Types and History of Polymers

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Questions and Answers

Which of the following best describes a plastic?

  • A simple element found on the periodic table.
  • A material composed of large molecules that are synthetically made or modified. (correct)
  • A naturally occurring mineral compound.
  • A material composed of small, naturally occurring molecules.

What happens to thermosetting plastics when heated?

  • They turn to ash and cannot be used to make new objects. (correct)
  • They become more flexible and elastic.
  • They melt and can be reformed.
  • They soften and can be reshaped.

Which of the following is a characteristic of thermoplastics?

  • They are only suitable for single-use applications.
  • They decompose upon heating.
  • They soften when heated and can be reshaped. (correct)
  • They maintain a rigid shape regardless of temperature.

In what year was Polyethylene first created?

<p>1942 (C)</p> Signup and view all the answers

Which of the following is an application of Fluorocarbon?

<p>Non-stick liners (B)</p> Signup and view all the answers

Which polymer is used in living hinges and safety helmets?

<p>Polypropylene (C)</p> Signup and view all the answers

Acrylonitrile-Butadiene-Styrene (ABS) was first made in 1948, what is it commonly used in?

<p>Luggage (C)</p> Signup and view all the answers

What makes plastics useful in the automotive industry?

<p>Reduced weight (D)</p> Signup and view all the answers

Which of the following is a common application of blow molding?

<p>Manufacturing plastic bottles and containers. (D)</p> Signup and view all the answers

Which molding process is most suitable for creating complex, three-dimensional parts such as plastic model kits and bottle caps?

<p>Injection molding (B)</p> Signup and view all the answers

Which of the following processes involves forcing a melted plastic through a die or nozzle?

<p>Extrusion (B)</p> Signup and view all the answers

Which of the following products is commonly made using extrusion?

<p>Pipes and tubing (D)</p> Signup and view all the answers

What adaptation has influenced blow molding technology?

<p>The glass industry (C)</p> Signup and view all the answers

Which polymer is primarily utilized in gears?

<p>Polyimide (C)</p> Signup and view all the answers

Which processes involves injecting molten polymer material between two closed halves of a mold?

<p>Blow molding (C)</p> Signup and view all the answers

What is the approximate value of plastic materials used in the medical field in the United States as of 2000?

<p>$4 billion (B)</p> Signup and view all the answers

Which characteristics of Polycarbonate make it suitable for eye protection?

<p>Impact resistance (D)</p> Signup and view all the answers

What is the primary purpose of the 'screw' component in the extrusion process?

<p>To rotate and push the melted polymer out of the nozzle. (C)</p> Signup and view all the answers

In the melt spinning process, what is the role of the cooling air?

<p>To solidify the polymer fibers. (C)</p> Signup and view all the answers

Which of the following properties makes silicone suitable for use in gaskets, tubing, and utensils?

<p>Chemical inertness and flexibility (C)</p> Signup and view all the answers

Which of the following factors primarily contributes to the increased use of plastics in the aviation industry?

<p>Reduction of aircraft weight (C)</p> Signup and view all the answers

Which of the following materials are injection molded?

<p>Plastic bottle caps (D)</p> Signup and view all the answers

Which polymer is a key component of milk jugs?

<p>Polyethylene (A)</p> Signup and view all the answers

What aspect of plastic usage is most applicable to medicine?

<p>Sterility and Biocompatibility (B)</p> Signup and view all the answers

What properties make polymers suitable for foam cushions?

<p>Flexibility and Lightweight (B)</p> Signup and view all the answers

How does increasing the use of plastics in automobiles affect fuel efficiency?

<p>Increases fuel efficiency due to reduced weight. (C)</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between the cooling cycle and the mold in injection molding?

<p>The cooling cycle precedes the mold opening to solidify the plastic part. (C)</p> Signup and view all the answers

What is the role of the 'spinneret' in the melt spinning process?

<p>To shape the molten polymer into fibers. (A)</p> Signup and view all the answers

Why is understanding the thermal properties of different types of plastics, such as their glass transition temperature (Tg), crucial in selecting a manufacturing process?

<p>It affects the choice of molding process and processing temperature. (C)</p> Signup and view all the answers

In the context of polymer classification, what distinguishes elastomers from thermoplastics and thermosets?

<p>Elastomers exhibit high elasticity and can return to their original shape after deformation. (B)</p> Signup and view all the answers

During which stage of injection molding would issues such as 'short shots' (incomplete filling of the mold cavity) most likely be detected?

<p>Part Ejected (D)</p> Signup and view all the answers

Which material is used in skin packages and golf balls?

<p>Ionomer (B)</p> Signup and view all the answers

You are tasked with selecting a plastic for a component that must withstand high temperatures and maintain its structural integrity. Which material would be the most suitable?

