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Questions and Answers
Why is it crucial to use a suitable indicator in a titration, and what property of indicators makes them effective for this purpose?
Why is it crucial to use a suitable indicator in a titration, and what property of indicators makes them effective for this purpose?
A suitable indicator exhibits a distinct, easily observable color change within a narrow pH range that closely matches the equivalence point of the titration. This ensures accurate determination of the reaction's completion.
Explain how you would determine both the endpoint and the equivalence point in a titration experiment, and discuss whether these points are always identical.
Explain how you would determine both the endpoint and the equivalence point in a titration experiment, and discuss whether these points are always identical.
The endpoint is determined experimentally by observing a distinct color change of the indicator. The equivalence point is the theoretical point where the acid and base have completely neutralized each other. These points are not always identical; the endpoint ideally should be as close as possible to the equivalence point but may vary depending on the indicator used.
In a titration, if you overshoot the endpoint by adding too much titrant, how would you correct this to obtain a more accurate result? Describe the technique and the chemistry behind it.
In a titration, if you overshoot the endpoint by adding too much titrant, how would you correct this to obtain a more accurate result? Describe the technique and the chemistry behind it.
To correct overshooting the endpoint, back titration should be performed. A known excess of a standard solution (e.g., acid) is added, then the excess is titrated with another standard solution (e.g., base). This allows precise determination of the amount of the original analyte.
Describe the effect of using a burette that was not rinsed with the titrant solution before the titration on the molarity calculation of the unknown solution?
Describe the effect of using a burette that was not rinsed with the titrant solution before the titration on the molarity calculation of the unknown solution?
Explain why a strong acid-strong base titration is generally more accurate and easier to perform compared to a weak acid-strong base titration.
Explain why a strong acid-strong base titration is generally more accurate and easier to perform compared to a weak acid-strong base titration.
If air bubbles are present in the tip of the burette during a titration, how does this affect the accuracy of the results? Explain the error introduced.
If air bubbles are present in the tip of the burette during a titration, how does this affect the accuracy of the results? Explain the error introduced.
Describe a scenario where using a mixed indicator (a combination of two or more indicators) would be advantageous over using a single indicator in a titration. Explain the principle behind using mixed indicators.
Describe a scenario where using a mixed indicator (a combination of two or more indicators) would be advantageous over using a single indicator in a titration. Explain the principle behind using mixed indicators.
Explain the purpose of performing a 'rough titration' before conducting accurate titrations. What information is gained, and how does it improve the accuracy of subsequent titrations?
Explain the purpose of performing a 'rough titration' before conducting accurate titrations. What information is gained, and how does it improve the accuracy of subsequent titrations?
In the context of titrations, explain the difference between a primary standard and a secondary standard. Provide an example of each, and describe why primary standards are essential for accurate titrations.
In the context of titrations, explain the difference between a primary standard and a secondary standard. Provide an example of each, and describe why primary standards are essential for accurate titrations.
How would you adjust a titration procedure if you suspected that the analyte solution was not homogenous? Explain the steps you would take to ensure your results are still accurate and reliable.
How would you adjust a titration procedure if you suspected that the analyte solution was not homogenous? Explain the steps you would take to ensure your results are still accurate and reliable.
Flashcards
What is a pH indicator?
What is a pH indicator?
A substance that changes color depending on the pH of the solution it's in.
What is the pH scale?
What is the pH scale?
A scale used to specify the acidity or basicity of an aqueous solution.
What is titration?
What is titration?
A technique where a solution of known concentration is used to determine the concentration of an unknown solution.
What is the purpose of titrations?
What is the purpose of titrations?
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List common strong acids used in titrations.
List common strong acids used in titrations.
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What calculations are involved in titrations?
What calculations are involved in titrations?
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Study Notes
- The reaction between an acid and a base can be represented by the equation: H+ + OH- -> H2O
- Universal indicator, or a wide range indicator, can measure the approximate pH of a solution
- The pH scale identifies acidic or alkaline solutions
Titrations
- Titrations measure the volumes of acid and alkali solutions that react with each other using a suitable indicator.
- Titrations are carried out using strong acids and strong alkalis to find the reacting volumes
- Sulfuric, hydrochloric, and nitric acids are suitable for titrations
- Chemical quantities in titrations can be accurately calculated involving concentrations in mol/dm3 and in g/dm3.
- Quantities in titrations include concentrations in mol/dm3 and in g/dm3
Required practical 2
- Determination of the reacting volumes of solutions of a strong acid and a strong alkali by titration
- Determination of the concentration of one of the solutions in mol/dm3 and g/dm3 from the reacting volumes and the known concentration of the other solution is required.
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