Transport Phenomena Fundamentals
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Questions and Answers

In heat transfer through a solid slab, what does the term '$k$' represent in Fourier's Law?

  • The thermal conductivity of the slab (correct)
  • The heat flux through the slab
  • The temperature difference across the slab
  • The thermal resistance of the slab

Fick's First Law describes mass transfer based on what driving force?

  • Pressure gradient
  • Concentration gradient (correct)
  • Velocity gradient
  • Temperature gradient

According to the principles of transport phenomena, which direction does heat flow?

  • From low concentration to high concentration
  • From high concentration to low concentration
  • From low temperature to high temperature
  • From high temperature to low temperature (correct)

What best describes the fundamental processes of momentum, heat, and mass transport?

<p>Momentum transport is the transfer of motion, heat transport is the transfer of thermal energy, and mass transport is the transfer of substances. (D)</p> Signup and view all the answers

In the context of mass transfer, what is the significance of $D_{AB}$?

<p>Diffusivity of A in B (B)</p> Signup and view all the answers

In which direction do heat, momentum, and mass transport typically occur in a system?

<p>From regions of higher to lower temperature, velocity, and concentration, respectively. (B)</p> Signup and view all the answers

Which of the following analogies is correct regarding the driving force in different transport phenomena?

<p>Momentum Transfer: Velocity gradient (D)</p> Signup and view all the answers

What is the correct relationship between flux and the transferring quantity in heat transfer?

<p>The flux describes the rate of transfer of molecular energy. (B)</p> Signup and view all the answers

What characterizes molecular transport in the context of transport phenomena?

<p>It depends on the motion of individual molecules for the transport of mass, heat, or momentum. (C)</p> Signup and view all the answers

If the temperature difference across a slab is doubled and the thermal conductivity remains the same, how does the heat flux change according to Fourier's Law?

<p>The heat flux is doubled. (A)</p> Signup and view all the answers

Which of the following applications is primarily concerned with the transfer of momentum in moving media?

<p>Sedimentation processes in fluid flow (C)</p> Signup and view all the answers

Heat transfer involves the movement of energy from high-energy molecules to low-energy molecules, characterized by which quantity?

<p>Heat, $mC_pT$ (B)</p> Signup and view all the answers

Considering Fick's First Law, if the diffusivity $D_{AB}$ increases while the concentration gradient remains constant, what happens to the molar flux $J_{Ay}$?

<p>$J_{Ay}$ increases (B)</p> Signup and view all the answers

In mass transfer, what drives the movement of molecules from one phase to another?

<p>A concentration gradient (B)</p> Signup and view all the answers

What differentiates turbulent transport from molecular transport?

<p>Turbulent transport is chaotic and fast, while molecular transport is orderly and slow. (C)</p> Signup and view all the answers

Considering an ice cube placed in warm water, which action would most effectively speed up the cooling process, utilizing principles of transport phenomena?

<p>Stirring the water to enhance turbulent transport. (B)</p> Signup and view all the answers

According to the Kinetic Molecular Theory, what type of collisions do gas molecules experience?

<p>Perfectly elastic (B)</p> Signup and view all the answers

Which statement is NOT consistent with the Kinetic Molecular Theory of gases?

<p>Kinetic energy is lost due to collisions between gas molecules. (C)</p> Signup and view all the answers

The Kinetic Theory of Gases assumes gas molecules behave as perfect spheres with diameter $d$. What is the significance of this assumption?

<p>It simplifies the calculation of the mean free path. (A)</p> Signup and view all the answers

According to the Kinetic Theory of Gases, what happens to the mean free path ($l$) of a gas molecule if the number density of molecules increases at a constant temperature?

<p>$l$ decreases because more molecules mean more frequent collisions, reducing the distance between collisions. (D)</p> Signup and view all the answers

In real gases, intermolecular forces and the volume of molecules are not negligible. How does this affect the applicability of the Kinetic Theory of Gases?

<p>The Kinetic Theory provides a good approximation only at low pressures and high temperatures. (B)</p> Signup and view all the answers

If the temperature of a gas is doubled, how does the average kinetic energy of the gas molecules change?

<p>It doubles. (C)</p> Signup and view all the answers

A gas mixture contains two types of molecules with different masses. According to the Kinetic Theory of Gases, which molecules will have the higher average speed at the same temperature?

<p>The lighter molecules will have a higher average speed. (D)</p> Signup and view all the answers

How is the mean free path ($l$) related to the effective molecular diameter ($d$) of gas molecules according to the Kinetic Theory of Gases?

<p>$l$ decreases as $d$ increases because larger molecules have a higher probability of collision. (C)</p> Signup and view all the answers

In the context of molecular transport phenomena, what is the fundamental characteristic that momentum, energy, and mass transfer have in common?

