Chemistry Unit
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Questions and Answers

Which of the following is NOT typically considered evidence of a chemical change?

  • Change in state of matter (correct)
  • Release of light
  • A change in color
  • Formation of bubbles

Which process demonstrates a physical change in water?

  • Electrolysis of water into hydrogen and oxygen
  • Reaction of water with sodium metal
  • Boiling water to produce steam (correct)
  • Formation of rust when water reacts with iron

What fundamental principle is demonstrated when the total mass of reactants equals the total mass of products in a chemical reaction?

  • The Law of Multiple Proportions
  • The Law of Definite Proportions
  • The Law of Conservation of Mass (correct)
  • The Law of Conservation of Energy

In a balanced chemical equation, what is permissible to change, and what must remain constant?

<p>Coefficients can be changed, but subscripts must remain constant. (A)</p> Signup and view all the answers

Consider the reaction: $6CO_2 + 6H_2O \rightarrow C_6H_{12}O_6 + 6O_2 $. What role does $H_2O$ play in this reaction?

<p>It is a reactant. (A)</p> Signup and view all the answers

When balancing the equation $Fe + Cl_2 \rightarrow FeCl_3$, what coefficient is placed before $Fe$ to correctly balance the equation?

<p>2 (C)</p> Signup and view all the answers

A chemist observes that mixing two clear solutions results in the immediate formation of a cloudy solid. This observation is most indicative of:

<p>The formation of a precipitate. (C)</p> Signup and view all the answers

A student performs an experiment where they burn a wooden log in a controlled environment. After the log is completely burned, they collect all the remaining ash and gases. When comparing the mass before and after the experiment, which statement is most accurate concerning observations based on the Law of Conservation of Mass?

<p>The combined mass of the ash and the collected gases will be approximately equal to the original mass of the log. (A)</p> Signup and view all the answers

Which of the following is a physical change?

<p>Melting ice (C)</p> Signup and view all the answers

What is the definition of a chemical equation?

<p>A description of a reaction using element symbols and chemical formulas. (A)</p> Signup and view all the answers

In a chemical equation, what distinguishes reactants from products?

<p>Reactants are the substances consumed, and products are the substances formed. (D)</p> Signup and view all the answers

According to the law of conservation of mass, what must be true of a chemical reaction?

<p>The total mass of the reactants must equal the total mass of the products. (A)</p> Signup and view all the answers

Why is it unacceptable to change subscripts when balancing a chemical equation?

<p>Changing a subscript changes the identity of the compound or molecule. (A)</p> Signup and view all the answers

Which of the following observations most likely indicates a chemical reaction has occurred?

<p>A gas is produced when two solutions are mixed. (C)</p> Signup and view all the answers

In the balanced chemical equation for the reaction of methane ($CH_4$) with oxygen ($O_2$), what is the coefficient in front of oxygen?

<p>2 (C)</p> Signup and view all the answers

Consider the (unbalanced) reaction: $Al + HCl \rightarrow AlCl_3 + H_2$. Once balanced, what is the coefficient in front of $HCl$?

<p>6 (B)</p> Signup and view all the answers

A student mixes two clear solutions, and observes that the mixture becomes cloudy, with solid particles settling to the bottom of the container. Which of the following best describes this observation?

<p>Formation of a precipitate (A)</p> Signup and view all the answers

A chemist attempts to react two substances, but no reaction occurs. Upon closer inspection, they realize a crucial element is missing from the reactant mixture, one that is present in the products. This violates which fundamental chemical principle?

<p>The law of conservation of mass (A)</p> Signup and view all the answers

In the balanced equation $2FeBr_3 + 3H_2SO_4 \rightarrow Fe_2(SO_4)_3 + 6HBr$, what is the ratio of iron(III) bromide to sulfuric acid?

<p>2:3 (B)</p> Signup and view all the answers

For the equation $P_4 + 5O_2 \rightarrow P_4O_{10}$, what is the coefficient of the oxygen reactant?

<p>5 (B)</p> Signup and view all the answers

What type of reaction is exemplified by the general equation: Hydrocarbon + Oxygen → Water + Carbon Dioxide + Energy?

<p>Combustion (A)</p> Signup and view all the answers

Which type of reaction involves simpler substances combining to form a more complex compound?

<p>Synthesis (B)</p> Signup and view all the answers

The breakdown of $H_2CO_3$ into $H_2O$ and $CO_2$ is an example of which type of reaction?