<p>Polyimide (D)</p> Signup and view all the answers

A design engineer is creating a new type of medical implant that requires a material that is both biocompatible and can be precisely shaped. Which manufacturing process would be MOST appropriate?

<p>Injection molding (D)</p> Signup and view all the answers

A company is looking to reduce the environmental impact of its packaging by using a material that can be repeatedly softened and reshaped. Which plastic should they choose?

<p>Thermoplastic (C)</p> Signup and view all the answers

If you melt two distinct thermoplastic polymers together, what outcome is MOST probable regarding the properties of the resulting material?

<p>The result is highly variable and depends on various factors as polymer miscibility, processing conditions, and potential interactions. (D)</p> Signup and view all the answers

If you needed to optimize the 'cooling cycle' in injection molding, what action would MOST directly influence and shorten this phase?

<p>Implementing cooling channels closer to the mold's surface facilitates heat dispersion. (D)</p> Signup and view all the answers

Flashcards

What is a plastic?

Materials composed of large molecules which are synthetically made or modified.

Thermosetting plastic

A type of plastic that does not melt when heated; it turns to ash and cannot be reshaped.

Thermoplastic

A type of plastic that softens when heated and can be reshaped into new objects.

Extrusion

A process that involves forcing a melted plastic through a die or nozzle to create continuous shapes.

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Injection Molding

A manufacturing process where molten plastic is injected into a mold to create complex shapes.

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Blow Molding

A molding process used to create hollow plastic items like bottles by inflating a heated plastic tube inside a mold.

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Melt Spinning

A method of producing fibers by extruding molten polymer through a spinneret and then solidifying them by cooling.

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Thermoplastic

A polymer that can be reshaped with temperature.

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Thermoset Polymers

A polymer that undergoes irreversible chemical change when heated.

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Elastomers

A polymer with elastic properties.

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Study Notes

  • Plastics are materials composed of large molecules that are synthetically made or modified
  • Thermosetting plastics and Thermoplastics are the two main types of plastic
  • Thermosetting plastics do not melt when heated and turn to ash, and therefore, cannot be used to make new objects
  • Thermoplastics soften when heated, can be reshaped, and can be used to make new objects

History of Polymers

  • 1942: Polyester was used for clothing and boat hulls
  • 1942: Polyethylene was utilized for milk jugs
  • 1943: Fluorocarbon was used for industrial gaskets and non-stick liners
  • 1943: Silicone was used for gaskets, tubing, and utensils
  • 1947: Epoxy was used for glues
  • 1948: Acrylonitrile-Butadiene-Styrene was used for luggage
  • 1954: Polyurethane or Urethane was used for foam cushions, shoe soles, and wheels
  • 1956: Acetal was used for automotive and toilet parts
  • 1957: Polypropylene was used for living hinges and safety helmets
  • 1957: Polycarbonate was used for water bottles and eye protection
  • 1964: Ionomer was used for golf balls and skin packages
  • 1964: Polyimide was used for gears

Plastic Uses

  • Plastics are used in automobiles for weight reduction (mileage)
  • Plastics are used in aviation, such as the 767/787 and Voyager/Space Ship One
  • Plastics are everywhere

Plastic Intensive Vehicles

  • Corvette
  • Lotus

Medical Plastics and Composites Use

  • Containers like bottles and bags
  • Drug delivery systems, including IV bags, syringes, tubing and surgery tools
  • Implants and artificial skins
  • The use of plastic materials in the medical field amounts to about $4 billion in 2000 (US)

Classification of Polymers

  • Polymers
  • Thermoplastics
  • Thermosets
  • Elastomers

Extrusion Process

  • Extrusion involves forcing a melted plastic through a "die" or nozzle
  • Dry plastic powder or granules endure heat and pressure as they go through an extruder
  • Parts are fed to a hopper with polymer pellets, a screw then rotates to move the molten polymer through heaters
  • Extruded products include auto trim, vinyl window frames, house siding, pipes, tubing, fibers, films (bags, coverings, and laminates), and coatings

Injection Molding Process

  • Injection molding is the most important commercial method for transforming thermoplastics into useful products
  • Injection molded items are computer keyboards, plastic model or hobby kits, plastic bottle caps, circuit breakers, power tools, and tableware
  • The process includes a filling cycle, cooling cycle, mold opening, and part ejection

Melt Spinning

  • Melt spinning is a process that utilizes a heating plate, gear pump, filter pack, spinneret, cooling air, roller, and winder

Blow Molding Process

  • Blow molding technology was adapted from the glass industry for molding hollow containers from thermoplastic materials
  • Widely known blow molded objects are bottles , jars, and containers for beverage, cosmetic, medical, pharmaceutical, and home product industries
  • Step 1: Melted polymer material is injected between two closed halves of a mold
  • Step 2: Air enters the cavity to push the polymer into the shape of the mold
  • Step 3: The mold opens, and the hollow product is removed and trimmed

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