<p>They all involve transport of 'something', and that transport occurs from high to low. (A)</p> Signup and view all the answers

Which of the following statements accurately describes Newton's Law of Viscosity?

<p>The shear stress in a fluid is proportional to the velocity gradient. (B)</p> Signup and view all the answers

What do Fourier's Law and Fick's Law have in common regarding transport processes?

<p>Both describe transport driven by a gradient: temperature for Fourier's Law and concentration for Fick's Law. (C)</p> Signup and view all the answers

In the general transport equation $\psi_z = -\delta \frac{d\Gamma}{dz}$, what does the term $\delta$ represent?

<p>The diffusivity (A)</p> Signup and view all the answers

According to the general transport equation, how is the 'rate' of transport related to the 'driving force' and 'resistance'?

<p>$rate = \frac{driving force}{resistance}$ (D)</p> Signup and view all the answers

A fluid is at rest between two parallel plates. The bottom plate is suddenly moved with a velocity V, and after some time, a linear velocity profile is attained. At steady state, what is the relationship between the force F required to maintain the movement, the area A of the plate, the fluid's viscosity $\mu$, the velocity V, and the distance Y between the plates?

<p>$\frac{F}{A} = -\mu \frac{V}{Y}$ (C)</p> Signup and view all the answers

Newton's Law of Viscosity is represented by $\tau = -\mu \frac{dv}{dy}$. In this equation, what does $\frac{dv}{dy}$ represent?

<p>Velocity gradient (B)</p> Signup and view all the answers

In the context of flux and driving forces, how is the flux related to the gradient and the transport coefficient?

<p>$Flux = Transport\ Coefficient \times Gradient$ (D)</p> Signup and view all the answers

Flashcards

Gas Composition

Tiny, discrete particles (atoms or molecules) that compose gases.

Gas Molecular motion

Gases move randomly, colliding with each other and container walls.

Perfectly Elastic Collisions

Collisions where kinetic energy is conserved; no energy lost.

Temperature and Kinetic Energy

Temperature is directly proportional to the average kinetic energy of gas molecules.

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Intermolecular Forces (Gases)

Attractive or repulsive forces between gas molecules are negligible. Occurs at low pressure

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Gas Particle Volume

The volume of gas particles is insignificant compared to the total gas volume.

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Mean Free Path

The average distance a molecule travels between collisions.

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Mean Time between Collisions

The average time it takes for a molecule to travel its mean free path.

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Momentum Transport

Transfer of motion in a moving medium.

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Heat Transfer

Transfer of thermal energy from high to low energy molecules.

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Mass Transfer

Transfer of mass from high to low concentration between phases.

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Molecular Transport

Mass, heat, or momentum transfer due to individual molecule movement.

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Molecular Transport (Speed)

Orderly but slower transport mechanism.

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Turbulent Transport (Speed)

Chaotic but faster transport mechanism.

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Incorrect statement about transport

Flow of energy, heat involves mass movement, and mass involves viscosity.

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Direction of Transport

From regions of higher to lower temperature, velocity, and concentration, respectively.

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Phenomenological Laws

Governing equations for momentum, energy, and mass transfer, describing transport from high to low concentrations.

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Newton's Law of Viscosity

Shear stress in a fluid is proportional to the velocity gradient.

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Fourier's and Fick's Law Commonality

Describes transport driven by a gradient: temperature (Fourier's Law) and concentration (Fick's Law).

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General Transport Equation Components

Property flux, diffusivity, transported property, and direction of transfer.

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General Transport Equation

ψ_z = -δ (dΓ/dz), where ψ_z is flux, δ is diffusivity, Γ is transported property, and z is direction.

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Transport Rate Equation

rate = driving force / resistance

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Newton's Law of Viscosity (Equation)

τ = -μ (dv/dy), where τ is shear stress, μ is viscosity, and dv/dy is velocity gradient.

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Temperature Gradient

Describes how temperature changes in space, specifically dT/dy.

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Heat Transfer: Q/A

Heat transfer rate (Q) per unit area (A) is proportional to the temperature difference (T1 - T2) over a distance (Δx).

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Fourier's Law

The equation: q_x = -k (dT/dx), describes heat flux (q_x) as proportional to the negative temperature gradient (dT/dx), where k is thermal conductivity.

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Fick's First Law

Molar flux of component A (J_Ay) is proportional to the negative concentration gradient (dC_A/dy), with D_AB as the diffusivity.

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Momentum Transfer Flux

Relates shear stress (τ) to velocity gradient (dv/dy) with viscosity (μ) as the transport coefficient.

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Heat Transfer Flux

Heat flux (q/A) is proportional to the temperature gradient (dT/dx) with thermal conductivity (k) as the transport coefficient.

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Mass Transfer Flux

Molar flux (J_A) is proportional to the concentration gradient (dC_A/dx), with diffusivity (D_AB) as the transport coefficient.

