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CH 18: Understanding of the processes and redox reactions taking place in galvanic Cells

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What is the main function of a galvanic cell?

Convert chemical energy into electrical energy

In a galvanic cell, where do cations move towards?

Cathode

What is the direction of electron flow in a galvanic cell?

From anode to cathode

Which half-reaction takes place at the cathode of a galvanic cell?

Cu²⁺(aq) + 2e⁻ → Cu(s)

What is the role of the salt bridge in a galvanic cell?

Allows the flow of ions between half-cells to maintain electrical neutrality

Where does oxidation occur in a galvanic cell?

In the reduction half-cell

How is the overall reaction of a galvanic cell obtained?

By adding the two half-reactions

What does the standard cell notation represent in a galvanic cell setup?

The reactants and products involved

How is the electromotive force (EMF) of a cell calculated?

$E(anode) - E(cathode)$

What does a positive EMF value indicate about a reaction in a galvanic cell?

The reaction is spontaneous

What is the purpose of a salt bridge in a galvanic cell?

To maintain charge balance by allowing the flow of ions between half-cells

In a galvanic cell, where do anions move towards?

Anode

What occurs at the cathode of a galvanic cell?

Reduction

Which process converts chemical energy into electrical energy in galvanic cells?

Spontaneous redox reactions

What flows through the external circuit in a galvanic cell?

Electrons

What happens at the anode of a galvanic cell?

Oxidation

Which agent is reduced at the cathode of a galvanic cell?

$Cu^{2+}$(aq)

What is the function of cations in a galvanic cell?

Move towards the cathode for reduction

Which component allows for the flow of electrons between the two half-cells in a galvanic cell?

Electrolyte solution

What is the movement of anions in a galvanic cell related to?

Oxidation

Where does oxidation occur in a galvanic cell?

At the anode

What does a positive EMF value indicate about a reaction in a galvanic cell?

The reaction is spontaneous

In the standard cell notation for a galvanic cell, what does the double vertical line '||' represent?

A connection allowing ion movement

What is the main function of an inert electrode like Pt in a galvanic cell?

Facilitate electron transfer

How can oxidation and reduction sites be predicted in a galvanic cell from given half-cell reactions?

By comparing standard electrode potentials

Which electrode is written first in the standard cell notation for a galvanic cell?

Anode

What determines the overall cell reaction in a galvanic cell?

Addition of half-reactions without canceling electrons

What is the purpose of the salt bridge in a galvanic cell setup?

To complete the electrical circuit and prevent solutions from mixing directly

Which factor determines whether a reaction in a galvanic cell is spontaneous under standard conditions?

Electromotive force (EMF) of the cell

What role do ions play in completing the electrical circuit in a galvanic cell?

Ions facilitate movement of charge to allow continuous function of the cell

Which half-cell reaction has the higher tendency to lose electrons in a galvanic cell?

Oxidation half-cell

What is represented by the double vertical line '||' in the standard cell notation for a galvanic cell?

Salt bridge

In a galvanic cell, what does a positive EMF value indicate about the reaction under standard conditions?

The reaction is spontaneous

Which component of the galvanic cell setup allows for the flow of electrons between the two half-cells?

Inert electrode

What is the primary factor that determines whether a redox reaction in a galvanic cell is spontaneous?

Standard electrode potentials

Where does reduction occur in a galvanic cell setup?

Cathode

What is the function of an inert electrode like Pt or C in a galvanic cell when used as electrodes?

Facilitate electron flow

How is the overall cell reaction obtained in a galvanic cell from individual half-reactions?

Balancing electrons to cancel out and adding reactions

What flows through the external circuit in a galvanic cell to complete the electrical circuit?

$\text{e}^-$ (electrons)

What does the standard cell notation in a galvanic cell represent when inert electrodes are used?

Inert electrode materials

What is the main function of a salt bridge in a galvanic cell?

Helps maintain charge balance by allowing ion movement

Which direction do cations move in a galvanic cell?

Toward the cathode

What occurs at the cathode of a galvanic cell?

Reduction reaction

How do electrons flow within a galvanic cell?

From the anode to the cathode through the external circuit

What contributes to the generation of electrons in a galvanic cell?

Oxidation reaction at the anode

What is the role of an inert electrode like Pt in a galvanic cell?

Provides surface for electron transfer without participating in reactions

Where does oxidation primarily occur in a galvanic cell?

At the anode

What is the primary function of galvanic cells?

Generate electrical energy from chemical energy

What is the purpose of ion movement in a galvanic cell?

To maintain charge balance

What is the key role played by cations in a galvanic cell?

To move towards the cathode for reduction reactions

What is the primary role of the salt bridge in a galvanic cell setup?

To maintain electrical neutrality by facilitating the flow of ions between the half-cells

What determines the overall cell reaction in a galvanic cell?

The relative tendencies of the half-cell reactions to lose or gain electrons

What is the significance of a positive EMF value for a galvanic cell reaction under standard conditions?

The reaction is spontaneous and has a positive free energy change

How is the electromotive force (EMF) of a galvanic cell calculated?

By subtracting the reduction potential of the cathode from the reduction potential of the anode

Which half-reaction takes place at the cathode of a galvanic cell?

The reduction half-reaction

What is the role of an inert electrode like Pt or C in a galvanic cell?

To provide a surface for the redox reactions to occur

What is the purpose of the double vertical line '||' in the standard cell notation for a galvanic cell?

To represent the salt bridge

What is the primary factor that determines whether a redox reaction in a galvanic cell is spontaneous under standard conditions?

The relative tendencies of the half-cell reactions to lose or gain electrons

What is the direction of electron flow in a galvanic cell?

From the anode to the cathode through the external circuit

Where does oxidation primarily occur in a galvanic cell?

At the anode

What does the electromotive force (EMF) of a galvanic cell indicate when calculated using the standard reduction potentials?

The spontaneity of the redox reaction under standard conditions

In a galvanic cell, what is the function of using inert electrodes like Pt or C?

To prevent mixing of solutions and complete the electrical circuit

What is the specific role of the salt bridge in a galvanic cell setup?

Maintain electrical neutrality within the half-cells

Which factor primarily determines whether a redox reaction is spontaneous in a galvanic cell under standard conditions?

The difference in standard electrode potentials

How does oxidation occur in a galvanic cell with respect to electron transfer?

Gaining electrons at the anode

What is represented by the standard cell notation 'Zn(s) | Zn²⁺(aq) || Cu²⁺(aq) | Cu(s)' for a galvanic cell?

Oxidation of Cu and reduction of Zn

What determines whether a redox reaction in a galvanic cell is spontaneous when using standard reduction potentials?

The difference in standard electrode potentials between half-cells

What does it mean if a redox reaction in a galvanic cell has a positive electromotive force (EMF)?

The reaction is spontaneous under standard conditions

In a galvanic cell notation, what role do inert electrodes like Pt or C play when written outside the half-cell solutions?

Indicate non-reactive materials used in the setup

What does oxidation predict about a half-cell's tendency to lose electrons in a galvanic cell?

The half-cell with higher standard electrode potential loses more electrons

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