<p>Decomposition Reaction (C)</p> Signup and view all the answers

What is the coefficient for $O_2$ when the following equation is properly balanced? $C_3H_8 + O_2 \rightarrow CO_2 + H_2O$

<p>5 (D)</p> Signup and view all the answers

What term describes the minimum energy required to initiate a chemical reaction?

<p>Activation Energy (A)</p> Signup and view all the answers

In a double replacement reaction, what type of chemical species switch places?

<p>Negative ions (C)</p> Signup and view all the answers

Which of the following is a balanced equation?

<p>$2Na + 2H_2O \rightarrow 2NaOH + H_2$ (C)</p> Signup and view all the answers

Which of the following is characteristic of an exothermic reaction?

<p>Increase in temperature (B)</p> Signup and view all the answers

What is the process by which living organisms obtain energy, similar to a combustion reaction?

<p>Cellular Respiration (A)</p> Signup and view all the answers

Which type of reaction involves one substance breaking down into two or more substances?

<p>Decomposition (C)</p> Signup and view all the answers

What is the primary characteristic of a combustion reaction?

<p>Release of energy in the form of heat and light (C)</p> Signup and view all the answers

How does a catalyst affect a chemical reaction?

<p>It decreases the activation energy. (C)</p> Signup and view all the answers

Which of the following best describes a synthesis reaction?

<p>Two or more substances combine to form a single compound. (B)</p> Signup and view all the answers

In an endothermic reaction, is energy absorbed or released, and does the temperature increase or decrease?

<p>Energy is absorbed, and temperature decreases. (C)</p> Signup and view all the answers

What role does a catalyst play in a chemical reaction?

<p>It lowers the activation energy of the reaction. (C)</p> Signup and view all the answers

Which of the following is NOT a factor that typically increases the rate of a chemical reaction?

<p>Decreasing the concentration of reactants. (B)</p> Signup and view all the answers

Identify the type of reaction represented by: $Mg + 2HCl \rightarrow MgCl_2 + H_2$

<p>Single Replacement (C)</p> Signup and view all the answers

Which of the following is an example of a balanced decomposition reaction?

<p>$2H_2O_2 \rightarrow 2H_2O + O_2$ (C)</p> Signup and view all the answers

In the balanced equation $2AlBr_3 + 3K_2SO_4 \rightarrow 6KBr + Al_2(SO_4)_3$, how many moles of $KBr$ are produced if you start with 2 moles of $AlBr_3$?

<p>6 (A)</p> Signup and view all the answers

If a substance has a pH of 14, such as Drano, what can be said about it?

<p>It is a strong base (B)</p> Signup and view all the answers

Which reaction type is represented by: $2HCl + CaCO_3 \rightarrow CaCl_2 + H_2O + CO_2$?

<p>Double Replacement (A)</p> Signup and view all the answers

In the balanced equation $2HgO \rightarrow 2Hg + O_2$, if 216.6 grams of mercury (Hg) are produced from the decomposition of mercury oxide (HgO), and knowing that the molar mass of Hg is approximately 200.59 g/mol, how many moles of $O_2$ are also produced, assuming the reaction goes to completion and the molar mass of $O_2$ is approximately 32 g/mol?

<p>Approximately 0.54 moles (A)</p> Signup and view all the answers

In an endothermic reaction, what is the relationship between the energy required to break bonds in the reactants and the energy released when products form?

<p>More energy is required to break bonds in the reactants than is released when products form. (C)</p> Signup and view all the answers

Given the unbalanced equation $FeCl_3 + NaOH \rightarrow Fe(OH)_3 + NaCl$, what is the coefficient of $NaOH$ when the equation is balanced?

<p>3 (B)</p> Signup and view all the answers

Consider a scenario where an aqueous solution of hydrochloric acid (HCl) at a concentration of 1.0 M is mixed with an equal volume of aqueous ammonia ($NH_3$) at a concentration of 1.0 M in a calorimeter. Given that the neutralization reaction releases heat, and assuming that both solutions were initially at 25°C, what would be the most likely final temperature reading of the mixture inside the calorimeter, and what can be inferred about the reaction's enthalpy change ($\Delta H$)?

<p>Slightly above 25°C; $\Delta H &lt; 0$ (exothermic reaction) (B)</p> Signup and view all the answers

Consider the reaction: $C_6H_{12}O_6 + 6O_2 \rightarrow 6CO_2 + 6H_2O$. What is the common name for this specific type of combustion reaction?

