Podcast
Questions and Answers
What is the meaning of $1/\tau_c$ in the context of electron collision?
What is the meaning of $1/\tau_c$ in the context of electron collision?
In the Drude model, electrons primarily collide with each other.
In the Drude model, electrons primarily collide with each other.
False
What is meant by 'mean free-path' in the context of Drude theory?
What is meant by 'mean free-path' in the context of Drude theory?
The average distance an electron travels between collisions.
In the Drude model, the equation of motion under an applied electric field is given by ( F = ma = -eE ), where ( e ) represents the _____ of the electron.
In the Drude model, the equation of motion under an applied electric field is given by ( F = ma = -eE ), where ( e ) represents the _____ of the electron.
Signup and view all the answers
Match the terms related to the Drude model with their correct descriptions:
Match the terms related to the Drude model with their correct descriptions:
Signup and view all the answers
What type of materials are primarily discussed in the course relating to Thin Film Transistors (TFTs)?
What type of materials are primarily discussed in the course relating to Thin Film Transistors (TFTs)?
Signup and view all the answers
A fully flexible Thin Film Transistor (TFT) requires each layer to be rigid and stable over time.
A fully flexible Thin Film Transistor (TFT) requires each layer to be rigid and stable over time.
Signup and view all the answers
What is the main difference between a MOSFET and a TFT?
What is the main difference between a MOSFET and a TFT?
Signup and view all the answers
The conductivity in organic TFTs is influenced by the ________ of the materials used.
The conductivity in organic TFTs is influenced by the ________ of the materials used.
Signup and view all the answers
Match the following types of materials with their usage:
Match the following types of materials with their usage:
Signup and view all the answers
What phenomenon occurs when metal, oxide, and semiconductor layers are combined in a TFT?
What phenomenon occurs when metal, oxide, and semiconductor layers are combined in a TFT?
Signup and view all the answers
Accumulation in TFTs occurs when the voltage applied is more positive than the flat band voltage (VFB).
Accumulation in TFTs occurs when the voltage applied is more positive than the flat band voltage (VFB).
Signup and view all the answers
Name a 2D material mentioned that can assist in creating ultrathin films and TFTs.
Name a 2D material mentioned that can assist in creating ultrathin films and TFTs.
Signup and view all the answers
What are the two main design approaches for TFT layouts?
What are the two main design approaches for TFT layouts?
Signup and view all the answers
Organic thin film transistors exhibit both electron and hole mobility.
Organic thin film transistors exhibit both electron and hole mobility.
Signup and view all the answers
What is one of the key functions of the substrate in a thin film transistor?
What is one of the key functions of the substrate in a thin film transistor?
Signup and view all the answers
The operation of TFTs generally occurs in the __________ region.
The operation of TFTs generally occurs in the __________ region.
Signup and view all the answers
Match the following terms related to MOSFET and TFT:
Match the following terms related to MOSFET and TFT:
Signup and view all the answers
In what configuration can TFTs be arranged?
In what configuration can TFTs be arranged?
Signup and view all the answers
What materials can serve as substrates for TFTs?
What materials can serve as substrates for TFTs?
Signup and view all the answers
TFTs function similarly to MOSFETs in terms of charge creation.
TFTs function similarly to MOSFETs in terms of charge creation.
Signup and view all the answers
What primarily governs charge transport in the p-type channel of a Thin Film Transistor (TFT)?
What primarily governs charge transport in the p-type channel of a Thin Film Transistor (TFT)?
Signup and view all the answers
In a TFT's accumulation region, holes are repelled from the semiconductor/oxide interface when a negative gate bias is applied.
In a TFT's accumulation region, holes are repelled from the semiconductor/oxide interface when a negative gate bias is applied.
Signup and view all the answers
What is the effect of applying a negative gate voltage (Vg < 0 V) in a TFT?
What is the effect of applying a negative gate voltage (Vg < 0 V) in a TFT?
Signup and view all the answers
In a Thin Film Transistor, the condition when Vg is less than VFB indicates a transition to the ______ state.
In a Thin Film Transistor, the condition when Vg is less than VFB indicates a transition to the ______ state.
Signup and view all the answers
Match the following terms related to TFT operation with their correct descriptions:
Match the following terms related to TFT operation with their correct descriptions:
Signup and view all the answers
What is the primary role of the oxide layer in a TFT?
What is the primary role of the oxide layer in a TFT?
Signup and view all the answers
Charge carriers in a p-type TFT channel are primarily electrons.
Charge carriers in a p-type TFT channel are primarily electrons.
Signup and view all the answers
What happens to the energy bands of a TFT when the gate voltage is lower than the flat-band voltage?
What happens to the energy bands of a TFT when the gate voltage is lower than the flat-band voltage?
