Thermodynamics: Understanding Entropy
5 Questions
0 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Which reaction shows a decrease in entropy?

  • 2KCIO3(s) → 2KCI(s) + 302(g)
  • COâ‚‚(s) → CO2(g)
  • NaCl(s) → Na+(aq) + Cl-(aq)
  • H2O(l) → Hâ‚‚O(s) (correct)

In which reaction does the entropy increase significantly?

  • Ag+(aq) + Cl-(aq) → AgCl(s)
  • H+(aq) + Câ‚‚H₃Oâ‚‚(aq) → HCâ‚‚Hâ‚‚O₃(1)
  • COâ‚‚(s) → CO2(g) (correct)
  • Nâ‚‚(g) + 3H2(g) → 2NH3(g)

Which of the following reactions does not result in an increase in entropy?

  • 2NO(g) → Nâ‚‚(g) + O2(g)
  • H2(g) + Cl2(g) → 2HCI(g) (correct)
  • KCI(s) → KCI(I)
  • H+(aq) + OH-(aq) → Hâ‚‚O(1)

Identify the reaction that results in a decrease in entropy.

<p>2Al(s) + 312(s) → 2All3(s) (B)</p> Signup and view all the answers

Which reaction indicates that the system is moving towards higher entropy?

<p>2KCIO3(s) → 2KCI(s) + 302(g) (A)</p> Signup and view all the answers

Flashcards

Entropy (ΔS)

The measure of randomness or disorder in a substance.

Solid Entropy

Solids have low entropy because their particles are tightly packed and have little movement.

Gas Entropy

Gases have high entropy because their particles are widely separated and move freely.

Entropy Increase in Reactions

Reactions that produce more moles of gas, or break down solids to liquids or gases, usually increase entropy (ΔS > 0).

Signup and view all the flashcards

Entropy Decrease in Reactions

Reactions that form more ordered substances, like solids forming from liquids or gases, tend to decrease entropy (ΔS < 0).

Signup and view all the flashcards

Study Notes

Entropy and Chemical Reactions

  • Entropy is a measure of the randomness or disorder of a system.
  • Entropy increases when a system becomes more disordered.
  • Entropy decreases when a system becomes more ordered.

Factors Influencing Entropy Changes

  • Phase Changes:
    • Solid to Liquid: Entropy increases (more disorder)
    • Liquid to Gas: Entropy increases (more disorder)
    • Gas to Liquid: Entropy decreases (more order)
    • Liquid to Solid: Entropy decreases (more order)
  • Number of Molecules:
    • Reactions that increase the number of molecules: Entropy increases.
    • Reactions that decrease the number of molecules: Entropy decreases.
  • Complexity of Molecules:
    • Reactions forming more complex molecules: Entropy generally decreases.
    • Reactions breaking down complex molecules: Entropy generally increases.

Identifying Entropy Changes in Reactions

  • To determine if a reaction results in an increase or decrease in entropy, analyze the following:
    • Phase changes of reactants and products.
    • Number of molecules on each side of the reaction.
    • Complexity of molecules on each side of the reaction.
  • Reactions with a net increase in the number of molecules generally have a positive entropy change.
  • Reactions with a net decrease in the number of molecules generally have a negative entropy change.
  • Reactions that form more complex molecules generally have a negative entropy change.
  • Reactions that break down more complex molecules generally have a positive entropy change.

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

Entropy Practice Questions PDF

Description

This quiz explores the concept of entropy, its relation to states of matter, and the implications for chemical reactions. You'll learn how entropy reflects randomness and how it varies across solids, liquids, and gases. Test your knowledge on entropy changes during various reactions and their thermodynamic significance.

More Like This

Chemical Thermodynamics Quiz
42 questions
Chemical Reactions & Thermodynamics
6 questions
Entropy
27 questions

Entropy

FervidChrysoprase6800 avatar
FervidChrysoprase6800
Use Quizgecko on...
Browser
Browser