<p>Respiration (C)</p> Signup and view all the answers

Which of these processes is an example of an endothermic reaction?

<p>Photosynthesis. (C)</p> Signup and view all the answers

What is activation energy?

<p>The minimum amount of energy needed to start a chemical reaction. (C)</p> Signup and view all the answers

Which of the equations correctly represents the balanced form of: $K + MgBr_2 \rightarrow KBr + Mg$?

<p>$2K + MgBr_2 \rightarrow 2KBr + Mg$ (A)</p> Signup and view all the answers

Given the balanced equation: $1 S_8 + 12 O_2 \rightarrow 8 SO_3$, if the reaction vessel initially contains 8 moles of $S_8$ and 96 moles of $O_2$, assuming complete conversion according to the balanced chemical equation, how many moles of the limiting reactant will remain after the reaction goes to completion?

<p>0 (D)</p> Signup and view all the answers

How does increasing the surface area of a solid reactant typically affect the rate of a chemical reaction?

<p>It increases the rate of reaction. (D)</p> Signup and view all the answers

A chemist mixes two clear solutions, $A$ and $B$, and observes the formation of a yellow precipitate. Conceptualizing this scenario within the context of reaction types, select the reaction which would most probably correlate with the observed chemical process, assuming solubility rules are being followed correctly.

<p>A double displacement (metathesis) reaction that results in the formation of a new compound, which is insoluble in nature. (C)</p> Signup and view all the answers

Why does increasing the temperature generally increase the rate of a chemical reaction?

<p>Particles move faster and collide more often with greater energy. (C)</p> Signup and view all the answers

How does a catalyst increase the rate of a chemical reaction?

<p>By lowering the activation energy of the reaction. (C)</p> Signup and view all the answers

What is the primary function of an enzyme in a living cell?

<p>To speed up specific biochemical reactions. (C)</p> Signup and view all the answers

What effect do inhibitors have on chemical reactions?

<p>They slow down or stop the reaction. (D)</p> Signup and view all the answers

Cellular respiration is the reverse process of photosynthesis. Photosynthesis is endothermic, which means cellular respiration is:

<p>Exothermic. (C)</p> Signup and view all the answers

Which actions would cause an iron bar to rust more quickly?

<p>Increasing the temperature and the concentration of oxygen. (A)</p> Signup and view all the answers

Why does refrigerating food extend its life?

<p>The cold temperature slows the rate of chemical reactions that cause spoilage. (A)</p> Signup and view all the answers

A catalyst does not increase the amount of product formed in a reaction because:

<p>It only speeds up the reaction without affecting the equilibrium. (B)</p> Signup and view all the answers

How does the chewing of food relate to the rate of a chemical reaction during digestion?

<p>Chewing increases the surface area of food, speeding digestion. (D)</p> Signup and view all the answers

Predict the effect on reaction rate if a chemist tripled the concentration of a gaseous reactant and simultaneously decreased the volume of the reaction vessel to one-third of its original size, assuming temperature remains constant.

<p>The reaction rate will increase by a factor of 9 ($3 \cdot 3$). (D)</p> Signup and view all the answers

Flashcards

Signs of Chemical Change?

Change in color, odor, bubble formation, precipitate formation, temperature change, or light emission.

Chemical Change

Original substances transform into different substances with new properties.

Physical Change

A change that alters the form or appearance of a substance but does not change it into a new substance.

Law of Conservation of Mass

The total mass of reactants equals the total mass of products in a chemical reaction.

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Balancing Chemical Equations

You can only change coefficients to balance, not the subscripts.

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Coefficient

Indicates the amount of each substance involved in the reaction.

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Reactant

A starting material in a chemical reaction.

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Product

A substance formed as a result of a chemical reaction.

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Chemical Reaction

A process in which atoms rearrange to form new substances.

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Chemical Equation

A description of a reaction using element symbols and chemical formulas.

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Signs of a Chemical Reaction

Color change, odor change, bubbles, precipitate, temperature change, light release.

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Bonds in Chemical Reaction

Breaking and forming new molecules or compounds.

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Combustion Reaction

A reaction where a fuel reacts rapidly with an oxidant, usually oxygen, to produce heat and light.

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Synthesis Reaction

A reaction in which simpler substances combine to form a more complex compound.

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Decomposition Reaction

A reaction where a compound breaks down into simpler substances.

