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What is internal energy primarily comprised of in a monatomic gas?
What is internal energy primarily comprised of in a monatomic gas?
Which of the following equations correctly represents the internal energy of a monatomic gas with N particles?
Which of the following equations correctly represents the internal energy of a monatomic gas with N particles?
How does the internal energy of an ideal gas relate to its temperature?
How does the internal energy of an ideal gas relate to its temperature?
For a monatomic gas, how can the internal energy also be expressed using moles (n)?
For a monatomic gas, how can the internal energy also be expressed using moles (n)?
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What condition is NOT applicable when using the equation U = nRT for internal energy?
What condition is NOT applicable when using the equation U = nRT for internal energy?
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What does the internal energy of an ideal gas depend on?
What does the internal energy of an ideal gas depend on?
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According to the first law of thermodynamics, which equation correctly represents the relationship between internal energy, heat, and work?
According to the first law of thermodynamics, which equation correctly represents the relationship between internal energy, heat, and work?
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Which of the following accurately describes a thermodynamic system?
Which of the following accurately describes a thermodynamic system?
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What is the change in internal energy when 3000 J of heat flows into a system and 1000 J of work is done by the system?
What is the change in internal energy when 3000 J of heat flows into a system and 1000 J of work is done by the system?
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What conclusion can be made about the energy of diatomic gases compared to monatomic gases regarding internal energy?
What conclusion can be made about the energy of diatomic gases compared to monatomic gases regarding internal energy?
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What does the branch of thermodynamics primarily focus on?
What does the branch of thermodynamics primarily focus on?
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Which type of wall allows heat to flow through?
Which type of wall allows heat to flow through?
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Which law states that two systems in equilibrium with a third are also in thermal equilibrium with each other?
Which law states that two systems in equilibrium with a third are also in thermal equilibrium with each other?
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When two systems are brought into contact and no heat flows between them, they are said to be in what?
When two systems are brought into contact and no heat flows between them, they are said to be in what?
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If a thermometer is used to measure the temperature of two systems, what can be concluded about the systems if they are in equilibrium with the thermometer?
If a thermometer is used to measure the temperature of two systems, what can be concluded about the systems if they are in equilibrium with the thermometer?
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In the context of the Zeroth Law, what is an indicator of thermal equilibrium?
In the context of the Zeroth Law, what is an indicator of thermal equilibrium?
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Which of the following best describes an adiabatic wall?
Which of the following best describes an adiabatic wall?
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What is the main requirement for a system to be described as having a single temperature?
What is the main requirement for a system to be described as having a single temperature?
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What is the relationship between temperature and heat flow when systems are in thermal contact?
What is the relationship between temperature and heat flow when systems are in thermal contact?
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What does the change in internal energy depend on according to the first law of thermodynamics?
What does the change in internal energy depend on according to the first law of thermodynamics?
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In the context of the first law of thermodynamics, how is work defined by engineers?
In the context of the first law of thermodynamics, how is work defined by engineers?
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If a system gains heat, what is the sign of Q in ΔU = Q - W?
If a system gains heat, what is the sign of Q in ΔU = Q - W?
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How is work treated in the sign convention used by physicists?
How is work treated in the sign convention used by physicists?
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What would be the internal energy change if a system gains 1500 J of heat and 2200 J of work is done by the system?
What would be the internal energy change if a system gains 1500 J of heat and 2200 J of work is done by the system?
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What does ΔU = U f − U i = Q − W represent?
What does ΔU = U f − U i = Q − W represent?
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What does work done BY the system indicate in terms of energy transfer?
What does work done BY the system indicate in terms of energy transfer?
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Which statement correctly describes the other sign convention mentioned?
Which statement correctly describes the other sign convention mentioned?
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How does an air conditioner operate in terms of heat transfer?
How does an air conditioner operate in terms of heat transfer?
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What happens to the internal energy of a monatomic gas that absorbs heat while expanding at constant pressure and temperature?
What happens to the internal energy of a monatomic gas that absorbs heat while expanding at constant pressure and temperature?
