Types and Theories of Metal Corrosion

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Questions and Answers

What causes the formation of reddish brown scale on iron?

Formation of Fe2O3

Explain the formation of green scale on a copper vessel.

CuCO3 & Cu(OH)2

What are the two types of corrosion based on the way it occurs?

Dry corrosion and wet corrosion

Explain dry corrosion.

<p>Direct chemical attack by dry gases like SO2, CO2, Cl2, H2S</p> Signup and view all the answers

Describe wet corrosion and how it occurs.

<p>Electrochemical attack on the metal with moisture and oxygen present in the atmosphere</p> Signup and view all the answers

What is the fundamental principle of the electrochemical theory of corrosion?

<p>Formation of anodic and cathodic regions on the same metal surface</p> Signup and view all the answers

Explain the factors that affect the rate of galvanic corrosion.

<p>Potential difference between anodic and cathodic regions, ratio of anodic area to cathodic area, environmental factors, tendency of the metal to exhibit passivity</p> Signup and view all the answers

In a galvanic cell with iron and copper in contact, which metal acts as the anode and which as the cathode?

<p>Iron acts as the anode and copper acts as the cathode.</p> Signup and view all the answers

Describe what happens in a bimetallic couple in terms of corrosion.

<p>The metal that is anodic corrodes while the metal that becomes cathodic is protected.</p> Signup and view all the answers

Explain the reactions that take place in a galvanic cell with iron and copper electrodes.

<p>At the anode: Fe → Fe2+ + 2e-, At the cathode: O2 + 2H2O + 4e- → 4 OH-</p> Signup and view all the answers

What is differential aeration corrosion and how does it occur?

<p>Differential aeration corrosion occurs when a metal surface is exposed to varying oxygen concentrations.</p> Signup and view all the answers

Explain the process of rust formation on iron in the presence of copper in a galvanic cell.

<p>2Fe2+ + 4OH- + O2 + 2H2O → 2 Fe(OH)2 → 2 [Fe2O3.3H2O] (Rust)</p> Signup and view all the answers

What is the principle behind conductometry?

<p>Conductometry is based on the measurement of electrical conductivity of a solution.</p> Signup and view all the answers

How is iron estimated using potentiometry?

<p>Potentiometry is a method based on the measurement of the potential of an electrochemical cell involving iron ions.</p> Signup and view all the answers

Define IR spectroscopy and its application in self-study components.

<p>IR spectroscopy is a technique that measures the vibrations of chemical bonds and is used for structural analysis in self-study components.</p> Signup and view all the answers

Explain UV-Visible spectroscopy and its significance in self-study components.

<p>UV-Visible spectroscopy measures the absorption of ultraviolet and visible light by a substance, providing information about its electronic structure.</p> Signup and view all the answers

What is the electrochemical theory of corrosion based on?

<p>The electrochemical theory of corrosion is based on the transformation of pure metal into undesired metallic compounds through chemical or electrochemical attack.</p> Signup and view all the answers

How is the destruction or deterioration of metal by chemical or electrochemical attack defined?

<p>The destruction or deterioration of metal by surrounding environment through chemical or electrochemical attack is known as corrosion.</p> Signup and view all the answers

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