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Activation Energy

The minimum energy required to start a chemical reaction.

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Exothermic Reaction

A reaction that releases energy, usually in the form of heat, causing the temperature to increase.

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Enzymes

Biological catalysts that speed up chemical reactions in living cells.

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Catalyst

A substance that speeds up a chemical reaction without being consumed in the reaction.

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Endothermic Reaction

A reaction that absorbs energy, usually in the form of heat, causing the temperature to decrease.

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pH Scale

Scale used to specify the acidity or basicity of an aqueous solution.

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Acid

A substance with a pH less than 7.

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Base

A substance with a pH greater than 7.

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Photosynthesis

A process used by plants and other organisms to convert light energy into chemical energy.

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Single Replacement Reaction

One element replaces another in a compound.

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Double Replacement Reaction

Ions in two compounds switch places, forming two new compounds.

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Reaction Patterns

Chemical reactions grouped by similar changes.

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Inhibitor

Substance that slows down or stops a chemical reaction.

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Chemical Energy

Energy stored within chemical bonds of a substance.

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Cellular respiration

Process where a substance (typically glucose) is broken down to produce energy in cells, using oxygen and releasing carbon dioxide.

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Reaction Rate

The speed at which a chemical reaction occurs.

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Surface Area

The amount of exposed outer area of a solid.

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Temperature (Reaction Rate)

Increases reaction rate; particles move faster and collide more often.

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Concentration (Reaction Rate)

More particles available to collide, which increases reaction rate.

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Exo vs. Endo

Exothermic releases energy, endothermic absorbs it. They are reverse processes.

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Opposite of Photosynthesis?

Cellular respiration.

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Refrigeration

Colder temperatures slow down chemical reactions.

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Sun's Energy

Energy from the sun is stored in molecules like glucose via photosynthesis (endothermic), which is then released by cellular respiration (exothermic).

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Chewing Food

Increases surface area, allowing for faster digestion rates.

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Study Notes

  • A chemical reaction involves atoms of substances rearranging to form new substances.
  • In a chemical reaction, the original bonds of molecules or compounds break, and new ones form in new substances.
  • A chemical equation uses element symbols and chemical formulas to describe a reaction.
  • Reactants are the starting substances in a chemical reaction, and products are the substances produced.
  • The law of conservation of mass: the total mass of reactants equals the total mass of products in a chemical reaction.
  • Balanced equations are those that show that the amounts of each type of atom are equal on both sides of the equation.
  • Balancing occurs by adding coefficients, which are numbers in front of element symbols or chemical formulas.

Signs of a Chemical Change

  • Change in color, e.g., tarnish or rust
  • Change in odor, e.g., rotting or burning food, or HCl and zinc mixing
  • Formation of bubbles, e.g., vinegar and baking soda producing CO2
  • Formation of a precipitate (solid), e.g., cooking eggs
  • Change in temperature, e.g., burning wood increases temp
  • Release of light, e.g., a firefly

Physical vs. Chemical Changes

  • Physical change: A substance changes state (solid, liquid, gas)
  • No new substance is formed.
  • Chemical change: Original substances turn into different substances with different properties.

Examples of Water Changes

  • Physical change: boiling water, melting ice cubes, adding food coloring
  • Chemical change: decomposition of water into hydrogen and oxygen

Balancing Chemical Equations

  • Only coefficients can be changed.
  • Subscripts cannot be altered because they change the substance's formula, creating a different substance.
  • Log burning: mass transforms into ash and gas

Chemical Equations

  • In the equation 6CO2 + 6H2O → C6H12O6 + 6O2, H2O is a reactant.
  • Coefficients adjust the quantity of substances.
  • Subscripts define a substance's formula.

Balanced Equations Examples

  • 2Fe + 3Cl2 → 2FeCl3
  • C2H4 + 3O2 → 2CO2 + 2H2O
  • 2FeBr3 + 3H2SO4 → Fe2(SO4)3 + 6HBr

More Equations

  • In the equation P4 + 5O2 → P4O10, the coefficient of the oxygen reactant is 5.
  • CH4 + 2O2 → 2H2O + CO2 + energy is a combustion reaction.

Types of Reactions

  • Combustion: Involves a fuel burning.
  • Involves hydrocarbon and oxygen reactants, and water and carbon dioxide products.
  • Synthesis: Combines simpler reactants into a new compound.
  • Decomposition: Breaks down a compound into simpler substances, like carbonic acid (H2CO3) to water (H2O) and carbon dioxide (CO2).

