Thomson's Plum Pudding Model of the Atom
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Questions and Answers

What is the primary method used to measure the wettability of a solid surface?

  • Contact angle measurement (correct)
  • Force microscopy of surfaces
  • Spectroscopic methods
  • Polymer melt
  • What is the term used to describe the tendency of similar molecules to attract each other?

  • Wettability
  • Cohesion (correct)
  • Surface energy
  • Adhesion
  • What is the formula used to represent Young's equation?

  • γSV = γSL - γLV
  • γSV = γSL + γLV (correct)
  • γLV = γSV - γSL
  • γSL = γSV + γLV
  • What is the characteristic of a solid surface that is ideal for measuring wettability?

    <p>Perfectly smooth and chemically homogeneous</p> Signup and view all the answers

    What is the significance of a contact angle greater than 90°?

    <p>The surface is unfavourable to wetting</p> Signup and view all the answers

    What is the term used to describe the attraction between dissimilar molecules?

    <p>Adhesion</p> Signup and view all the answers

    What is the purpose of measuring the surface energy of a solid?

    <p>To determine the wettability of the surface</p> Signup and view all the answers

    What is the advantage of using contact angle measurement to determine the wettability of a solid surface?

    <p>It is a simple and least expensive method</p> Signup and view all the answers

    What is the significance of a contact angle of 0°?

    <p>The surface is completely wettable</p> Signup and view all the answers

    What is the term used to describe the balance between cohesion and adhesion?

    <p>Wettability</p> Signup and view all the answers

    Study Notes

    Atomic Models

    • Thomson's model of the atom: electrons in homogeneous spheres of positive charge (plum-pudding model)
    • Thomson's model limitations: only determined relative charge-to-mass ratio of electron and proton
    • Robert Millikan's contribution: determined actual charge on the electron, allowing Thomson to calculate actual mass of electron and proton

    Rutherford's Alpha Particle Experiment

    • Rutherford's experiment: firing alpha particles at thin gold foils
    • Unexpected observation: alpha particles deflected at large angles, contradicting the plum-pudding model
    • Rutherford's conclusion: alpha particles are helium atoms that have lost all their electrons

    Metallic Bonding

    • Electron sea model: positively charged metal atoms embedded in a sea of shared electrons
    • Characteristics of metals: low to moderate hardness, very malleable and ductile, soluble in acids, good thermal and electrical conductors

    Chemical Equilibrium

    • Chemical equilibrium: a dynamic, reversible process where reactants and products are constantly being formed
    • Equilibrium constant expression: [B] / [A]^2
    • Equilibrium constant (K): a measure of the ratio of concentrations of products to reactants at equilibrium

    Equilibrium Expressions Involving Pressures

    • For gases: PV = nRT or P = CRT / V
    • Equilibrium constant expression for gases: KP = KC.RT^Δn
    • Δn: the difference between the number of moles of products and reactants

    Heterogeneous Equilibria

    • Heterogeneous equilibrium: a reaction where one of the substances is in a different physical state
    • Equilibrium constant expression: concentrations of liquids and solids are omitted
    • Example: CaCO3(s) ⇌ CaO(s) + CO2(g)

    Shifts in Gaseous Equilibria

    • Le Chatelier's principle: the equilibrium shifts to relieve the stress when a reversible reaction is disturbed
    • Effect of concentration: increasing the amount of reactants or products shifts the equilibrium to the right or left
    • Effect of temperature: increasing the temperature favors the endothermic reaction, while decreasing the temperature favors the exothermic reaction
    • Effect of pressure: increasing the pressure favors the reaction with fewer gas molecules

    Wettability

    • Wettability: a measure of the ease at which liquids spread on solid surfaces
    • Contact angle measurement: a method to determine wettability
    • Ideal solid surface: flat, rigid, perfectly smooth, chemically homogeneous, and has zero contact angle hysteresis
    • Real surfaces: unlike ideal surfaces, they do not have perfect smoothness, rigidity, or chemical homogeneity

    Cohesion and Adhesion

    • Wettability as a balance between cohesion and adhesion
    • Cohesion: the tendency for similar molecules to attract each other
    • Adhesion: the degree to which dissimilar molecules attract each other

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    Description

    This quiz is about J.J. Thomson's model of the atom, which proposes that electrons are embedded in a sphere of positive charge. It's also known as the plum-pudding model of the atom.

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