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In an adiabatic process, what happens to the temperature of boiling water in a thermally equilibrated container?
In an adiabatic process, what happens to the temperature of boiling water in a thermally equilibrated container?
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What is the change in internal energy when heat is lost by a system?
What is the change in internal energy when heat is lost by a system?
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What does the first law of thermodynamics imply when a system does work on its surroundings?
What does the first law of thermodynamics imply when a system does work on its surroundings?
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When is heat considered positive in the context of thermodynamics?
When is heat considered positive in the context of thermodynamics?
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If a physicist removes energy from a system until it reaches a temperature close to absolute zero, what is true about the internal energy?
If a physicist removes energy from a system until it reaches a temperature close to absolute zero, what is true about the internal energy?
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Which statement about the transfer of heat and work in the context of the first law of thermodynamics is accurate?
Which statement about the transfer of heat and work in the context of the first law of thermodynamics is accurate?
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Study Notes
Lecture 9 Summary
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Lecture 9 covers internal energy, thermodynamic systems, the zeroth law of thermodynamics, and the first law of thermodynamics.
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The reading material is from Cutnell & Johnson sections 14.3, 15.1-15.3.
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Internal energy (U) is the sum of all the energies of the individual atoms or molecules of a substance. This includes translational, rotational, vibrational (kinetic and potential) energies, and potentially other energies (e.g., magnetic).
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For a monatomic gas, atoms are considered point-like with mass concentrated at the point. There is no rotational, vibrational, or chemical bonding energy. Internal energy is the sum of only the translational kinetic energies.
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For N particles, U = N * (1/2) * mvrms2. Using the microscopic definition of temperature, mvrms2/2 = (3/2)kT, internal energy becomes U = N * (3/2)kT. n moles can replace N particles, so U = (3/2)*nRT.
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Internal energy is proportional to Kelvin temperature for any ideal gas, although the constant of proportionality can differ based on the gas type (monatomic, diatomic, etc.)
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Thermodynamics is the branch of physics dealing with heat and its relation to other energy forms and work. It looks at macroscopic properties like temperature, internal energy, pressure, and volume.
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A car engine is an example of a thermodynamic system: Fuel is burned at high temperatures. Some internal energy is used to drive pistons, and excess heat is removed by the cooling system.
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A thermodynamic system is the object or collection of objects of interest. Surroundings are everything else in the environment.
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Heat and work may transfer between the system and the surroundings.
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Walls of a system, like diathermal walls, permit heat flow, or adiabatic walls (perfectly insulating) prevent heat flow.
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The zeroth law of thermodynamics states: Two systems individually in equilibrium with a third system are in thermal equilibrium with each other. This signifies a shared temperature. No heat flow occurs between objects of the same temperature in contact. Thermal equilibrium exists when there's no heat flow between two objects when brought in contact. Temperature is the indicator of this equilibrium.
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The zeroth law of thermodynamics is useful conceptually in defining a temperature scale in relation to various objects and systems. For example, a thermometer is used as a third system to determine if two other systems are in thermal equilibrium with each other.
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First law of thermodynamics: Forces can do work, changing the kinetic and potential energy of an object. A substance's atoms/molecules collide; exert forces on each other and surrounding walls. This gives kinetic and potential energy. Internal energy is the total sum of this energy and other molecular energies.
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When heat or work occurs in a thermodynamic system, the internal energy can change as a result. The first law relates the change in internal energy to the heat transferred and the work done.
- AU = Uf – Ui = Q – W
- A system gains heat (Q), the change in internal energy (AU) is equal to the heat gained minus the work done. The sign convention is that heat is positive when the system gains heat, and negative when it loses heat. Work (W) is positive when done by the system and negative when done on the system.
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The example problems illustrate how heat and work affect the change in internal energy (AU) of a system (following the first law in either scenario with heat being absorbed by the system, or work done by the system or on the system.
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Test your knowledge on the internal energy of monatomic gases in this thermodynamics quiz. Explore key concepts such as the relationship between internal energy, temperature, and thermodynamic laws. Ideal for students studying thermodynamics in physics courses.