Signup and view all the answers
What is the formula for current density (j) in terms of electron density (n), charge (e), and average velocity (
<
v
)?
What is the formula for current density (j) in terms of electron density (n), charge (e), and average velocity ( < v
)?
Signup and view all the answers
The drift velocity is directly proportional to the electric field strength.
The drift velocity is directly proportional to the electric field strength.
Signup and view all the answers
What is the primary relationship described by Ohm's law?
What is the primary relationship described by Ohm's law?
Signup and view all the answers
The expression for conductivity (σ) can be represented as σ = _____ / ρ.
The expression for conductivity (σ) can be represented as σ = _____ / ρ.
Signup and view all the answers
Match the following terms with their corresponding definitions:
Match the following terms with their corresponding definitions:
Signup and view all the answers
What happens when the gate voltage is higher than the threshold voltage (Vth)?
What happens when the gate voltage is higher than the threshold voltage (Vth)?
Signup and view all the answers
The formula for mobility (μe) is μe = Vd / E.
The formula for mobility (μe) is μe = Vd / E.
Signup and view all the answers
Define what is meant by 'electron mobility'.
Define what is meant by 'electron mobility'.
Signup and view all the answers
What happens to the Schottky barrier when a positive voltage is applied?
What happens to the Schottky barrier when a positive voltage is applied?
Signup and view all the answers
In the OFF state of a Schottky barrier, there is an electric field driving the charge carriers.
In the OFF state of a Schottky barrier, there is an electric field driving the charge carriers.
Signup and view all the answers
What major phenomenon allows some electrons to flow through the Schottky barrier even in the OFF state?
What major phenomenon allows some electrons to flow through the Schottky barrier even in the OFF state?
Signup and view all the answers
The height of the Schottky barrier is represented by ___
The height of the Schottky barrier is represented by ___
Signup and view all the answers
Match the states of the Schottky barrier with their characteristics:
Match the states of the Schottky barrier with their characteristics:
Signup and view all the answers
What is the result of a small UD applied in the OFF state?
What is the result of a small UD applied in the OFF state?
Signup and view all the answers
The width of the Schottky barrier changes when a positive gate voltage is applied.
The width of the Schottky barrier changes when a positive gate voltage is applied.
Signup and view all the answers
Who proposed Drude's classical theory and in what year?
Who proposed Drude's classical theory and in what year?
Signup and view all the answers
In the ON state, electrons are injected from the ___ into the effective channel.
In the ON state, electrons are injected from the ___ into the effective channel.
Signup and view all the answers
Which of the following correctly describes the behavior of charge carriers in the OFF state of a Schottky barrier?
Which of the following correctly describes the behavior of charge carriers in the OFF state of a Schottky barrier?
Signup and view all the answers
Study Notes
Processable Electronics: Materials Chemistry to Device Applications
- Lecture 9 covers thin-film transistors (TFTs), focusing on organic and small molecule TFTs.
- The lecture also discusses the thin film transistor, MOSFET vs TFT, and transport in organic TFTs.
Thin Film Transistor
- Thin-film transistors (TFTs) are discussed in the context of processable electronics.
- The lecture covers the operation and characteristics of TFTs, particularly focusing on organic/small molecule TFTs.
- TFTs differ from MOSFETs in their operation regions and charge carrier inversion.
MOSFET vs TFT
- MOSFETs typically operate in accumulation, inversion, and depletion regions, whereas TFTs typically operate in accumulation.
- Organic TFTs often exhibit poor inversion regions compared to the broader operation regions of MOSFETs.
Transport in Organic TFTs
- Transport in organic TFTs involves charge carriers, such as holes and electrons.
- The factors influencing the transport are described in the document.
Flexible Thin Film Transistor (TFT)
- A flexible TFT requires each layer to be flexible, stable, and conformable for long-term operation.
- Semiconducting materials, including inorganic (Group III, V, and VI semiconductors), organic (small molecules and polymers), and nanomaterials (e.g., graphene, single-layer MoS₂), are important components in the TFT's design.
Organic Thin Film Transistor
- Organic TFTs differ from inorganic MOSFETs (Si-substrate) in their basic operation of accumulation rather than inversion of charge carriers.
- Organic TFTs rarely demonstrate electron and hole mobility simultaneously.
TFT Design Approaches
- TFT layouts are categorized into staggered and coplanar configurations, further differentiated by bottom-gate and top-gate designs.
- Staggered bottom-gate structures are often used for high-temperature dielectric layers, whilst coplanar top-gate structures are common for high-temperature semiconductors.
The Thin Film Transistor (p-type)
- Charge transport in p-type TFT channels is dependent on the field effect.
- TFTs typically operate in accumulation. Holes are attracted to the semiconductor/oxide interface when a negative gate bias (Vg < 0 V) is applied.
The TFT - Accumulation
- VFB (flat-band voltage) is a crucial factor in TFT operation.