Reaction Energy

  • Activation energy: The minimum energy to start a chemical reaction.
  • Exothermic reaction: Increases temperature.

Biological Reactions

  • Cellular respiration: A combustion-like process for energy in living things.
  • Enzymes: Biological catalysts that speed up chemical reactions.

Catalysts

  • Catalysts lower activation energy, speeding up reactions.
  • Catalysts remain unchanged after a reaction; they are not reactants or products.

Endothermic Reactions

  • Endothermic reactions: Energy is absorbed and temperature decreases.
  • All chemical reactions involve energy absorption or release.

Factors Increasing Reaction Rate

  • Increase surface area: Crumbling an Alka-Seltzer tablet.
  • Increase temperature: Food spoils faster in heat.
  • Increase concentration or pressure: Higher oxygen concentration speeds up reactions needing oxygen.
  • Catalyst/enzymes: Enzymes break down proteins.

Labeling Reactions

  • Synthesis (S): Smaller substances combine into a larger one.
  • Decomposition (D): A larger substance breaks into smaller ones.
  • Single Replacement (SR): One element replaces another in a compound. Double Replacement (DR): Two compounds switch ions.
  • Combustion (C): Hydrocarbons and oxygen form carbon dioxide and water, releasing energy.

pH Scale

  • The pH scale ranges from 0 to 14.
  • Bases pH is above 7, strong bases (Drano) have a pH of 13-14.
  • Acids pH is below 7, strong acids (HCl) have a pH of 1-2.
  • Distilled water pH is 7.

Conservation of Mass Lab

  • A vinegar and baking soda reaction in a closed system (balloon) showed mass was conserved.

Formulas

  • In the formula 2H2 + O2 → 2H2O, the reactants are 2H2 and O2, and the product is 2H2O.
  • In CH4 + 2O2 → CO2 + 2H2O, the subscript for hydrogen in methane (CH4) is 4, and the coefficient for the water product is 2.

Energy and Reactions

  • An endothermic reaction absorbs heat/energy and feels cold.
  • An exothermic reaction releases heat/energy and feels warm/hot.

Photosynthesis

  • Photosynthesis is an endothermic reaction, its energy comes from the sun
  • Energy is stored within the bonds of glucose which is an example of chemical energy.

Properties of Acids and Bases

  • Acids: Sour taste, conduct electricity, corrosive, pH less than 7 (e.g., citric acid, lemon, HCl, vinegar)
  • Bases: Slippery, bitter, corrosive, pH greater than 7 (e.g., calcium carbonate, bleach, soap, Drano)

Physical vs. Chemical Changes in Bubbles

  • Water boiling is a physical change, no new substance is formed.
  • Baking soda and vinegar mixing is a chemical change since carbon dioxide gas is produced.

Reaction types

  • Synthesis reaction involves the combination of two or more substances to create one compound.
  • Decomposition reaction involves breaking down one compound into two or more substances.
  • In single replacement one element replaces another in a compound.
  • In double replacement two compounds switch ions creating two new compounds.
  • Combustion reaction is when one substance combines with oxygen and releases energy.

Chemical Energy in Bonds

  • Energy is released in a chemical reaction and comes from the chemical energy contained in chemical bonds.
  • Breaking a chemical bond absorbs energy from the surroundings.
  • Forming a chemical bond releases energy to the surroundings.
  • The energy in chemical bonds and the energy absorbed or released is always conserved.

Endothermic Reactions

  • Endothermic reactions are chemical reactions that absorb thermal energy ex: photosynthesis
  • More energy is required to break the bonds of the reactants than is released when products form.

Exothermic Reactions

  • Cellular Respiration (combustion) is an exothermic reaction.
  • Combustion of fuel & other hydrocarbons (wood) is also an exothermic reaction
  • Less energy is required to break the bonds of the reactants than is released when products form.

Activation Energy

  • All reactions require energy to start the breaking of bonds
  • Activation energy is the minimum amount of energy that is needed to start a chemical reaction.

Reaction Rates

  • Surface area can affect the rate of a reaction.
  • Increased surface area increases the rate of reaction.
  • Temperature can affect the rate of reaction, at higher temperatures particles move faster.
  • An increase in concentration also increases reaction rate.
  • Catalysts increase reaction rate by lowering the activation energy of a reaction.
  • An enzyme is a catalyst that speeds up chemical reactions in living cells

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