Titrations in Analytical Chemistry
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Questions and Answers

What is the major difference between the equivalence point and the end point in a titration?

  • Color change
  • Chemical reaction
  • Volume difference (correct)
  • Physical change

Why are weak acids and bases never used as standard reagents in acid-base titrations?

  • They are colorless
  • They react incompletely with analytes (correct)
  • They are too stable
  • They are too reactive

Why are HCl and NaOH classified as secondary standard solutions?

  • They are less pure than primary standards (correct)
  • They are highly stable
  • They react selectively with analytes
  • They react completely with analytes

In complexometric titration, what forms a covalent bond with a metal atom to produce a complex?

<p>Ligand (D)</p> Signup and view all the answers

What type of acid-base titration results in a solution with pH greater than 7 at the equivalence point?

<p>Weak acid + strong base (A)</p> Signup and view all the answers

Why is EDTA commonly used as a complexometric titrant?

<p>It forms a colored complex with metal ions (A)</p> Signup and view all the answers

What type of ligand has two groups available for covalent bonding?

<p>Bidentate (D)</p> Signup and view all the answers

In precipitation titration, what method is based on the formation of slightly soluble precipitates?

<p>Precipitation titration (B)</p> Signup and view all the answers

Which method of detection of endpoint utilizes adsorption indicators?

<p>Fajans Method (B)</p> Signup and view all the answers

What does an acid-base indicator do in a titration?

<p>Undergoes color change near the equivalence point (C)</p> Signup and view all the answers

Why is AgCl ppt. in the Volhard method filtered before undertaking the back titration?

<p>To prevent interference with the back titration (D)</p> Signup and view all the answers

In the Volhard method, why must the solution be a strong acid?

<p>To avoid side reactions involving hydroxide ions (B)</p> Signup and view all the answers

Why is the pH range of Mohr method titration specified to be between 6.5-9?

<p>To avoid unwanted precipitate formation (B)</p> Signup and view all the answers

Why is the Volhard method rarely used nowadays?

<p>It is time-consuming due to multiple steps involved (D)</p> Signup and view all the answers

Why does the first drop of excess Ag+1 react with Fluorescein indicator in the Volhard method?

<p>To indicate the endpoint of the titration (C)</p> Signup and view all the answers

Why does the Mohr method not use CrO4-2 for titrations involving Ag+1?

<p>CrO4-2 forms a complex that interferes with endpoint detection (C)</p> Signup and view all the answers

Why does the Volhard method not use for determination of SCN-1?

<p>Scn-1 forms a colored complex that affects endpoint detection (A)</p> Signup and view all the answers

What is the purpose of using a strong acid solution in the Volhard method?

<p>To prevent side reactions involving hydroxide ions (B)</p> Signup and view all the answers

Why do types of redox indicators differ based on their oxidized and reduced forms' colors?

<p>To provide visual cues for endpoint detection during titrations. (C)</p> Signup and view all the answers

In oxidation-reduction reactions, what characterizes an oxidizing agent?

<p>Substance that accepts electrons and gets oxidized. (A)</p> Signup and view all the answers

What is the purpose of titration methods in Analytical Chemistry?

<p>To measure the quantity of a reagent needed to react with the analyte completely (A)</p> Signup and view all the answers

What is the function of a standard solution in volumetric titrations?

<p>To be a solution of known concentration (C)</p> Signup and view all the answers

When is back-titration used in titration methods?

<p>When stability of the standard solution is a concern (A)</p> Signup and view all the answers

What is the Equivalence point in a titration?

<p>The point when added standard reagent equals the analyte (D)</p> Signup and view all the answers

Which statement best describes an Analyte in titration methods?

<p>It's a solution of unknown concentration but known volume (B)</p> Signup and view all the answers

In a volumetric titration, why is it important to measure the volume of the standard solution needed for complete reaction?

<p>To know how much reagent is needed for complete reaction (A)</p> Signup and view all the answers

What does the End Point indicate in a titration?

<p>The completion of the titration reaction (C)</p> Signup and view all the answers

How is back-titration different from direct titration?

<p>In back-titration, an excess of one standard solution reacts with an analyte first. (A)</p> Signup and view all the answers

What is the role of the burette in volumetric titrations?

<p>To deliver controlled amounts of standard solution to the analyte. (B)</p> Signup and view all the answers

When is a back-titration preferred over direct titration?

<p>When there are issues with slow reactions or unstable standard solutions. (C)</p> Signup and view all the answers

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