  • Valence electrons are electrons found in the outermost energy level of atoms.
  • Periods are horizontal rows in the periodic table.
  • Elements in the same periodic group have the same valence configuration, valence electrons, and similar chemical properties
  • Elements in the same period have the same number of occupied energy levels.
  • A period where only s and p sublevels are filled has 8 elements.
  • A period containing 32 elements contains the sublevels s, p, d, f.
  • Group 17 elements have 7 valence electrons
  • For groups 13-18, valence electrons equals the group number minus 10
  • Group 2 elements have valence electrons in the s sublevel.

Elements, Classes, and Families

  • Three classes of elements: metals, nonmetals, and metalloids
  • A on the table represents metals
  • B on the table represents metalloids
  • C on the ble represents nonmetals
  • Element in period 5, group 14: tin, Sn
  • Element in period 3, group 17: chlorine, Cl
  • Element in period 6, group 2: barium, Ba
  • Metals lose electrons, are good conductors, and are malleable and ductile
  • Nonmetals gain electrons, are brittle and dull, and are not conductors
  • Most reactive nonmetals belong to group 17: halogens
  • Group 18 elements are unreactive (noble gases)
  • The family termed "basic" are group 2: alkaline earth metals
  • Groups 3-12 are transition metals, and are also metals
  • The most reactive metals are groups 1: alkali metals
  • Actinides are elements in the second row of the f-block
  • Metalloids have both metallic and nonmetallic properties
  • Atomic radius decreases across the periodic table because the number of protons in the nucleus increases and pulls the electrons closer
  • Atomic radius generally increases moving down a group because the number of occupied energy levels increases
  • Arsenic is the largest of the following: nitrogen, phosphorus, or arsenic
  • Phosphorus is the largest atom out of phosphorus, sulfur and chlorine on the periodic table
  • Fluorine is the smallest atom out of nitrogen, oxygen and fluorine
  • Ionization energy is the energy needed to remove one electron from an atom
  • Aluminum requires more energy than sodium to remove its first electron.
  • First ionization energies increase moving left to right across a period.
  • Moving from top to bottom of a group, first ionization energies decrease.
  • Of the choices below, which gives the correct order of ionization energy? Cl > S > P > Si > Al
  • Phosphorus has the highest ionization energy of aluminum, silicon and phosphorus.
  • The third ionization energy of magnesium is greater because magnesium will achieve a full octet for its outer energy level
  • Sulfur has the highest ionization energy of tin, arsenic, and sulfur
  • Decreasing electronegativity: chlorine, zinc, potassium (Cl, Zn, K)
  • Electronegativity decreases moving down the periodic table.
  • Fluorine is the most electronegative element
  • Metals tend to have low electronegativity.
  • Of the following, the smallest is a lithium ion
  • Of the following, K+ will have a larger radius than K or Ca2+
  • Reactivity increases going down group 1 and decreases going down group 17

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