Titrations: Strong Acids and Alkalis

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson
Download our mobile app to listen on the go
Get App

Questions and Answers

Why is it crucial to use a suitable indicator in a titration, and what property of indicators makes them effective for this purpose?

A suitable indicator exhibits a distinct, easily observable color change within a narrow pH range that closely matches the equivalence point of the titration. This ensures accurate determination of the reaction's completion.

Explain how you would determine both the endpoint and the equivalence point in a titration experiment, and discuss whether these points are always identical.

The endpoint is determined experimentally by observing a distinct color change of the indicator. The equivalence point is the theoretical point where the acid and base have completely neutralized each other. These points are not always identical; the endpoint ideally should be as close as possible to the equivalence point but may vary depending on the indicator used.

In a titration, if you overshoot the endpoint by adding too much titrant, how would you correct this to obtain a more accurate result? Describe the technique and the chemistry behind it.

To correct overshooting the endpoint, back titration should be performed. A known excess of a standard solution (e.g., acid) is added, then the excess is titrated with another standard solution (e.g., base). This allows precise determination of the amount of the original analyte.

Describe the effect of using a burette that was not rinsed with the titrant solution before the titration on the molarity calculation of the unknown solution?

<p>If the burette is not rinsed with the titrant solution before use, any remaining water will dilute the titrant, leading to a lower concentration than expected. Consequently, the calculated molarity of the unknown solution will be incorrectly higher.</p> Signup and view all the answers

Explain why a strong acid-strong base titration is generally more accurate and easier to perform compared to a weak acid-strong base titration.

<p>Strong acid-strong base titrations have a sharper, more distinct endpoint due to the complete reaction and significant pH change near the equivalence point. Weak acid-strong base titrations have a less pronounced pH change, making endpoint detection more challenging and less accurate.</p> Signup and view all the answers

If air bubbles are present in the tip of the burette during a titration, how does this affect the accuracy of the results? Explain the error introduced.

<p>Air bubbles in the burette tip can lead to inaccurate volume readings. The recorded volume will be higher than the actual volume of titrant dispensed, because the space occupied by the air bubble is included in the volume measurement. This results in an underestimation of the concentration of the solution being titrated.</p> Signup and view all the answers

Describe a scenario where using a mixed indicator (a combination of two or more indicators) would be advantageous over using a single indicator in a titration. Explain the principle behind using mixed indicators.

<p>A mixed indicator is advantageous when the pH change at the equivalence point is broad or gradual. Mixed indicators provide a sharper, more distinct color change by combining indicators with overlapping pH ranges, making the endpoint more easily detectable.</p> Signup and view all the answers

Explain the purpose of performing a 'rough titration' before conducting accurate titrations. What information is gained, and how does it improve the accuracy of subsequent titrations?

<p>A rough titration is performed to quickly estimate the approximate volume of titrant needed to reach the equivalence point. This prevents overshooting in subsequent, more accurate titrations, saving time and resources while improving precision.</p> Signup and view all the answers

In the context of titrations, explain the difference between a primary standard and a secondary standard. Provide an example of each, and describe why primary standards are essential for accurate titrations.

<p>A primary standard is a highly pure, stable compound used to directly prepare a solution of known concentration. Example: potassium hydrogen phthalate (KHP). A secondary standard is a solution whose concentration is determined by titrating against a primary standard. Example: NaOH solution. Primary standards are essential because they ensure the accurate determination of titrant concentration.</p> Signup and view all the answers

How would you adjust a titration procedure if you suspected that the analyte solution was not homogenous? Explain the steps you would take to ensure your results are still accurate and reliable.

<p>If the analyte solution is suspected to be non-homogeneous, vigorous mixing is essential before taking any aliquots for titration. Multiple titrations should be performed on different aliquots to assess variability. If significant variation persists, a larger sample size or modified sampling technique may be needed.</p> Signup and view all the answers

Flashcards

What is a pH indicator?

A substance that changes color depending on the pH of the solution it's in.

What is the pH scale?

A scale used to specify the acidity or basicity of an aqueous solution.

What is titration?

A technique where a solution of known concentration is used to determine the concentration of an unknown solution.

What is the purpose of titrations?

To accurately determine the volume of acid needed to neutralize a base, or vice versa.

Signup and view all the flashcards

List common strong acids used in titrations.

Sulfuric, hydrochloric, and nitric acids.

Signup and view all the flashcards

What calculations are involved in titrations?

Calculations using volumes and concentrations (mol/dm³ or g/dm³) to find the amount of substance.

Signup and view all the flashcards

Study Notes

  • The reaction between an acid and a base can be represented by the equation: H+ + OH- -> H2O
  • Universal indicator, or a wide range indicator, can measure the approximate pH of a solution
  • The pH scale identifies acidic or alkaline solutions

Titrations

  • Titrations measure the volumes of acid and alkali solutions that react with each other using a suitable indicator.
  • Titrations are carried out using strong acids and strong alkalis to find the reacting volumes
  • Sulfuric, hydrochloric, and nitric acids are suitable for titrations
  • Chemical quantities in titrations can be accurately calculated involving concentrations in mol/dm3 and in g/dm3.
  • Quantities in titrations include concentrations in mol/dm3 and in g/dm3

Required practical 2

  • Determination of the reacting volumes of solutions of a strong acid and a strong alkali by titration
  • Determination of the concentration of one of the solutions in mol/dm3 and g/dm3 from the reacting volumes and the known concentration of the other solution is required.

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

More Like This

Acid-Base Reactions and Theories
5 questions
Acid-Base Titration Quiz
8 questions

Acid-Base Titration Quiz

EnergyEfficientTopaz8386 avatar
EnergyEfficientTopaz8386
Titration Gizmos Answer Key Flashcards
5 questions
Chemistry of Acid-Base Reactions
50 questions
Use Quizgecko on...
Browser
Browser