Trends in Atomic Radius

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Questions and Answers

What does K L M N stand for?

The number of shells in an atom

How does the number of shells affect the atomic radius?

The atomic radius increases as the number of shells increases.

What happens to the atomic radius as you move across a period?

The atomic radius decreases as you move across a period.

Describe the shielding effect.

<p>The shielding effect refers to the repulsion of the outermost electrons by the inner electrons.</p> Signup and view all the answers

What happens to the atomic radius as the shielding effect increases?

<p>The atomic radius increases.</p> Signup and view all the answers

Flashcards

Atomic radius trend across a period

The number of electron shells surrounding the nucleus increases from left to right across a period.

Atomic radius trend down a group

The number of electron shells increases as you move down a group.

Shielding effect

The inner electrons shield the outer electrons from the full attraction of the nucleus, making the outer electrons less tightly held, leading to a larger atomic radius.

Nuclear charge effect

As the number of protons increases, the attraction between the nucleus and the electrons increases, pulling them closer and decreasing the atomic radius.

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Atomic radius trend across a period (continued)

The decrease in atomic radius across a period is mainly due to the increase in nuclear charge, which outweighs the shielding effect.

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Atomic radius trend down a group (continued)

The increase in atomic radius down a group is due to the increase in the number of electron shells, which overcomes the increase in nuclear charge.

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Electron shells across a period

Across a period, the number of electron shells stays the same.

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Electron shells down a group

Down a group, the number of electron shells increases.

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Shielding effect across a period

The shielding effect decreases across a period because the number of inner electrons stays the same, while the nuclear charge increases.

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Shielding effect down a group

The shielding effect increases down a group because the number of inner electrons increases, creating a stronger shield against the nucleus.

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Nuclear charge vs. shielding effect down a group

As you move down a group, the nuclear charge also increases, but the shielding effect increases even more.

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Atomic radius and ionization energy

The strong attraction between the nucleus and the electrons in a smaller atom leads to a higher ionization energy. It takes more energy to remove an electron from a smaller atom.

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Atomic radius and ionization energy (continued)

The larger atomic radius of elements down a group means that the outermost electrons are farther from the nucleus, and are easier to remove.

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Atomic radius and ionization energy (continued 2)

The smaller atomic radius of elements across a period means that the outer electrons are more attracted to the nucleus, making it harder to remove them.

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Atomic radius and electronegativity

Atoms with a larger atomic radius tend to have a lower electronegativity. The farther away the valence electrons are from the nucleus, the less they attract electrons from other atoms.

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Atomic radius and electronegativity (continued)

Atoms with a smaller atomic radius tend to have a higher electronegativity. The closer the valence electrons are to the nucleus, the more they attract electrons from other atoms.

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Study Notes

Variation of atomic radius

  • Atomic radius varies across the periodic table (left to right).
  • The number of shells remains constant across a period.

Shielding Effect

  • Atomic number increases, the number of inner electrons decreases
  • Shielding effect also decreases, and atomic radius decreases.

Nuclear Charge

  • Atomic number increases, nuclear charge increases.
  • Atomic radius decreases.

Number of Shells

  • Moving down a group, the number of shells increases.
  • Atomic radius increases.
  • Moving down a group, the nuclear charge increases and atomic radius increases.

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