- A negative voltage applied to the gate causes a bending of valence and conduction bands, leading to accumulation of holes at the semiconductor/oxide interface.
TFT Channel Operations
- In TFTs, the metal-semiconductor junctions give rise to Schottky barriers, which play a crucial role in preventing high leakage current during the off-state.
- Applying a voltage between the drain and source contacts creates an off-current by tunneling. The gate electrode controls the potential barrier, thus controlling the drain current.
Schottky Barrier - Poor Blocking
- A Schottky barrier is formed at metal-semiconductor interfaces in TFTs, preventing charge carrier flow.
- The presence of this barrier can yield a leakage current, even in the off state, if this barrier is not high enough.
- The height of the barrier is controlled by factors (e.g. Va applied voltage).
Current in the Linear Region
- When gate voltage is higher than the threshold voltage, it induces a conductive channel in the TFT.
- Assuming μ_d is the mobility, the current is proportional to the product of μ_d, width, gate voltage, and potential difference, divided by the length.
Current in the Saturation Region
- For higher drain voltages, the current becomes constant (saturation).
- The saturation current is also described by mobility but is dependent on the square of the gate voltage.
TFT Operating Regions
- TFTs demonstrate linear and saturation regions of operation, distinct from MOSFETs.
- In the linear region, drain current linearly increases with increasing voltage.
- In saturation, the current levels off for higher drain voltages due to pinch-off.
Example of IGZO-TFT Fabrication (Sol-Gel Method)
- The fabrication of IGZO TFTs by the sol-gel method involves steps to deposit metallic gate electrodes, a dielectric layer (Al₂O₃ or SiO₂), and a channel layer (oxide precursor).
- These steps result in a finished IGZO-TFT.
Towards Flexible Transistors: Organic TFTs
- Conjugated molecules in organic TFTs typically arrange with their long axes parallel to facilitate charge transport.
- The charge density in the accumulation region depends on the stacking of dielectric layers with defined thickness.
Macromolecular Design of Conjugated Polymers
- Factors affecting conjugated polymer design include doping properties, control over bandgap, and electronic transport (conductivity).
Charge Transport in Conducting Polymers
- Describe and discuss types of transport in organic materials (polymers), potentially incorporating various scattering mechanisms (impurities, phonon scattering) and the effect of temperature.
Transport in Conducting Polymers
- Conjugated structures with alternating bonds support intrinsic conductivity in polymers such as polyacetylene.
- Molecular orbital formation directly affects electron density distribution within molecules, influencing electronic transport.
Electrons in Solids
- Wave functions and interfering standing waves can generate new quantum states.
- Multiple wells give rise to quasi-continuous energy levels in the solid.
Transport in Conducting Polymers
- Properties of conjugated materials often involve continuous orbital overlap that facilitates charge transport.
- Lowest energy molecular orbitals represent stable states for molecules.
Band Transport
- Band transport is common in conjugated polymers, often observed in the presence of an applied electric field, and involves scattering processes.
- The conductivity of a polaron is dependent on the mobility and the charge density.
Transport in Conducting Polymers
- Different transport mechanisms exist in conducting polymers. Variable-range hopping is an important consideration in conductivity.
- Conductivity is expressed as a function of temperature, often exhibiting exponential dependence described by the Mott law formula.
Child's Law
- Child's law describes current density in materials with high total charge Q under constant electric field and describes additional factors required to compute total current density.
Traps
- Trap states within a material can store charge and influence the current density.
- Traps affect the mobility within the surrounding space-charge region because of an effective mobility.
Transport in Conducting Polymers
- Band transport and the various potential transport mechanisms (e.g., polaron transport, hopping) in conducting polymers are discussed.
Example of Organic TFTs
- Examples of organic TFT devices include PMMA OTFT and P(VDF-TrFE)/PMMA.
- The characteristics of these devices include mobility, saturation current, and linear current.
Organic small molecules TFT
- Different devices and the properties (mobility) for these different types of conducting organic materials are covered.
- Properties such as mobility and switching behavior of organic small molecules (e.g., pure thiophene) can be modulated or enhanced by blending with certain polymers.
Organic TFTs
- A graph illustrates the increase in electron mobility in various organic TFTs from the 1980s to 2010.
Materials for Electronics
- Various materials for electronic applications, including graphene, single-crystalline silicon, and III-Vs, are discussed in the context of their electron mobility and band gaps.
Studying That Suits You
Use AI to generate personalized quizzes and flashcards to suit your learning preferences.
Related Documents
Description
Test your knowledge on the Drude model and its application to Thin Film Transistors (TFTs). This quiz covers key concepts such as mean free path, electron collisions, and the differences between MOSFETs and TFTs. Discover how material properties influence the performance of TFTs and understand the interactions within semiconductor layers.