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Fourier's Law & Fick's Law

Both describe a flux (heat or mass) as proportional to a gradient (temperature or concentration).

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Study Notes

  • ChE 407 covers momentum transfer, which is an introduction to transport processes.

Kinetic Molecular Theory

  • Gases comprise minute discrete particles referred to as atoms or molecules
  • The molecules move randomly while they collide with each other as well as the walls of their container
  • Collisions between molecules do not result in energy loss due to friction, thus remain perfectly elastic
  • Absolute temperature relates proportionally to average kinetic energy
  • At relatively low pressures, the average intermolecular distance significantly exceeds the molecular diameters, rendering the Intermolecular Forces of Attraction, IMFA negligible
  • Particle volume is minuscule compared to the entire gas

Kinetic Theory of Gases

  • Gases consist of molecules, each shaped like a perfect sphere
  • Gas molecules do not have attractive or repulsion forces between them
  • Molecule volume is negligible relative to the space separating them
  • Collisions are perfectly elastic
  • Molecules move randomly at average speed in random directions
  • Individual molecules travel a certain distance "l" between collisions, which relates to the mean free path
  • The mean free path describes the required time it takes for each molecule to travel at average speed between collisions
  • Statistical averages describe large numbers of molecules

Types of Transport

  • Molecular transport relies on molecule motion for mass, heat, or momentum
  • Microscopic changes influence macroscopic observation
  • Momentum transfer, commonly called fluid mechanics, focuses on momentum transfer in moving media
  • Momentum transfer relates to separation processes of fluid flow, sedimentation, mixing, and filtration
  • Heat transfer relates to transfer energy as heat from high to low-energy molecules through drying, evaporation, or distillation
  • Mass transfer transfers material or mass from one phase to another when molecules shift from high to low concentrations from processes like distillation, absorption, liquid-liquid extraction, or crystallization
  • Transport phenomena take place through molecular or turbulent mechanisms
  • Molecular transport is orderly but gradual
  • Turbulent transport is chaotic but rapid

Molecular Transport

  • Molecular transport transports momentum, energy, and mass from high to low concentrations
  • Molecular transports follow similar governing equations or Phenomenological Laws

General Transport Equation

  • Molecular transport mechanisms follow the general equation:
    • Ψz = -δ(dΓ/dz) where:
      • Ψz = property flux (flux = rate/area)
      • δ = diffusivity (momentum, thermal, and mass diffusivity)
      • Γ = transported property (momentum, energy, and concentration)
      • z = direction of transfer
  • Rate can be described:
    • rate = drivingforce/ resistance

Newton's Law of Viscosity

  • A liquid at rest between two plates starts to flow upon the bottom plate's movement at velocity V, which causes laminar flow
    • F/A=-μ(0-V)/(Y-0)
    • Ï„ = -μ(dv/dy)
    • Ï„ is shear stress
    • μ corresponds to viscosity

Flux occurs due to a driving force

  • Flux = (Flow Quantity/ (Time)(Area)
  • Flux = (Transport Coefficient)(Gradient)
  • Expressing unidirectional temperature gradients:
    • Temperature Gradient = dT/dy

Fourier's Law states heat will flow from high to low temperatures

  • The temperature of one of the opposite faces of the slab increases to T2. The result is that heat flows from the higher to the lower temperature region
  • Q/A = -k((T1-T2)) /Δx
  • qx = -k dT/dx
  • qx is heat flux in the x direction
  • k signifies thermal conductivity

Fick's First Law

  • Fick's First Law covers mass transfer due to concentration differences in a binary system
  • JAy = -DAB dCA/dy where:
    • JAy = molar flux of component A in the y direction
    • DAB = the diffusivity of A in B (the other component); transport coefficient
    • dCA/dy = change in concentration with respect to position

Transport Phenomena Comparisons

  • Momentum:
    • Flux: Ï„ = F/A
    • Driving Force: dv/dy = Δv/Δy
    • Diffusivity: μ
    • Transferring Quantity: Molecular Velocity
    • Direction: high to low velocity
  • Heat:
    • Flux: Q = q/A
    • Driving Force: dT/dx = ΔT/Δx
    • Diffusivity: k
    • Transferring Quantity: Molecular energy (temperature)
    • Direction: high to low temperature
  • Mass:
    • Flux: JA = NA/A
    • Driving Force: dCA/dx = ΔCA/Δx
    • Diffusivity: DAB
    • Transferring Quantity: Molecules
    • Direction: high to low concentration

Transport Properities

  • Diffusivity relates to each molecular transport
  • Momentum (μ), Heat (k), and Mass (DAB) diffusivities all have the same dimensions: L2/t

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Explore fundamental concepts in transport phenomena including heat transfer, mass transfer, and momentum transfer. Understand Fourier's Law, Fick's First Law, and the driving forces behind these phenomena. Learn about molecular transport and the relationships between flux and transferring quantities.

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